Heat treatment of a nanofibrillar cellulose hydrogel

Patent metadata

Field	Value
Publication number	US-10322196-B2
Application number	US-201515538441-A
Country	US
Kind code	B2
Filing date	Dec 21, 2015
Priority date	Dec 22, 2014
Publication date	Jun 18, 2019
Grant date	Jun 18, 2019

Abstract

The invention relates to a method for treating a nanofibrillar cellulose hydrogel, wherein the method comprises the steps of: providing a nanofibrillar cellulose hydrogel; and subjecting the nanofibrillar cellulose hydrogel to a heat treatment, wherein the heat treatment is carried out by transferring the nanofibrillar cellulose hydrogel through at least one heat exchanger or through at least one insulated holding tube, during which heat treatment the nanofibrillar cellulose hydrogel is kept at a predetermined temperature within the range of 110-150° C. for a period of time in the range of 15 seconds to 20 minutes, wherein the pre-determined temperature and period of time are chosen such that the number of viable micro-organisms in the nanofibrillar cellulose hydrogel is reduced by a factor of at least 10 3 .

First claim

The invention claimed is:

1. A method for treating a nanofibrillar cellulose hydrogel, wherein the method comprises the steps of:
providing a nanofibrillar cellulose hydrogel; and
subjecting the nanofibrillar cellulose hydrogel to a heat treatment, wherein the heat treatment is carried out by transferring the nanofibrillar cellulose hydrogel through at least one heat exchanger, wherein at least one of the at least one heat exchangers is a scraped surface heat exchanger, or through at least one insulated holding tube, during which heat treatment the nanofibrillar cellulose hydrogel is kept at a predetermined temperature within the range of 110-150° C. for a period of time in the range of 15 seconds to 20 minutes, wherein the pre-determined temperature and period of time are chosen such that the number of viable micro-organisms in the nanofibrillar cellulose hydrogel is reduced by a factor of at least 10 3 .

2. The method of claim 1 , wherein the step of providing a nanofibrillar cellulose hydrogel comprises providing a nanofibrillar cellulose hydrogel having a dry-matter content of at least 0.6 weight-%.

3. The method of claim 1 , wherein the step of providing a nanofibrillar cellulose hydrogel comprises providing a nanofibrillar cellulose hydrogel having a dry-matter content of at most 4 weight-%.

4. The method of claim 1 , wherein the method comprises a step of pre-heating the nanofibrillar cellulose hydrogel, during which step the nanofibrillar cellulose hydrogel is heated up to a temperature of below 100° C., before subjecting the nanofibrillar cellulose hydrogel to the heat treatment.

5. The method of claim 1 , wherein the heat treatment is carried out by transferring the nanofibrillar cellulose through at least one heat exchanger or through at least one insulated holding tube, in which the nanofibrillar cellulose hydrogel is kept at a predetermined temperature within the range of 121-145° C.

6. The method of claim 1 , wherein the method comprises, after the heat treatment, the step of cooling the nanofibrillar cellulose hydrogel to a temperature of below 30° C.

7. The method of claim 1 , wherein providing the nanofibrillar cellulose hydrogel and subjecting the nanofibrillar cellulose hydrogel to heat treatment are carried out while maintaining aseptic conditions.

8. The method of claim 1 , wherein the pre-determined temperature and period of time are chosen such that the number of viable micro-organisms in the nanofibrillar cellulose hydrogel is reduced by a factor of at least 10 6 .

9. The method of claim 1 , wherein the viscosity of the nanofibrillar cellulose hydrogel, after the heat treatment, differs at most 50% from the viscosity of the nanofibrillar cellulose hydrogel before the heat treatment, when the dry matter content of the nanofibrillar cellulose hydrogel subjected to the heat treatment is at least 0.6 weight-% and when the viscosity after the heat treatment is measured in the same dry matter content of at least 0.6 weight-%.

10. The method of claim 1 , wherein providing the nanofibrillar cellulose hydrogel comprises fibrillation of a cellulose-based raw material.

11. A system for treating a nanofibrillar cellulose hydrogel, wherein the system comprises:
a fibrillation unit for providing a nanofibrillar cellulose hydrogel, wherein the fibrillation unit is configured to fibrillate a cellulose-based raw material; and
at least one heat exchanger, wherein at least one of the at least one heat exchangers is a scraped surface heat exchanger, or at least one insulated holding tube for subjecting the nanofibrillar cellulose hydrogel to a heat treatment, wherein the heat treatment is carried out by transferring the nanofibrillar cellulose hydrogel through the at least one heat exchanger or through the at least one insulated holding tube, wherein the heat exchanger or the insulated holding tube is configured to keep the nanofibrillar cellulose hydrogel at a predetermined temperature within the range of 110-150° C. for a period of time in the range of 15 seconds to 20 minutes, wherein the pre -determined temperature and period of time are chosen such that the number of viable micro-organisms in the nanofibrillar cellulose hydrogel is reduced by a factor of at least 10 3.

12. The system of claim 11 , wherein the system comprises a heat exchanger configured to heat the nanofibrillar cellulose hydrogel up to a temperature of below 70° C. before subjecting the nanofibrillar cellulose hydrogel to the heat treatment.

13. The system of claim 11 , wherein the heat exchanger or the insulated holding tube is configured to keep the nanofibrillar cellulose hydrogel at a predetermined temperature within the range of 121-145° C.

14. The system of claim 11 , wherein, the system comprises a heat exchanger configured to cool the nanofibrillar cellulose hydrogel to a temperature of below 30° C. after the heat treatment.

15. Use of a heat treatment for reducing the number of viable micro-organisms in a nanofibrillar cellulose hydrogel, wherein the heat treatment is carried out by transferring the nanofibrillar cellulose hydrogel through at least one heat exchanger, wherein at least one of the at least one heat exchangers is a scraped surface heat exchanger, or through at least one insulated holding tube, during which heat treatment the nanofibrillar cellulose hydrogel is kept at a predetermined temperature within the range of 110-150° C. for a period of time in the range of 15 seconds to 20 minutes, wherein the pre-determined temperature and period of time are chosen such that the number of viable micro-organisms in the nanofibrillar cellulose hydrogel is reduced by a factor of at least 10 3 .

Assignees

• Upm Kymmene Corp

Inventors

• Kajanto Isko

Classifications

• A61L2400/12

  Nanosized materials, e.g. nanofibres, nanoparticles, nanowires, nanotubes; Nanostructured surfaces · CPC title

• B01J13/0069

  Post treatment · CPC title

• A61L27/20 Primary

  Polysaccharides · CPC title

• A61L2/04 Primary

  Heat (radiation A61L2/08) · CPC title

• D21H11/18 Primary

  Highly hydrated, swollen or fibrillatable fibres · CPC title