Catalyst for selective paraffin isomerization and preparation method and use thereof

Patent metadata

Field	Value
Publication number	US-9314781-B2
Application number	US-201113858964-A
Country	US
Kind code	B2
Filing date	Oct 13, 2011
Priority date	Oct 13, 2010
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

The present invention discloses a catalyst for paraffin isomerization, as well as a preparation method and use thereof. The catalyst comprises a TON molecular sieve modified by rare earth, an inorganic refractory oxide modified by zirconium oxide and a noble metal of group VIII. The weight ratio of the TON molecular sieve modified by rare earth to the inorganic refractory oxides modified by zirconium oxide is 10:90 to 90:10, and the content of the metal of group VIII is 0.1 to 10 wt % based on the metal. When used in the process of isomerization dewaxing of various raw materials containing paraffins, the catalyst can not only decrease the solidifying points of raw oil containing paraffins, but also increase the yield of liquid products. Particularly, when used in the process of isomerization dewaxing of lubricating oil distillates, the catalyst is advantageous in producing base oil for lubricating oil with a high a higher yield, a lower pour point (solidifying point) and a higher viscosity index.

First claim

The invention claimed is:

1. A method of preparing a catalyst for paraffin isomerization, comprising:
a) mixing one or more rare earth compounds with a TON molecular sieve to form a first mixture, drying and calcining the first mixture to obtain a TON molecular sieve modified by one or more rare earth oxides;
b) mixing one or more zirconium compounds with an inorganic refractory oxide to form a second mixture, drying and calcining the second mixture to obtain an inorganic oxide modified by zirconium oxide;
c) kneading the TON molecular sieves comprising one or more rare earth oxides and the inorganic refractory oxide modified by zirconium oxide to form a third mixture, drying and calcining the third mixture to obtain a catalyst carrier; and
d) loading a compound of a noble metal of group VIII on the catalyst carrier to obtain a catalyst precursor, drying and calcining the catalyst precursor to obtain the catalyst for paraffin isomerization.

2. The method according to claim 1 , wherein said TON molecular sieve is chosen from ZSM-22, Nu-10, KZ-2, ISI-1, or a mixture of one or more thereof.

3. The method according to claim 1 , wherein a molar ratio of silicon to aluminum in said TON molecular sieve is 50 to 200.

4. The method according to claim 1 , wherein said inorganic refractory oxide is chosen from aluminum oxide, titanium oxide, silicon oxide, boron oxide, magnesium oxide, clay, or a mixture of at least two or more thereof.

5. The catalyst according to claim 1 , wherein said noble metal of group VIII is chosen from platinum, palladium, or a mixture thereof.

6. The method according to claim 1 , wherein said rare earth compound is chosen from lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, dysprosium, gadolinium, erbium, thulium, yttrium, or lutetium.

7. The method according to claim 1 , wherein said TON molecular sieve is H molecular sieve.

Assignees

• Xu Huiqing
• Liu Quanjie
• Jia Liming
• Zhang Xiwen
• Wang Wei
• China Petroleum & Chemical
• Fushun Res Inst Petroleum & Petrochemicals Sinopec

Inventors

• Xu Huiqing
• Liu Quanjie
• Jia Liming
• Zhang Xiwen
• Wang Wei

Classifications

• B01J2229/42

  Addition of matrix or binder particles · CPC title

• B01J29/7484 Primary

  TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22 · CPC title

• C10G45/64

  containing crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10G2400/10

  Lubricating oil · CPC title

• B01J2229/20

  to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself · CPC title