Vaporization and transportation of alkali metal salts

Patent metadata

Field	Value
Publication number	US-10005046-B2
Application number	US-201314088108-A
Country	US
Kind code	B2
Filing date	Nov 22, 2013
Priority date	Apr 22, 2008
Publication date	Jun 26, 2018
Grant date	Jun 26, 2018

Abstract

An apparatus and method for vaporizing and transporting an alkali metal salt is shown. The apparatus has a first conduit capable of transporting an alkali metal salt solution and a second conduit in fluid communication with the first conduit, the second conduit capable of transporting steam so that the alkali metal salt is dissipated into the steam forming a solution that can be transported, such as to a remote reaction zone. The solution can be transported via a third conduit that is capable of being heated by a heat source. The method can be used to add a promoter to a dehydrogenation catalyst during a dehydrogenation reaction.

First claim

What is claimed is:

1. An apparatus for vaporizing an alkali metal salt into steam, comprising:
a first conduit capable of transporting a first stream of an alkali metal salt solution, the first conduit having at least one opening through which the first stream can exit the first conduit;
a second conduit in fluid communication with the first conduit, wherein the second conduit is capable of transporting a second stream comprising steam;
wherein as the first stream exits the first conduit it is dissipated into the second stream forming a third stream comprising a vaporized alkali metal salt solution, the vaporized alkali metal salt solution comprising the alkali metal solution vaporized in solution with the steam from the second stream, wherein the portion of the first conduit containing the at least one opening is disposed within a mixing chamber;
a third conduit in fluid communication with the mixing chamber, wherein the third conduit is capable of being heated by a heat source, wherein the vaporized alkali metal salt solution is formed in the mixing chamber prior to the third stream entering the third conduit;
wherein the third conduit is capable of transporting the third stream, and wherein the third conduit is connected to a fourth conduit for transporting the third stream into a fourth stream within the fourth conduit; and
a weir located adjacent to the connection of the third conduit to the fourth conduit to restrict the flow of any of the alkali metal that is not dissipated into the second stream from entering the fourth conduit.

2. The apparatus of claim 1 , further comprising at least one diffuser located adjacent to the at least one opening of the first conduit to dissipate the first stream into the second stream.

3. The apparatus of claim 1 , wherein the mixing chamber is heated by a heat source.

4. The apparatus of claim 3 , wherein the heat source is a steam jacket.

5. The apparatus of claim 1 , wherein the portion of the first conduit containing the at least one opening is disposed within the mixing chamber in a substantially concentric arrangement.

6. The apparatus of claim 1 , wherein the heat source is a steam jacket.

7. The apparatus of claim 1 , wherein the heat source comprises a first heat source configured to heat the second conduit, a second heat source configured to heat the third conduit, or combinations thereof.

8. The apparatus of claim 1 , wherein the heat source comprises a heat exchanger, an electrical heating element, a radiative heat source, or combinations thereof.

9. The apparatus of claim 1 , wherein the fourth conduit comprises a dehydrogenation catalyst.

10. The apparatus of claim 1 , further comprising a fifth conduit in fluid communication with the third conduit.

11. The apparatus of claim 10 , further comprising a sixth conduit in fluid communication with the third conduit.

12. An apparatus for enhancing an activity of a dehydrogenation catalyst promoted with an alkali metal during a catalytic dehydrogenation reaction, comprising:
a first conduit capable of transporting a first stream;
a second conduit in fluid communication with the first conduit, wherein the second conduit is capable of transporting a second stream, and wherein an opening of the first conduit is configured to dissipate the first stream into the second stream in a countercurrent flow pattern to form a third stream, wherein the portion of the first conduit containing the at least one opening is disposed within a mixing chamber;
a third conduit in fluid communication with the mixing chamber, wherein the third conduit is downstream from the first conduit and the second conduit, wherein the third stream is formed in the mixing chamber prior to the third stream entering the third conduit;
a first heat source capable of heating the third conduit, and optionally a second heat source capable of heating the second conduit;
a fourth conduit in fluid communication with the third conduit, wherein the fourth conduit is downstream from the third conduit; and
a weir located adjacent to the connection of the third conduit to the fourth conduit.

13. The apparatus of claim 12 , wherein the fourth conduit comprises the dehydrogenation catalyst.

14. The apparatus of claim 12 , further comprising a fifth conduit in fluid communication with the third conduit, wherein the fifth conduit is upstream from the fourth conduit and downstream from the first conduit and the second conduit.

15. The apparatus of claim 14 , further comprising a sixth conduit in fluid communication with the third conduit, wherein the sixth conduit is upstream from the fourth conduit and downstream from the first conduit and the second conduit.

16. The apparatus of claim 12 , further comprising a diffuser located adjacent to the opening of the first conduit to dissipate the first stream into the second stream.

17. The apparatus of claim 12 , wherein the portion of the first conduit containing the opening is disposed within the second conduit, wherein the second conduit comprises the mixing chamber, and wherein the first stream is dissipated into the second stream to form the third stream prior to the third stream entering the third conduit.

18. The apparatus of claim 17 , wherein the mixing chamber is capable of being heated by the second heat source.

19. The apparatus of claim 12 , wherein each heat source comprises a steam jacket, a heat exchanger, an electrical heating element, or a radiative heat source.

20. The apparatus of claim 12 , wherein the portion of the first conduit containing the opening is disposed within the second conduit in a substantially concentric arrangement.

21. The apparatus of claim 12 , wherein the first stream comprises an alkali metal salt solution, the second stream comprises steam, and the third stream comprises the alkali metal salt in solution with the steam.

Assignees

• Fina Technology

Inventors

• Pelati Joseph E
• Butler James R
• Craig Hollie

Classifications

• B01J38/64

  using alkaline material; using salts · CPC title

• B01J4/001

  Feed or outlet devices as such, e.g. feeding tubes · CPC title

• C07C5/32

  by dehydrogenation with formation of free hydrogen · CPC title

• B01J38/06

  using steam · CPC title

• B01D7/00

  Sublimation (B01D8/00 takes precedence; freeze-drying F26) · CPC title