Technique for designing and manufacturing solid oxide fuel cell having improved output capability in mid to low temperature

Patent metadata

Field	Value
Publication number	US-9318766-B2
Application number	US-201214377109-A
Country	US
Kind code	B2
Filing date	Nov 20, 2012
Priority date	Feb 27, 2012
Publication date	Apr 19, 2016
Grant date	Apr 19, 2016

Abstract

The present invention relates to a technique for manufacturing a unit cell for a solid oxide fuel cell (SOFC) which can improve the output of the unit cell of the solid oxide fuel cell, without occurring cost due to an additional process. The unit cell of the solid oxide fuel cell, comprises: a fuel electrode support body; a fuel electrode reaction layer; an electrolyte; and an air electrode, wherein the fuel electrode support body is made from an NiO and YSZ mixed material, the fuel electrode reaction layer is made from a CeScSZ and NiO mixed material, the electrolyte is made from a CeCsSZ material, and wherein the air electrode is made from an LSM and CeScSZ mixed material.

First claim

What is claimed is:

1. A unit cell of a solid oxide fuel cell comprising:
an anode supporter formed of a mixture of Nickel(II) oxide (NiO) and Yttria-stabilized zirconia (YSZ);
an anode reaction layer formed of a mixture of Cerium Scandia Stabilized Zirconia (CeScSZ) and NiO;
an electrolyte formed of CeScSZ; and
a cathode formed of a mixture of Lanthanum strontium cobalt (LSM) and CeScSZ.

2. The unit cell of claim 1 , wherein the anode reaction layer, the electrolyte, and the cathode comprise 1Ce10ScSZ powder.

3. The unit cell of claim 1 , wherein the anode supporter, the anode reaction layer and the electrolyte are manufactured by stacking and cofiring a film manufactured by tape casting.

4. The unit cell of claim 3 , wherein the cathode is manufactured by screen printing.

5. The unit cell of claim 3 , wherein the anode reaction layer is manufactured by mixing a NiO powder and a CeScSZ powder at 46:54% by weight (wt %).

6. The unit cell of claim 5 , wherein the NiO powder has a size of 0.5 micrometers (μm), and the CeScSZ powder has a size of 0.2 to 0.5 um and a specific surface area of 11 square meters/gram (m 2 /g).

7. The unit cell of claim 3 , wherein the electrolyte is manufactured by mixing the CeScSZ powder and a solvent at 40:60 wt %.

8. The unit cell of claim 7 , wherein the CeScSZ powder has a size of 0.2 to 0.5 μm and a specific surface area of 11 m 2 /g.

9. The unit cell of claim 3 , wherein the cathode is manufactured by mixing LSM powder and CeScSZ powder at a weight ratio 1:1 (wt %).

10. A method of manufacturing a unit cell of a solid oxide fuel cell, the method comprising:
preparing an anode supporter slurry by mixing Nickel(II) oxide (NiO) powder and Yttria-stabilized zirconia (YSZ) powder;
preparing an anode reaction layer slurry by mixing Cerium Scandia Stabilized Zirconia (CeScSZ) powder and NiO powder;
preparing an electrolyte slurry using CeScSZ powder;
manufacturing an anode supporter sheet using the anode supporter slurry by tape casting;
manufacturing an anode reaction layer sheet using the anode reaction layer slurry by tape casting;
manufacturing an electrolyte sheet using the electrolyte slurry by tape casting;
manufacturing an anode supporter-electrolyte assembly by sequentially stacking the anode supporter sheet, the anode reaction layer sheet and the electrolyte sheet;
manufacturing an anode supporter-electrolyte by calcining and cofiring the anode supporter-electrolyte assembly;
preparing cathode paste by mixing Lanthanum strontium cobalt (LSM) powder and CeScSZ powder;
applying the cathode paste to the anode supporter-electrolyte by screen printing; and
performing sintering.

11. The method of claim 10 , wherein the anode reaction layer slurry, the electrolyte slurry, and the cathode paste comprise 1Ce10ScSZ powder.

12. The method of claim 11 , wherein the anode reaction layer slurry is manufactured by mixing the NiO powder and the CeScSZ powder at 46:54% by weight (wt %).

13. The method of claim 12 , wherein the NiO powder has a size of 0.5 μm, and the CeScSZ powder has a size of 0.2 to 0.5 micrometers (μm) and a specific surface area of 11 square meters/gram (m 2 /g).

14. The method of claim 11 , wherein the electrolyte slurry is prepared by mixing the CeScSZ powder and a solvent at 40:60 wt %.

15. The method of claim 14 , wherein the CeScSZ, powder has a size of 0.2 to 0.5 μm and a specific surface area of 11 m 2 /g.

16. The method of claim 11 , wherein the cathode paste is prepared by mixing the LSM powder and the CeScSZ powder at a weight ratio 1:1 (wt %).

17. The method of claim 10 , wherein the manufacturing of the anode supporter-electrolyte assembly stacks the anode supporter sheet, the anode reaction layer sheet and the electrolyte sheet alternately in a first direction and a second direction perpendicular to the first direction.

18. The method of claim 10 , wherein the manufacturing of the anode supporter-electrolyte mounts a flat alumina ceramic supporter with a fixed size and weight on the anode supporter-electrolyte assembly and conducts cofiring at 1,350° C. while exerting a force of about 40 kilograms/square centimeter (kg/cm 2 ).

Assignees

• Korea Ind Tech Inst

Inventors

• Kim Ho Sung
• Kang Ju Hee
• Kim Hyo Sin
• Jo Jin Hun
• Kim Yeong Mok
• Heo Sang Hun
• Kim Tae Won

Classifications

• Y02P70/50

  Manufacturing or production processes characterised by the final manufactured product · CPC title

• Y02E60/50

  Fuel cells · CPC title

• Y02E60/525

  Cross-Sectional Technologies · mapped topic

• H01M8/1226

  characterised by the supporting layer · CPC title

• H01M2300/0077

  based on zirconium oxide · CPC title