Low temperature stabilization process for production of carbon fiber having structural order

Patent metadata

Field	Value
Publication number	US-2016258082-A1
Application number	US-201514640788-A
Country	US
Kind code	A1
Filing date	Mar 6, 2015
Priority date	Mar 6, 2015
Publication date	Sep 8, 2016
Grant date	—

Abstract

A method for producing a carbon fiber, the method comprising: (i) subjecting a continuous carbon fiber precursor having a polymeric matrix in which strength-enhancing particles are incorporated to a stabilization process during which the carbon fiber precursor is heated to within a temperature range ranging from the glass transition temperature to no less than 20° C. below the glass transition temperature of the polymeric matrix, wherein the maximum temperature employed in the stabilization process is below 400° C., for a processing time within said temperature range of at least 1 hour in the presence of oxygen and in the presence of a magnetic field of at least 1 Tesla, while said carbon fiber precursor is held under an applied axial tension; and (ii) subjecting the stabilized carbon fiber precursor, following step (i), to a carbonization process. The stabilized carbon fiber precursor, resulting carbon fiber, and articles made thereof are also described.

First claim

What is claimed is:

1 . A method for producing a carbon fiber, the method comprising:
(i) subjecting a continuous carbon fiber precursor having a polymeric matrix in which strength-enhancing particles are incorporated to a stabilization process during which the carbon fiber precursor is heated to within a temperature range ranging from the glass transition temperature to no less than 20° C. below the glass transition temperature of the polymeric matrix, wherein the maximum temperature employed in the stabilization process is below 400° C., for a processing time within said temperature range of at least 1 hour in the presence of oxygen and in the presence of a magnetic field of at least 1 Tesla, while said carbon fiber precursor is held under an applied axial tension; and (ii) subjecting the stabilized carbon fiber precursor, following step (i), to a carbonization process.

2 . The method of claim 1 , wherein said maximum temperature is no more than 300° C.

3 . The method of claim 1 , wherein said polymer matrix has a composition comprised of lignin, polyacrylonitrile, polyolefin, viscose, rayon, or pitch.

4 . The method of claim 1 , wherein said polymer matrix has a composition comprising lignin

5 . The method of claim 1 , wherein said strength-enhancing particles are carbon particles.

6 . The method of claim 5 , wherein said carbon particles are selected from carbon fibers, carbon nanotubes, graphene, graphene oxide, graphene nanoribbons, graphite, carbon black, activated carbon, carbon foam, carbon onion, carbon nanoflakes, spherical fullerenes, and amorphous carbon.

7 . The method of claim 1 , wherein said carbonization process is conducted at a temperature of at least 500° C.

8 . The method of claim 1 , wherein said carbonization process is conducted at a temperature of up to 2000° C.

9 . The method of claim 1 , wherein said carbonization process is conducted at a temperature of at least 800° C. and up to 1800° C.

10 . The method of claim 1 , wherein said magnetic field is at least 2 Tesla.

11 . The method of claim 1 , wherein said magnetic field is at least 3 Tesla.

12 . The method of claim 1 , wherein said magnetic field is at least 4 Tesla.

13 . The method of claim 1 , wherein said magnetic field is at least 5 Tesla.

14 . The method of claim 1 , wherein said processing time is at least 3 hours.

15 . The method of claim 1 , wherein said carbon fiber is included in an amount of at least 1 wt % and up to 50 wt %.

16 . The method of claim 1 , wherein said carbon fiber is included in an amount of at least 5 wt % and up to 40 wt %.

17 . The method of claim 1 , wherein the polymeric matrix in the stabilized carbon fiber precursor in step (i) possesses substantially ordered domains with alignment in the axial direction of the carbon fiber precursor.

18 . The method of claim 1 , wherein the carbon particles in the stabilized carbon fiber precursor in step (i) are substantially aligned in the axial direction of the carbon fiber precursor.

19 . The method claim 1 , wherein said continuous carbon fiber precursor is provided by a melt spinning process.

20 . The method of claim 1 , wherein said carbon fiber precursor is heated to within said temperature range by heating the carbon fiber precursor from ambient temperature to within said temperature range at a rate of no more than 1° C. per minute.

21 . The method of claim 1 , wherein said temperature range and processing time is sufficient for said polymeric matrix to remain solid but of sufficient plasticity to permit reorganization and axial ordering of polymeric domains in the polymeric matrix.

22 . The method of claim 1 , wherein said polymeric matrix comprises lignin, and the resulting lignin-containing carbon fiber precursor is subjected to a temperature within a range of 100-180° C. for at least one hour in the stabilization process of step (i).

Assignees

• Ut Battelle Llc

Inventors

• Rios Orlando
• Mcguire Michael Alan
• More Karren Leslie
• Tenhaeff Wyatt Evan
• Menchhofer Paul A
• Paulauskas Felix Leonard

Classifications

• D01F9/20 Primary

  from polyaddition, polycondensation or polymerisation products (D01F9/145, D01F9/16, D01F9/18 take precedence) · CPC title

• D01F9/22

  from polyacrylonitriles · CPC title

• D01F1/10

  Other agents for modifying properties · CPC title

• D01F9/14 Primary

  by decomposition of organic filaments · CPC title

• D01F9/17

  from lignin · CPC title