Regeneration of catalyst for hydrogenation of sugars

Patent metadata

Field	Value
Publication number	US-9687839-B2
Application number	US-201615223401-A
Country	US
Kind code	B2
Filing date	Jul 29, 2016
Priority date	May 24, 2012
Publication date	Jun 27, 2017
Grant date	Jun 27, 2017

Abstract

A process for regenerating catalysts that have been deactivated or poisoned during hydrogenation of biomass, sugars and polysaccharides is described, in which polymerized species that have agglomerated to catalyst surfaces can be removed by means of washing the catalyst with hot water at subcritical temperatures. A feature of the process can regenerate the catalysts in situ, which allows the process to be adapted for used in continuous throughput reactor systems. Also described is a continuous hydrogenation process that incorporated the present regeneration process.

First claim

I claim:

1. A method of regenerating hydrogenation catalyst activity in-situ, the method comprising: a) providing a hydrogenation reactor for carbohydrates, said reactor being configured to have at least a first and a second vessel, said first vessel having a first catalyst and said second vessel having a second catalyst, said first and second catalysts being either the same or of a different material, said first and second vessels are arranged either in serial communication or in parallel communication with each other; and b) rinsing each respective vessel and catalyst with subcritical deionized water of between about 130° C.-250° C. for an extended period.

2. The method according to claim 1 , wherein said method further comprises: introducing a subcritical deionized aqueous solution containing H 2 O 2 in a concentration of ≦7% by volume to said first catalyst in said first vessel of said reactor when catalytic activity of said first catalyst decreases to a predetermined level; or introducing periodically an aqueous salt solution to either 1) said first catalyst in first vessel or 2) said second catalyst when catalytic activity of said second catalyst decreases to a predetermined level; removing respectively said aqueous H 2 O 2 solution from said first vessel and said aqueous salt solution from said first or second vessels of said reactor.

3. The method according to claim 1 , wherein said first or second catalyst is a sponge matrix catalyst.

4. The method according to claim 3 , wherein a metal of said first catalyst is Ni.

5. The method according to claim 3 , wherein a metal of said second catalyst is selected from Ru, Pt, and Pd.

6. The method according to claim 2 , wherein said aqueous H 2 O 2 solution is applied to said first catalyst in first vessel once for each 1-8 applications of aqueous salt solution applied to said second catalyst in second vessel.

7. The method according to claim 1 , wherein a degree of polymerization is reduced by at least 80%, relative to an untreated catalyst.

8. The method according to claim 1 , wherein a degree of polymerization is reduced by at least 85%, relative to an untreated catalyst.

9. The method according to claim 2 , wherein said catalytic activity of either said first catalyst or said second catalyst is restored to about 75% or greater of an initial catalytic activity level for each catalyst.

10. The method according to claim 1 , wherein said predetermined level of catalytic activity of either said first catalyst or second catalyst is ≦75% of an initial catalytic activity level for each catalyst.

Assignees

• Archer Daniels Midland Co
• Archer Daniels Midland Co

Inventors

• Ma Chicheng

Classifications

• B01J25/04

  Regeneration or reactivation · CPC title

• B01J23/96

  of catalysts comprising metals, oxides or hydroxides of the noble metals · CPC title

• B01J25/02

  Raney nickel · CPC title

• B01J38/64

  using alkaline material; using salts · CPC title

• C07C5/10

  of aromatic six-membered rings · CPC title