Alcohol reformer for reforming alcohol to mixture of gas including hydrogen

Patent metadata

Field	Value
Publication number	US-10450193-B2
Application number	US-201314389683-A
Country	US
Kind code	B2
Filing date	Mar 29, 2013
Priority date	Mar 30, 2012
Publication date	Oct 22, 2019
Grant date	Oct 22, 2019

Abstract

Reforming alcohol is disclosed. Alcohol is introduced into a conduit of an alcohol reformer so that the alcohol flows through a catalyst stage within the conduit. The catalyst stage includes an alcohol reforming catalyst, and a heat transfer member comprising thermally conductive material. The heat transfer member is in thermal contact with the conduit and the alcohol reforming catalyst. Simultaneously, exhaust gas is introduced from an internal combustion engine into an exhaust channel. The exhaust gas in the exhaust channel contacts fins extending outward from the conduit so that heat from the exhaust gas is transferred through the fins, the conduit, and the heat transfer member to the alcohol reforming catalyst.

First claim

What is claimed is:

1. An alcohol reformer comprising:
a conduit having an axis and including a wall having an exterior surface and an interior surface at least partially defining an interior chamber through which alcohol vapor flows along an alcohol flow path, the conduit wall comprising a thermally conductive material;
a plurality of fins extending generally radially outward from the exterior surface of the conduit wall, the fins comprising thermally conductive material, wherein the fins and the conduit wall are in thermal contact;
a catalyst stage in the interior chamber of the conduit having a length extending along the axis, wherein the catalyst stage is configured to allow alcohol vapor to flow through the catalyst stage along the alcohol flow path, the catalyst stage including
an alcohol reforming catalyst, and
a heat transfer member comprising thermally conductive material, wherein the heat transfer member is in thermal and physical contact with the conduit wall and the alcohol reforming catalyst along the length of the catalyst stage, whereby heat is transferable from the plurality of fins to the alcohol reforming catalyst along the length of the catalyst stage to enable reforming of the alcohol vapor as it flows through the catalyst stage;

a reheat stage in the interior chamber of the conduit and configured to allow alcohol vapor to flow through the reheat stage along the alcohol flow path, the reheat stage comprising a second heat transfer member, wherein the second heat transfer member is in thermal contact with the conduit wall, whereby heat is transferable from the plurality of fins to the second heat transfer member to enable heating of the alcohol vapor as it flows through the reheat stage;
a baffle disposed in the interior chamber of the conduit between the catalyst stage and the reheat stage, the baffle configured to direct the alcohol vapor through the catalyst stage in a first direction and direct the alcohol vapor through the reheat stage in a second direction that is opposite the first direction.

2. The alcohol reformer set forth in claim 1 , wherein the heat transfer member of the catalyst stage comprises at least one of metal wool, foam, and mesh.

3. The alcohol reformer set forth in claim 1 , wherein the reforming catalyst comprises at least one of copper-plated metal sponge, copper-plated palladium or platinum on carbon pellets, or a combination thereof.

4. The alcohol reformer set forth in claim 1 , wherein the conduit includes a plurality of conduits arranged side-by-side in at least one bank in the alcohol flow path.

5. The alcohol reformer set forth in claim 4 , wherein said at least one bank includes at least first and second banks of conduits, wherein the first bank is upstream of the second bank along the alcohol flow path.

6. The alcohol reformer set forth in any of claims 5 in combination with a reformer housing defining a generally horizontal exhaust channel through which exhaust gas flows along an exhaust gas path, wherein the alcohol reformer is received in the exhaust channel such that the interior chamber of the conduit is sealed from the exhaust channel and exhaust gas flowing through the exhaust channel is in thermal contact with the fins.

7. The alcohol reformer set forth in claim 6 , wherein the conduits of the first and second banks are oriented generally vertically in the exhaust channel and the alcohol flow path through the conduits in each of the first and second banks is in one of a downflow direction and an upflow direction.

