Hydrogen generator

Patent metadata

Field	Value
Publication number	US-9162203-B1
Application number	US-201113049510-A
Country	US
Kind code	B1
Filing date	Mar 16, 2011
Priority date	Mar 16, 2011
Publication date	Oct 20, 2015
Grant date	Oct 20, 2015

Abstract

A hydrogen generator into which a mixed gas is run and out of which a reformed gas including hydrogen is discharged, which can reliably control the hydrogen concentration in the reformed gas to a desired concentration. The hydrogen generator is provided with an upstream side oxidation unit and a downstream side decomposition unit, burns part of the compound in the mixed gas in the oxidation unit using the oxygen in the mixed gas so as to generate heat of combustion, and uses the heat of combustion to break down another part of the compound in the mixed gas in the decomposition unit so as to generate hydrogen. The hydrogen generator is provided with a first temperature sensor controller.

First claim

The invention claimed is:

1. A hydrogen generator into which a mixed gas is run and out of which a reformed gas including hydrogen is discharged, the mixed gas including a mixture of a compound containing hydrogen atoms and oxygen or air, the hydrogen generator comprising:
an upstream side oxidation unit,
a downstream side decomposition unit,
a first temperature sensor which detects a temperature of the mixed gas immediately after passing through the upstream side oxidation unit, the first temperature sensor being disposed in a space located between the upstream side oxidation unit and the downstream side decomposition unit, the space being a place where the upstream side oxidation unit and the downstream side decomposition unit do not exist,
a flow rate controller, and
an electronic control unit that controls the flow rate controller,
wherein the oxygen of the mixed gas burns part of the compound in the mixed gas in the upstream side oxidation unit so as to generate heat of combustion, and the heat of combustion is used to break down another part of the compound in the mixed gas in the downstream side decomposition unit to generate hydrogen, and
the electronic control unit, through controlling the flow rate controller, controls at least one of a flow rate of the compound contained in the mixed gas flowing into the hydrogen generator and a flow rate of the oxygen or the air contained in the mixed gas so that the temperature of the mixed gas detected by the first temperature sensor is maintained substantially constant at a set temperature, the set temperature being a temperature at which the hydrogen concentration of the reformed gas becoming a predetermined concentration, the set temperature being preset in the electronic control unit.

2. The hydrogen generator as set forth in claim 1 , wherein the electronic control unit, through controlling the flow rate controller, increases the flow rate of the oxygen or air when the temperature of the mixed gas detected by the first temperature sensor is lower than the set temperature, and decreases the flow rate of the oxygen or air when the temperature of the mixed gas detected by the first temperature sensor is higher than the set temperature.

3. The hydrogen generator as set forth in claim 2 , further comprising a second temperature sensor that detects a temperature in the downstream side decomposition unit at a downstream side from the first temperature sensor,
wherein it is determined that the upstream side oxidation unit has deteriorated when the temperature in the downstream side decomposition unit detected by the second temperature sensor is higher than the temperature of the mixed gas detected by the first temperature sensor.

4. The hydrogen generator as set forth in claim 2 , further comprising a third temperature sensor that detects a temperature of the reformed gas immediately after passing through the downstream side decomposition unit,
wherein it is determined that the downstream side decomposition unit has deteriorated when the temperature difference between the temperature of the mixed gas detected by the first temperature sensor and the temperature of the reformed gas detected by the third temperature sensor is a set temperature difference or less.

5. The hydrogen generator as set forth in claim 4 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

6. The hydrogen generator as set forth in claim 2 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

7. The hydrogen generator as set forth in claim 3 , further comprising a third temperature sensor that detects a temperature of the reformed gas immediately after passing through the downstream side decomposition unit,
wherein it is determined that the downstream side decomposition unit has deteriorated when the temperature difference between the temperature of the mixed gas detected by the first temperature sensor and the temperature of the reformed gas detected by the third temperature sensor is a set temperature difference or less.

8. The hydrogen generator as set forth in claim 3 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

9. The hydrogen generator as set forth in claim 7 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

10. The hydrogen generator as set forth in claim 1 , further comprising a second temperature sensor that detects a temperature in the downstream side decomposition unit at a downstream side from the first temperature sensor,
wherein it is determined that the upstream side oxidation unit has deteriorated when the temperature in the downstream side decomposition unit detected by the second temperature sensor is higher than the temperature of the mixed gas detected by the first temperature sensor.

11. The hydrogen generator as set forth in claim 10 , further comprising a third temperature sensor that detects a temperature of the reformed gas immediately after passing through the downstream side decomposition unit,
wherein it is determined that the downstream side decomposition unit has deteriorated when the temperature difference between the temperature of the mixed gas detected by the first temperature sensor and the temperature of the reformed gas detected by the third temperature sensor is a set temperature difference or less.

12. The hydrogen generator as set forth in claim 10 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

13. The hydrogen generator as set forth in claim 11 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

14. The hydrogen generator as set forth in claim 1 , further comprising a third temperature sensor that detects a temperature of the reformed gas immediately after passing through the downstream side decomposition unit,
wherein it is determined that the downstream side decomposition unit has deteriorated when the temperature difference between the temperature of the mixed gas detected by the first temperature sensor and the temperature of the reformed gas detected by the third temperature sensor is a set temperature difference or less.

15. The hydrogen generator as set forth in claim 14 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

16. The hydrogen generator as set forth in claim 1 , wherein the compound is ammonia and the set temperature is 1200° C. or less.

17. The hydrogen generator as set forth in claim 16 , wherein the set temperature is 800° C.

Assignees

• Miyagawa Hiroshi
• Koike Makoto
• Yamazaki Kiyoshi
• Toh Keiji
• Matsumoto Shohei
• Sugimoto Tomojiro
• Shimizu Rioh
• Kojima Susumu
• Toyota Chuo Kenkyusho Kk

Inventors

• Miyagawa Hiroshi
• Koike Makoto
• Yamazaki Kiyoshi
• Toh Keiji
• Matsumoto Shohei
• Sugimoto Tomojiro
• Shimizu Rioh
• Kojima Susumu

Classifications

• B01J8/0438 Primary

  the beds being placed next to each other · CPC title

• B01J8/04 Primary

  the fluid passing successively through two or more beds · CPC title

• C01B3/047

  Decomposition of ammonia · CPC title

• Y02E60/36

  Hydrogen production from non-carbon containing sources, e.g. by water electrolysis · CPC title

• B01J2208/00061

  of the reactants · CPC title