Catalyst compositions and use in heavy aromatics conversion processes

Patent metadata

Field	Value
Publication number	US-10058853-B2
Application number	US-201615004623-A
Country	US
Kind code	B2
Filing date	Jan 22, 2016
Priority date	Feb 4, 2015
Publication date	Aug 28, 2018
Grant date	Aug 28, 2018

Abstract

Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C 8 + aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a mordenite zeolite synthesized from TEA or MTEA, optionally at least one first metal of Group 10 of the IUPAC Periodic Table, and optionally at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m 2 /g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

First claim

The invention claimed is:

1. A process, comprising:
contacting a feedstock comprising toluene, C 8+ aromatic hydrocarbons and optionally hydrogen with a catalyst under suitable conversion conditions to transalkylate the C 8+ aromatic hydrocarbons with toluene; and
producing an effluent stream comprising aromatic products that are lighter than at least some of the C 8+ aromatic hydrocarbons in the feedstock, wherein the aromatic products comprise xylenes, wherein the catalyst composition comprises a mordenite zeolite synthesized from TEA or MTEA, wherein the mordenite zeolite has a mesopore surface area of greater than 30 m 2 /g and the mordenite comprises agglomerates composed of primary crystallites, and wherein the primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.

2. The process of claim 1 , wherein the catalyst further comprises (ii) 0.005 to 5.0 wt. % of at least one first metal of Group 10 of the IUPAC Periodic Table, based on the weight of the catalyst composition.

3. The process of claim 2 , wherein the catalyst further comprises (iii) 0.01 to 5.0 wt. % of at least one a second metal of Group 11 to 15 of the IUPAC Periodic Table, based on the weight of the catalyst composition.

4. The process of claim 1 , wherein the C 8+ aromatic hydrocarbons of the feedstock comprise aromatic compounds having nine or more carbon atoms.

5. The process of claim 1 , wherein the feedstock further comprises benzene.

6. The process of claim 1 , wherein the C 8+ aromatic hydrocarbons comprises aromatic compounds having a boiling point in the range of 135° C. to 260° C. at atmospheric pressure.

7. The process of claim 1 , wherein the effluent stream comprises at least one selected from the group consisting of benzene, and toluene.

8. The process of claim 1 , wherein the suitable conversion conditions comprise a temperature of 340° C. to 515° C., a pressure from 380 kPa (55 psia) to 4240 kPa (615 psia) and a weight hourly space velocity (WHSV) in the range of 1 to 100 hr −1 based on the weight of the feedstock.

9. The process of claim 1 , further comprising a reactor for contacting said feedstock with the catalyst composition under the suitable conversion conditions, wherein the reactor comprises at least one fixed catalyst bed of the catalyst composition.

10. The process of claim 1 , further comprising a reactor for contacting feedstock with the catalyst composition under the suitable conversion conditions, wherein the reactor comprises at least one fluid bed of the catalyst composition.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Lai Wenyih F
• Elia Christine N
• Cheng Jane C
• Luo Shifang L
• Nair Hari
• Cutler Joshua I
• Levin Doron
• Bai Chuansheng

Classifications

• B01J29/76

  Iron group metals or copper · CPC title

• B01J29/44 Primary

  Noble metals · CPC title

• B01J29/22

  Noble metals · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• B01J29/7653

  MFS-type, e.g. ZSM-57 · CPC title