Ceria-based composition including bismuth oxide, ceria-based composite electrolyte powder including bismuth oxide, method for sintering the same and sintered body made thereof

Patent metadata

Field	Value
Publication number	US-9252448-B2
Application number	US-201313929954-A
Country	US
Kind code	B2
Filing date	Jun 28, 2013
Priority date	Jun 29, 2012
Publication date	Feb 2, 2016
Grant date	Feb 2, 2016

Abstract

Provided are a ceria-based composition having an undoped or metal-doped ceria and an undoped or metal-doped bismuth oxide, wherein the undoped or metal-doped bismuth oxide is present in an amount equal to or more than about 10 wt % and less than about 50 wt % based on the total weight of the ceria-based composition, and at least one selected from the ceria and the bismuth oxide is metal-doped. The ceria-based composition may ensure high sintering density even at a temperature significantly lower than the known sintering temperature of about 1400° C., i.e., for example at a temperature of about 1000° C. or lower, and increase ion conductivity as well.

First claim

What is claimed is:

1. A sintered body of a ceria-based composition, the ceria-based composition comprising an undoped ceria or a metal-doped ceria; and an undoped bismuth oxide or a metal-doped bismuth oxide,
wherein the ceria-based composition comprises at least one selected from the group consisting of the metal-doped ceria and the metal-doped bismuth oxide; and the metal doped ceria and/or the metal-doped bismuth oxide comprises a doping metal at a concentration between 10 wt % and 30 wt % with respect to the metal-doped ceria and/or the metal-doped bismuth oxide; and
the undoped bismuth oxide or the metal-doped bismuth oxide is present in an amount more than 10 wt % and less than 50 wt % based on the total weight of the ceria-based composition, and
the doping metal is at least one selected from the group consisting of samarium, gadolinium, lanthanum, zirconium, yttrium, ytterbium, erbium, praseodymium, neodymium, and combinations thereof,
wherein the sintered body comprises ceria grains and bismuth oxide present at grain boundaries surrounding the ceria grains, wherein the doping metal is present in the grains and the grain boundaries.

2. The sintered body according to claim 1 , wherein the bismuth oxide or the metal-doped bismuth oxide is present in an amount of 10 wt % to 30 wt % based on the total weight of the ceria-based composition.

3. The sintered body according to claim 1 , wherein the bismuth oxide or the metal-doped bismuth oxide is present in an amount more than 15 wt % and equal to or less than 25 wt % based on the total weight of the ceria-based composition.

4. The sintered body according to claim 1 , wherein the bismuth oxide or the metal-doped bismuth oxide is present in an amount of 20 wt % to 25 wt % based on the total weight of the ceria-based composition.

5. The sintered body according to claim 1 , wherein the ceria-based composition consists essentially of the metal-doped ceria and the undoped bismuth oxide.

6. The sintered body according to claim 5 , wherein the ceria-based composition consists essentially of a samarium-doped ceria and the undoped bismuth oxide.

7. The sintered body according to claim 6 , wherein the samarium-doped ceria is Sm 0.2 Ce 0.6 O 2 .

8. The sintered body according to claim wherein the doping metal is at least one selected from the group consisting of lanthanum, zirconium, yttrium, ytterbium, erbium, praseodymium, neodymium, and combinations thereof.

9. A method of preparing a sintered body, the method comprising:
mixing together an undoped ceria or a metal-doped ceria; and an undoped bismuth oxide or a metal-doped bismuth oxide; to form a ceria-bismuth powder,
wherein the ceria-bismuth powder comprises at least one selected from the group consisting of the metal-doped ceria and the metal-doped bismuth oxide,
wherein the metal-doped ceria and/or the metal-doped bismuth oxide comprises a doping metal at a concentration between about 10 wt % and about 30 wt % with respect to the metal-doped ceria and/or the metal-doped bismuth oxide,
wherein the undoped bismuth oxide or the metal-doped bismuth oxide is present in an amount more than 10 wt % and less than 50 wt % based on the total weight of the ceria-bismuth powder,
wherein the doping metal is selected from the group consisting of samarium, gadolinium, lanthanum, zirconium, yttrium, ytterbium, erbium, praseodymium, neodymium, and combinations thereof; and

sintering the mixed together ceria-bismuth powder at temperatures between about 800° C. to about 1000° C. to form the sintered body,
wherein the sintered body comprises ceria grains and bismuth oxide present at grain boundaries surrounding the ceria grains, wherein the doping metal is present in the grains and the grain boundaries.

10. The method according to claim 9 , wherein the method further comprises:
molding an anode powder into an anode support wherein the anode powder comprises a metal powder mixed with an amount of the ceria-bismuth powder;
coating the anode support with an electrolyte slurry made from the ceria-bismuth powder to coat the anode support with an electrolyte coat;
layering a cathode slurry onto the electrolyte coated on the anode support; and
sintering in-situ the anode support coated with the electrolyte coat and layered with the cathode slurry at temperatures between about 800° C. to about 1000° C.

11. The method according to claim 9 , further comprising calcining, prior to sintering, the ceria-bismuth powder between about 300° C. to about 800° C.

12. The method according to claim 9 , wherein the ceria-bismuth powder consists essentially of the metal-doped ceria and the undoped bismuth oxide.

13. The method according to claim 9 , wherein the ceria-bismuth powder consists essentially of Sm 0.2 Ce 0.8 O 2 and Bi 2 O 3 , and the sintered body comprises Bi 0.775 Sm 0.225 O 1.5 .

14. The method according to claim 9 , wherein the ceria-bismuth powder is charged to a fuel cell without sintering, and then is sintered in-situ during an operation of the fuel cell.

Assignees

• Korea Inst Sci & Tech

Inventors

• Yoon Sung Pil
• Han Jonghee
• Song Shin Ae
• Lim Tae Hoon
• Kim Hyoung-Juhn
• Jang Jong Hyun
• Henkensmeier Dirk
• Cho Eun Ae
• Nam Suk Woo
• Hong Seong Ahn
• Cam-Anh Thieu

Classifications

• Y02E60/50

  Fuel cells · CPC title

• C04B35/62685

  characterised by the order of addition of constituents or additives · CPC title

• Y02E60/525

  Cross-Sectional Technologies · mapped topic

• C04B2235/3244

  Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof · CPC title

• C04B2235/3227

  Lanthanum oxide or oxide-forming salts thereof · CPC title