8. The alcohol reformer set forth in claim 7 , wherein the alcohol flow path through the conduits in the first bank is in the upflow direction, and wherein the alcohol flow path through the conduits in the second bank is in the upflow direction.

9. The alcohol reformer set forth in claim 8 , wherein the reformer housing at least partially defines first lower inlet plenum supplying alcohol vapor to the first bank of conduits, a first upper outlet plenum receiving alcohol vapor from the conduits of the first bank, a shunt conduit in fluid communication with the first upper outlet plenum for receiving alcohol vapor from the first upper outlet plenum, a second lower inlet plenum in fluid communication with shunt conduit for receiving alcohol vapor from the shunt conduit, and a second upper outlet plenum for receiving alcohol vapor from the conduits of the second bank.

10. The alcohol reformer set forth in claim 7 , wherein the alcohol flow path through the conduits in the first bank is in a direction opposite a direction of the alcohol flow path through the conduits in the second bank.

11. The alcohol reformer set forth in claim 6 , wherein said at least one bank further includes at least a third bank of conduits, wherein the third bank of conduits is downstream of the second bank along the alcohol flow path.

12. The alcohol reformer set forth in claim 7 , wherein the reheat stage is upstream of the catalyst stage along the alcohol flow path.

13. The alcohol reformer set forth in claim 1 , wherein the reheat stage is upstream of the catalyst stage along the alcohol flow path.

14. The alcohol reformer set forth in claim 1 , wherein the reheat stage is downstream of the catalyst stage along the alcohol flow path.

15. The alcohol reformer set forth in claim 14 , wherein the reheat stage comprises a plurality of second heat transfer members of different porosity to form a porosity gradient.

16. An alcohol reformer comprising:
a conduit having an axis and including a wall having an exterior surface and an interior surface at least partially defining an interior chamber through which alcohol vapor flows along an alcohol flow path, the conduit wall comprising a thermally conductive material;
a plurality of fins extending generally radially outward from the exterior surface of the conduit wall, the fins comprising thermally conductive material, wherein the fins and the conduit wall are in thermal contact;
a catalyst stage in the interior chamber of the conduit having a length extending along the axis, wherein the catalyst stage is configured to allow alcohol vapor to flow through the catalyst stage along the alcohol flow path, the catalyst stage including
an alcohol reforming catalyst, and
a heat transfer member comprising thermally conductive material, wherein the heat transfer member is in thermal and physical contact with the conduit wall and the alcohol reforming catalyst along the length of the catalyst stage, whereby heat is transferable from the plurality of fins to the alcohol reforming catalyst along the length of the catalyst stage to enable reforming of the alcohol vapor as it flows through the catalyst stage;

a reheat stage in the interior chamber of the conduit and configured to allow alcohol vapor to flow through the reheat stage along the alcohol flow path, the reheat stage comprising a second heat transfer member, wherein the second heat transfer member is in thermal contact with the conduit wall, whereby heat is transferable from the plurality of fins to the second heat transfer member to enable heating of the alcohol vapor as it flows through the reheat stage,
wherein the reheat stage is downstream of the catalyst stage along the alcohol flow path,
wherein the second heat transfer member comprises a plurality of second heat transfer members, and wherein the plurality of second heat transfer members comprising different porosities forming a porosity gradient.

17. The alcohol reformer set forth in claim 1 in combination with a reformer housing defining an exhaust channel through which exhaust gas

Assignees

• Monsanto Technology Llc

Inventors

• Morgenstern David A
• Sall Erik D
• Smith Roger C
• Ralph Brian Odell

Classifications

• B01J2208/00513

  using inert heat absorbing solids in the bed · CPC title

• C01B2203/107

  Platinum catalysts · CPC title

• C01B2203/1288

  Evaporation of one or more of the different feed components · CPC title

• B01J8/0285

  Heating or cooling the reactor (for tubular reactors in furnaces B01J8/062) · CPC title

• C01B2203/0833

  Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases · CPC title