Thermistor element, temperature sensor, and method for manufacturing the thermistor element

Patent metadata

Field	Value
Publication number	US-9312054-B2
Application number	US-201414199055-A
Country	US
Kind code	B2
Filing date	Mar 6, 2014
Priority date	Mar 12, 2013
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

A thermistor element includes a thermistor main body having a rectangular parallelepiped shape, and a first covering layer having reduction resistance and covering the periphery of the thermistor main body. At least a portion (exposed outer surface) of the outer surface of the first covering layer is exposed to the outside. When the shortest distance in a straight line in the first covering layer extending from a starting point on the thermistor main body to the exposed outer surface is defined as an exposed layer thickness at the starting point, the first covering layer is formed such that an exposed layer thickness measured by using any vertex of the rectangular parallelepiped thermistor main body as a starting point is equal to or greater than the smallest one of exposed layer thicknesses measured by using points on three sides and three flat surfaces which form the vertex.

First claim

The invention claimed is:

1. A thermistor element comprising:
a thermistor main body made of an electrically conductive sintered oxide and having a rectangular parallelepiped shape; and
a first covering layer which has reduction resistance, said first covering layer covering an entire periphery of the thermistor main body and having an outer surface, at least a portion of which is an exposed outer surface exposed to the outside, wherein
when a shortest distance in a straight line in the first covering layer extending from a starting point on the thermistor main body to the exposed outer surface is defined as an exposed layer thickness at the starting point,
the first covering layer is formed such that the exposed layer thickness measured by using any vertex of the rectangular parallelepiped thermistor main body as a starting point is equal to or greater than the smallest one of exposed layer thicknesses measured by using, as starting points, points which are other than the vertex and are located on three sides and three flat surfaces which form the vertex.

2. The thermistor element according to claim 1 , further comprising:
a plurality of leads which are connected to the thermistor main body and extend through the first covering layer and project therefrom; and
a second covering layer which has reduction resistance and is made of a material different from the material of the first covering layer, wherein
the second covering layer covers a portion of each lead and a portion of the first covering layer to thereby airtightly close interfaces between the leads and the first covering layer.

3. The thermistor element according to claim 2 , wherein
the leads are a pair of leads which are respectively connected to facing surfaces of the thermistor main body facing each other via one end surface of the thermistor main body and extend in the same direction beyond the end surface; and
the second covering layer is formed within an extension-side outer surface which is a portion of the outer surface of the first covering layer, said extension-side outer surface being located outward of the end surface with respect to an extending direction of the leads.

4. The thermistor element according to claim 2 , wherein a relation of X1>X2 and a relation of X3>X2 are satisfied, where X1 represents a coefficient of thermal expansion of the first covering layer, X2 represents a coefficient of thermal expansion of the second covering layer, and X3 represents a coefficient of thermal expansion of the leads.

5. The thermistor element according to claim 4 , wherein
a difference (X1−X2) between the coefficient of thermal expansion X1 of the first covering layer and the coefficient of thermal expansion X2 of the second covering layer satisfies a relation of (X1−X2)≦15×10 −7 /° C.; and
a difference (X3−X2) between the coefficient of thermal expansion X3 of the leads and the coefficient of thermal expansion X2 of the second covering layer satisfies a relation of (X3−X2)≦15×10 −7 /° C.

6. The thermistor element according to claim 2 , wherein the second covering layer is made of glass or a mixture of glass and metal oxide particles.

7. The thermistor element according to claim 6 , wherein the glass which forms the second covering layer is amorphous glass.

8. The thermistor element according to claim 1 , wherein the first covering layer is made of glass or a mixture of glass and metal oxide particles.

9. The thermistor element according to claim 8 , wherein the glass which forms the first covering layer is crystallized glass.

10. The thermistor element according to claim 1 , wherein the first covering layer has a rectangular parallelepiped outer shape and has flat surfaces parallel to flat surfaces of the rectangular parallelepiped thermistor main body.

11. The thermistor element according to claim 1 , wherein the first covering layer has a circular columnar outer shape and has a pair of flat surfaces which are parallel to a pair of flat surfaces of the rectangular parallelepiped thermistor main body, said flat surfaces facing each other.

12. A temperature sensor which comprises a thermistor element according to claim 1 .

13. A method of manufacturing a thermistor element including a thermistor main body made of an electrically conductive sintered oxide and having a rectangular parallelepiped shape, and a first covering layer which has reduction resistance, said first covering layer covering an entire periphery of the thermistor main body and having an outer surface, at least a portion of which is an exposed outer surface exposed to the outside, wherein when a shortest distance in a straight line in the first covering layer extending from a starting point on the thermistor main body to the exposed outer surface is defined as an exposed layer thickness at the starting point, the first covering layer is formed such that the exposed layer thickness measured by using any vertex of the rectangular parallelepiped thermistor main body as a starting point is equal to or greater than the smallest one of exposed layer thicknesses measured by using, as starting points, points which are other than the vertex and located on three sides and three flat surfaces which form the vertex, the method comprising the steps of:
press forming a green first covering layer, which is to become the first covering layer through firing, into a shape for encapsulating the thermistor main body; and
firing the green first covering layer to thereby form the first covering layer.

Assignees

• Ngk Spark Plug Co

Inventors

• Watanabe Hiroshi
• Okimura Yasuyuki

Classifications

• G01K2205/04

  for measuring exhaust gas temperature · CPC title

• H01C7/04

  having negative temperature coefficient · CPC title

• H01C1/032

  plural layers surrounding the resistive element (H01C1/028 takes precedence) · CPC title

• Y10T29/49085

  Thermally variable · CPC title

• H01C17/02

  adapted for manufacturing resistors with envelope or housing (apparatus or processes for filling or compressing insulating material in heating element tubes H05B3/52) · CPC title