Producing method of metal fine particles or metal oxide fine particles, metal fine particles or metal oxide fine particles, and metal-containing paste, and metal film or metal oxide film

Patent metadata

Field	Value
Publication number	US-9309119-B2
Application number	US-201113069825-A
Country	US
Kind code	B2
Filing date	Mar 23, 2011
Priority date	Mar 24, 2010
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

There is provided a producing method of metal fine particles or metal oxide fine particles for producing metal fine particles or metal oxide fine particles by atomizing raw materials by performing processes including an oxidizing process and a reducing process to the raw materials composed of metal or a metal compound.

First claim

What is claimed is:

1. A producing method of metal fine particles, comprising atomizing raw materials composed of copper and producing metal fine particles by repeating a cycle multiple times, the cycle comprising:
an oxidizing process of producing a metal oxide by oxidizing the raw materials;
a grinding process of grinding the metal oxide after the oxidizing process; and
a reducing process of reducing the metal oxide in a liquid solvent by
adding the metal oxide subjected to the grinding process in the liquid solvent,
dispersing the metal oxide in the liquid solvent by irradiating the liquid solvent with ultrasonic waves, thereafter
irradiating the liquid solvent with microwaves of 2.45 GHz, to thereby set a temperature of the liquid solvent to 80° C., thereafter
irradiating the liquid solvent with microwaves of 2.45 GHz for 1 hour.

2. The producing method of metal fine particles according to claim 1 , wherein when raw materials are added to the liquid solvent having a reducing force in the reducing process, a concentration of the raw materials in the liquid solvent is in a range of 0.01 mol/L to 10 mol/L.

3. The producing method of metal fine particles according to claim 1 , wherein the oxidizing process is performed to raw materials, which are set in a solid state, in a liquid phase, or in a gas phase having an oxidizing force.

4. The producing method of metal fine particles according to claim 1 , wherein the raw materials are particle-shaped or powder-shaped pure metal.

5. A producing method of metal fine particles, comprising:
a first reducing process of adding raw materials composed of CuO in a liquid solvent, and irradiating the liquid solvent with ultrasonic waves to disperse the CuO in the liquid solvent, and thereafter irradiating the liquid solvent with microwaves of 2.45 GHz to set a temperature of the liquid solvent to 70° C., and thereafter irradiating the liquid solvent with microwaves of 2.45 GHz for 1 hour to reduce the CuO in the solvent, to thereby obtain a product of Cu;
an oxidizing process of oxidizing the product of Cu to obtain a product of a copper oxide;
a grinding process of grinding the product of copper oxide after the oxidizing process; and
a second reducing process of adding the product of the copper oxide subjected to the grinding process, into a liquid solvent, then irradiating the liquid solvent with ultrasonic waves to disperse the product of the copper oxide in the liquid solvent, and thereafter irradiating the liquid solvent with microwaves of 2.45 GHz to set a temperature of the solvent to 70° C., and thereafter irradiating the liquid solvent with microwaves of 2.45 GHz for 1 hour to reduce the product of the copper oxide in the liquid solvent,
wherein after the first reducing process is performed, the oxidizing process, the grinding process, and the second reducing process are repeated multiple times, to thereby atomize the raw materials and produce metal fine particles.

Assignees

• Hayashi Yamato
• Sekiguchi Yoshihiro
• Takizawa Hirotsugu
• Ishikawa Dai
• Abe Tomiya
• Hitachi Metals Ltd

Inventors

• Hayashi Yamato
• Sekiguchi Yoshihiro
• Takizawa Hirotsugu
• Ishikawa Dai
• Abe Tomiya

Classifications

• B22F1/052

  characterised by a mixture of particles of different sizes or by the particle size distribution · CPC title

• C01B13/322 Primary

  of elements or compounds in the solid state · CPC title

• B22F1/0014

  Operations & Transport · mapped topic

• C01G3/02

  Oxides; Hydroxides · CPC title

• C01P2004/51

  Particles with a specific particle size distribution · CPC title