Method for suppressing increase in SO2 oxidation rate of NOx removal catalyst

Patent metadata

Field	Value
Publication number	US-9272265-B2
Application number	US-201214342862-A
Country	US
Kind code	B2
Filing date	Sep 5, 2012
Priority date	Sep 9, 2011
Publication date	Mar 1, 2016
Grant date	Mar 1, 2016

Abstract

In a NO x removal catalyst used for removing nitrogen oxides in flue gas, when a silica (Si) component as an inhibitor that causes an increase in a SO 2 oxidation rate accumulates on a surface of the catalyst, the silica component accumulating on the surface of the catalyst is dissolved, thereby regenerating the catalyst. Accordingly, the inhibitor such as the silica component covering the surface of the NO x removal catalyst can be removed, thereby enabling to provide a catalyst without having an increase in the SO 2 oxidation rate of the regenerated NO x removal catalyst.

First claim

The invention claimed is:

1. A method for suppressing an increase in a SO 2 oxidation rate of a NO x removal catalyst, comprising:
an alkali treatment step at which an inhibitor, which causes an increase in a SO 2 oxidation rate, is removed by washing with an aqueous alkaline solution, at a time of regeneration of the NO x removal catalyst; and
an activation treatment step at which activation treatment of the catalyst is performed with an acidic aqueous solution, after the alkali treatment step, wherein
a carrier of the NO x removal catalyst is titanium oxide, and the inhibitor is a silicon compound,
an intensity ratio of titanium and silicon (Si/Ti intensity ratio) on a surface of the NO x removal catalyst is obtained, and
when the Si/Ti intensity ratio exceeds a threshold of 0.1,
the alkali treatment step and the activation treatment step are performed again.

2. The method for suppressing an increase in a SO 2 oxidation rate of a NO x removal catalyst according to claim 1 , wherein
a measurement of the intensity ratio of titanium and silicon is performed by an electron probe microanalyzer (EPMA).

3. The method for suppressing an increase in a SO 2 oxidation rate of a NO x removal catalyst according to claim 1 , wherein
the aqueous alkaline solution is an aqueous solution of NaOH, KOH, Na 2 CO 3 , NaHCO 3 or K 2 CO 3 , and the acidic aqueous solution is an aqueous solution of HCl, HNO 3 , HF or H 2 SO 4 .

4. The method for suppressing an increase in a SO 2 oxidation rate of a NO x removal catalyst according to claim 1 , wherein
after washing the NO x removal catalyst, a catalytically active component is impregnated and supported in the NO x removal catalyst.

5. The method for suppressing an increase in a SO 2 oxidation rate of a NO x removal catalyst according to claim 1 , wherein
after washing the NO x removal catalyst, the NO x removal catalyst is pulverized and used as a raw material of a NO x removal catalyst.

6. The method for suppressing an increase in a SO 2 oxidation rate of a NO x removal catalyst according to claim 1 , wherein
after washing the NO x removal catalyst, a slurry raw material of a NO x removal catalyst is recoated on a surface of the NO x removal catalyst.

Assignees

• Nochi Katsumi
• Kiyosawa Masashi
• Mitsubishi Heavy Ind Ltd

Inventors

• Nochi Katsumi
• Kiyosawa Masashi

Classifications

• B01J38/64 Primary

  using alkaline material; using salts · CPC title

• B01J37/0036

  Grinding · CPC title

• B01J37/06

  Washing {(B01J37/0009, B01J37/0018 take precedence)} · CPC title

• B01J21/08

  Silica · CPC title

• B01D2255/20769

  Molybdenum · CPC title