Carbon fibers having improved strength and modulus and an associated method and apparatus for preparing same

Patent metadata

Field	Value
Publication number	US-9340905-B2
Application number	US-201514797314-A
Country	US
Kind code	B2
Filing date	Jul 13, 2015
Priority date	Nov 22, 2006
Publication date	May 17, 2016
Grant date	May 17, 2016

Abstract

The invention is directed to carbon fibers having high tensile strength and modulus of elasticity. The invention also provides a method and apparatus for making the carbon fibers. The method comprises advancing a precursor fiber through an oxidation oven wherein the fiber is subjected to controlled stretching in an oxidizing atmosphere in which tension loads are distributed amongst a plurality of passes through the oxidation oven, which permits higher cumulative stretches to be achieved. The method also includes subjecting the fiber to controlled stretching in two or more of the passes that is sufficient to cause the fiber to undergo one or more transitions in each of the two or more passes. The invention is also directed to an oxidation oven having a plurality of cooperating drive rolls in series that can be driven independently of each other so that the amount of stretch applied to the oven in each of the plurality of passes can be independently controlled.

First claim

The invention claimed is:

1. A carbon fiber having a tensile strength from about 950 to 1166 ksi and modulus of elasticity of about 45 to 53.3 Msi, and an average phase angle depth between 5 to 15.1 nanometers.

2. The carbon fiber according to claim 1 , wherein the carbon fiber has a modulus of elasticity of about 50 to 53.3 Msi.

3. The carbon fiber according to claim 1 , wherein the carbon fiber has a tensile strength about of 1000 to 1166 ksi and modulus of elasticity of about 50 to 53.3 Msi.

4. The carbon fiber according to claim 1 , wherein the carbon fiber has a tensile strength about of 1107 to 1166 ksi and modulus of elasticity of about 51.5 to 53.3 Msi.

5. The carbon fiber according to claim 1 , wherein the carbon fiber has at least one of the following
an Arithmetic Average Roughness (Ra) between 2 and 5.9;
a maximum phase angle depth between 32 and 50 nanometers; and
an average phase angle depth between 10 to 14 nanometers.

6. The carbon fiber according to claim 5 , wherein the carbon fiber has a maximum phase angle depth between 40 and 50 nm.

7. The carbon fiber according to claim 6 , wherein the carbon fiber has a roughness having a Root Mean Square Roughness (Rq) value between 2 and 8.2.

8. A carbon fiber having a tensile strength from about 950 to 1166 ksi and modulus of elasticity of about 45 to 53.3 Msi, and a maximum phase angle depth between 32 and 50 nanometers.

9. The carbon fiber according to claim 8 , wherein the carbon fiber has a modulus of elasticity of about 50 to 53.3 Msi.

10. The carbon fiber according to claim 8 , wherein the carbon fiber has a tensile strength about of 1000 to 1166 ksi and modulus of elasticity of about 50 to 53.3 Msi.

11. The carbon fiber according to claim 10 , wherein the carbon fiber has a tensile strength about of 1000 to 1166 ksi and modulus of elasticity of about 50 to 53.3 Msi, and an average phase angle depth between 5 to 15.1 nanometers.

12. The carbon fiber according to claim 8 , wherein the carbon fiber has a crystalline width value L a between 4 and 5.7 nanometers and an Arithmetic Average Roughness (Ra) between 2 and 5.9.

13. The carbon fiber according to claim 8 , wherein the carbon fiber has a radial uniformity value RU from 50 to 1,000.

14. The carbon fiber according to claim 8 , wherein the carbon fiber has a difference in crystallinity “RD” between the inner and outer layers of a single filament that is from 0.01 to 0.05.

15. The carbon fiber according to claim 8 , wherein the carbon fiber has an average phase angle depth between 10 to 14 nanometers; an Arithmetic Average Roughness (Ra) between 2 and 5.9; a roughness having a Root Mean Square Roughness (Rq) value between 2 and 8.2; and a radial uniformity RU value of about 50 to about 1000.

16. A carbon fiber having a tensile strength from about 950 to 1166 ksi and modulus of elasticity of about 45 to 53.3 Msi, a diameter from 3.4 to 4.5 μm, and at least one of the following:
an Arithmetic Average Roughness (Ra) between 2 and 5.9;
a crystalline width value L a between 4 and 5.7 nanometers;
a maximum phase angle depth between 32 and 50 nanometers; and
an average phase angle depth between 5 to 15.1 nanometers;
a roughness having a Root Mean Square Roughness (Rq) value between 2 and 8.2;
a radial uniformity RU value of about 50 to about 1000; and
an RD that is from 0.01 to 0.05.

17. The carbon fiber according to claim 16 , wherein the carbon fiber has a roughness having a Root Mean Square Roughness (Rq) value between 3.9 and 8.2 and a radial uniformity RU value of about 50 to about 1000.

18. The carbon fiber according to claim 16 , wherein the carbon fiber has a difference in crystallinity “RD” between the inner and outer layers of a single filament that is from about 0.01 to 0.05, and a maximum phase angle depth between 32 and 50 nm.

19. The carbon fiber according to claim 16 , wherein the carbon fiber has the following
an Arithmetic Average Roughness (Ra) between 2 and 5.9;
a maximum phase angle depth between 32 and 50 nanometers; and
an average phase angle depth between 5 to 15.1 nanometers.

20. The carbon fiber according to claim 16 , wherein the carbon fiber has at least two of the following:
an Arithmetic Average Roughness (Ra) between 2 and 5.9;
a crystalline width value L a between 4 and 5.7 nanometers;
a maximum phase angle depth between 32 and 50 nanometers; and
an average phase angle depth between 5 to 15.1 nanometers;
a roughness having a Root Mean Square Roughness (Rq) value between 2 and 8.2;
a radial uniformity RU value of about 50 to about 1000; and
an RD that is from 0.01 to 0.05.

Assignees

• Hexcel Corp

Inventors

• León Y León Carlos A

Classifications

• D02J1/228

  Stretching in two or more steps, with or without intermediate steps · CPC title

• D01F9/225 Primary

  from stabilised polyacrylonitriles · CPC title

• Y10T428/2918

  including free carbon or carbide or therewith [not as steel] · CPC title

• F27B9/28

  for treating continuous lengths of work · CPC title

• D01F9/22 Primary

  from polyacrylonitriles · CPC title