Fabricating porous materials using thixotropic gels

Patent metadata

Field	Value
Publication number	US-9308511-B2
Application number	US-201013499167-A
Country	US
Kind code	B2
Filing date	Oct 12, 2010
Priority date	Oct 14, 2009
Publication date	Apr 12, 2016
Grant date	Apr 12, 2016

Abstract

Methods, apparatuses, and systems for fabricating porous materials using thixotropic gels. A shear force is applied to a thixotropic material causing the material to flow. Multiple components are added to the thixotropic material while applying the shear force causing the multiple components to be distributed in the material. The shear force is removed such that the static properties of the thixotropic material in the absence of the shear force retain a distribution of the multiple components in the thixotropic material to form a composite gel material that includes liquid within a network of inter-connected solid particles that include the distributed plurality of components. The liquid in the composite gel material is removed to form a porous composite material.

First claim

What is claimed is:

1. A method of fabricating a porous material, the method comprising:
applying a shear force to a thixotropic wet gel to yield a thixotropic fluid;
adding a plurality of components to the thixotropic fluid while applying the shear force, thereby distributing the plurality of components in the thixotropic fluid;
removing the shear force from the thixotropic fluid in which the plurality of components is distributed to yield a composite gel in which the plurality of components is distributed; and
treating the composite gel to yield a porous material.

2. The method of claim 1 , wherein the thixotropic wet gel comprises a liquid and an oxygen-containing compound, the oxygen-containing compound comprising one of a metal, semi-metal, metalloid, or semi-conductor.

3. The method of claim 2 , wherein the thixotropic wet gel further comprises a second plurality of components that do not form a gel.

4. The method of claim 2 , wherein the thixotropic wet gel further comprises inorganic particles, organic particles, a polymer particles, a biological particles, biomass, or a combination thereof.

5. The method of claim 1 , wherein the thixotropic wet gel comprises a liquid and organic gelating particles.

6. The method of claim 5 , wherein the organic gelating particles are pre-mixed with the liquid or a solvent.

7. The method of claim 5 , wherein the thixotropic wet gel further comprises a second plurality of components that do not form a gel.

8. The method of claim 5 , wherein the thixotropic wet gel further comprises inorganic particles, organic particles, a polymer particles, a biological particles, biomass, or a combination thereof.

9. The method of claim 1 , wherein a component of the plurality of components comprises a monomer, a polymer, a metal, an inorganic particle, an organic particle, a solvated molecule, a surfactant, an emulsion, a fiber, a foam, a biological material, a quantum dot, a magnetic material, or a combination thereof.

10. The method of claim 1 , wherein applying the shear force to the thixotropic wet gel comprises:
placing the thixotropic wet gel in a container; and
stirring the thixotropic wet gel in the container.

11. The method of claim 1 , wherein applying the shear force to the thixotropic wet gel comprises:
placing the thixotropic wet gel in a container; and
shaking or shearing the thixotropic wet gel in the container.

12. The method of claim 1 , wherein applying the shear force to the thixotropic wet gel comprises:
placing the thixotropic wet gel in a container; and
spinning or vibrating the container.

13. The method of claim 1 , wherein a component of the plurality of components in the composite gel is removed by a process comprising etching, melting, dissolution, decomposition, evaporation, sublimation, heating, or combustion.

14. A method comprising:
applying a shear force to a thixotropic wet gel to yield a thixotropic fluid, wherein the thixotropic wet gel is prepared from AlCl 3 .6H 2 O, a solution including water and ethanol, and propylene oxide;
adding a monomer solution to the thixotropic fluid while applying the shear force, thereby mixing the monomer solution with the thixotropic fluid to yield a composite thixotropic fluid;
removing the shear force from the composite thixotropic fluid; and
gelling the composite thixotropic fluid to yield a porous matrix.

15. A method comprising:
applying a shear force to a thixotropic wet gel to yield a thixotropic fluid, wherein the thixotropic wet gel is prepared from Al(OH) 3 , a solution including water and hydrochloric acid, and urea;
adding a monomer solution to the thixotropic fluid while applying the shear force, thereby mixing the monomer solution with the thixotropic fluid to yield a composite thixotropic fluid;
removing the shear force from the composite thixotropic fluid; and
gelling the composite thixotropic fluid to yield a porous matrix.

16. The method of claim 1 , wherein the porous material is in the form of monoliths.

17. The method of claim 1 , wherein the porous material is in the form of films, plates, or coatings.

18. The method of claim 1 , wherein the porous material is in the form of powder or particulates.

19. The method of claim 1 , further comprising using the porous materials as a reactant or component to form a new material.

20. A porous material formed by the method of claim 1 .

Assignees

• Seo Dong-Kyun
• Volosin Alex
• Univ Arizona

Inventors

• Seo Dong-Kyun
• Volosin Alex

Classifications

• C04B38/10

  by using foaming agents (C04B38/02 takes precedence){or by using mechanical means, e.g. adding preformed foam} · CPC title

• B01J20/28069

  Pore volume, e.g. total pore volume, mesopore volume, micropore volume · CPC title

• B01J20/26

  Synthetic macromolecular compounds · CPC title

• C04B38/04

  by dissolving-out added substances · CPC title

• B01J20/0237

  Compounds of Cu · CPC title