Stretch releasable adhesive tape

Patent metadata

Field	Value
Publication number	US-9238758-B2
Application number	US-201414167443-A
Country	US
Kind code	B2
Filing date	Jan 29, 2014
Priority date	Mar 14, 2008
Publication date	Jan 19, 2016
Grant date	Jan 19, 2016

Abstract

An adhesive tape that is stretch releasable, articles that contain the adhesive tape, and uses of the adhesive tape are disclosed. The adhesive tapes include a backing layer that is adjacent to at least one pressure-sensitive adhesive layer. The backing layer typically is optically clear and includes a poly(alkylene) copolymer. The pressure-sensitive adhesive layer is a silicone-based adhesive composition. In many embodiments, the adhesive tape is optically clear.

First claim

We claim:

1. An adhesive article comprising:
a backing layer comprising a poly(alkylene) copolymer; and
a first pressure-sensitive adhesive layer adjacent to a first major surface of the backing layer, the pressure-sensitive adhesive layer comprising a polydiorganosiloxane polyoxamide block copolymer,

wherein the adhesive article is stretchable at least 50 percent in a first direction without breaking.

2. The adhesive article of claim 1 , wherein the polydiorganosiloxane polyoxamide block copolymer is crosslinked.

3. The adhesive article of claim 1 , wherein the first pressure-sensitive adhesive layer further comprises a tackifying resin.

4. The adhesive article of claim 3 , wherein the first pressure-sensitive adhesive layer comprises (a) 30 to 90 weight percent polydiorganosiloxane polyoxamide block copolymer and (b) 10 to 70 weight percent tackifying resin.

5. The adhesive article of claim 4 , wherein the tackifying resin comprises a silicone tackifying resin.

6. The adhesive article of claim 1 , further comprising a second pressure-sensitive adhesive layer adjacent to a second major surface of the backing layer.

7. The adhesive article of claim 6 , wherein the second pressure-sensitive adhesive layer comprises a polydiorganosiloxane polyoxamide block copolymer.

8. The adhesive article of claim 1 , wherein the first pressure-sensitive adhesive layer is adhered to a first substrate.

9. The adhesive article of claim 6 , wherein the first pressure-sensitive adhesive layer is adhered to a first substrate and the second pressure-sensitive adhesive layer is adhered to a second substrate.

10. The adhesive article of claim 8 , wherein the first pressure-sensitive adhesive layer comprises (a) 30 to 90 weight percent polydiorganosiloxane polyoxamide block copolymer and (b) 10 to 70 weight percent tackifying resin.

11. The adhesive article of claim 9 , wherein each of the first pressure-sensitive adhesive layer and the second pressure-sensitive adhesive layer comprises (a) 30 to 90 weight percent polydiorganosiloxane polyoxamide block copolymer and (b) 10 to 70 weight percent tackifying resin.

12. The adhesive article of claim 1 , wherein the poly(alkylene) copolymer comprises
a polymerized product of a reaction mixture comprising
(1) a first alkene selected from ethene, propene, or a mixture thereof; and
(2) a second alkene selected from a 1,2-alkene having 4 to 8 carbon atoms; and
(3) a metallocene catalyst.

13. The adhesive article of claim 1 , wherein the polydiorganosiloxane polyoxamide block copolymer comprises at least two repeat units of Formula (III)

wherein
each R 1 is independently an alkyl, haloalkyl, alkenyl, aralkyl, aryl, or aryl substituted with an alkyl, alkoxy, or halo;
each Y is independently an alkylene, an aralkylene, an arylene, or a combination thereof; and
G is a residual unit that is equal to a diamine compound of formula R 3 HN-G-NHR 3 minus the two amino groups of formula —NHR 3 ;
each R 3 is hydrogen, alkyl, or taken together with G and with the nitrogen to which both R 3 and G are attached formed a heterocyclic group;
n is an integer in a range of 40 to 1500;
p is an integer in a range of 1 to 10; and
each asterisk (*) indicates a site of attachment of the repeat unit to another group in the copolymer.

14. The adhesive article of claim 1 , wherein the polydiorganosiloxane polyoxamide block copolymer comprises greater than 50 weight percent polydiorganosiloxane segments based on the total weight of the polydiorganosiloxane polyoxamide block copolymer.

15. The adhesive article of claim 1 , wherein the polydiorganosiloxane polyoxamide block copolymer comprises greater than 90 weight percent polydiorganosiloxane segments based on the total weight of the polydiorganosiloxane polyoxamide block copolymer.

16. The adhesive article of article 9 , wherein at least one of the first substrate or the second substrate is selected from a display, polarizer, touch panel, lens, reflector, diffraction grating, mirror, projection prism, or multilayer optical film.

17. The adhesive article of claim 1 , wherein the backing layer has a thickness that varies by less than 10 percent in any direction.

18. The adhesive article of claim 1 , wherein the backing layer is free or substantially free of an anti-blocking agent, a slip agent, or both.

19. The adhesive article of claim 6 , wherein the second pressure-sensitive adhesive layer and the first pressure-sensitive adhesive layer have different adhesive strength.

20. The adhesive article of claim 9 , wherein the second substrate can be seen when viewed through the first substrate, the first pressure-sensitive adhesive layer, the backing, and the second pressure-sensitive adhesive layer.

21. The adhesive article of claim 1 , wherein the article is a tape.

Assignees

• 3M Innovative Properties Co

Inventors

• Determan Michael D
• Everaerts Albert I
• Purgett Mark D
• Tran Thu-Van T
• Bries James L
• Emslander Jeffrey O
• Seth Jayshree

Classifications

• C09J183/10 Primary

  Block or graft copolymers containing polysiloxane sequences (obtained by polymerising a compound having a carbon-to-carbon double bond on to a polysiloxane C09J151/08, C09J153/00) · CPC title

• C09J2483/00

  Presence of polysiloxane · CPC title

• Y10T428/1476

  Release layer · CPC title

• Y10T428/2852

  Adhesive compositions · CPC title

• Y10T428/24752

  Laterally noncoextensive components · CPC title