Hydrocarbon conversion to ethylene

Patent metadata

Field	Value
Publication number	US-9809506-B2
Application number	US-201615294898-A
Country	US
Kind code	B2
Filing date	Oct 17, 2016
Priority date	Dec 17, 2014
Publication date	Nov 7, 2017
Grant date	Nov 7, 2017

Abstract

The invention relates to a hydrocarbon conversion process and a reactor configured to carry out the hydrocarbon conversion process. The hydrocarbon conversion process is directed to increasing the overall equilibrium production of ethylene from typical pyrolysis reactions. The hydrocarbon conversion process can be carried out by exposing a hydrocarbon feed to a peak pyrolysis gas temperature in a reaction zone in the range of from 850° C. to 1200° C.

First claim

The invention claimed is:

1. A tubular, regenerative, reverse-flow thermal reactor for pyrolyzing hydrocarbon, the reactor comprising:
(a) first and second zones, and a reaction zone located between the first and second zones,
(b) first and second thermal masses, at least a portion of the first thermal mass being located in the first zone, and at least a portion of the second thermal mass being located in the second zone,
(c) at least one combustion feed conduit comprising a fuel channel and a separate oxidant channel, the feed conduit being adapted for introducing a combustion feed comprising a fuel and an oxidant into the reactor proximate to the first zone and conveying the combustion feed to the reaction zone, wherein the fuel and oxidant channels are located within the portion of the first thermal mass that is located in the first zone,
(d) at least one pyrolysis feed conduit for introducing a pyrolysis feed into the reactor proximate to the second zone and conveying pyrolysis feed to the reaction zone, and
(e) one or more valves for (i) establishing during a first time interval a flow of the combustion feed in a forward direction through the first zone to the reaction zone for combustion and (ii) establishing during a second time interval a flow of the pyrolysis feed in a reverse direction through the second zone to the reaction zone for the pyrolysis, wherein
the first zone is configured to transfer heat from the first thermal mass to the fuel and to the oxidant during the first time interval and to transfer heat from pyrolysis products to the first thermal mass during the second time interval,
the reaction zone is configured to combust the combustion feed during the first interval and to expose the pyrolysis feed to a peak pyrolysis temperature in the range of from 850° C. to 1200° C., at a hydrocarbon pressure ≧7 psia (0.48 bara), for a residence time ≦1.0 seconds during the second time interval, and
the second zone is configured to transfer heat from combustion products to the second thermal mass during the first time interval and to transfer heat from the second thermal mass to the pyrolysis feed during the second time interval.

2. The reactor of claim 1 , wherein the first time interval and the second time interval are included in a cycle time, the cycle time being in the range of from 1 second to 240 seconds.

3. The reactor of claim 1 , wherein the first time interval and the second time interval are included in a cycle time, the cycle time being in the range of from 1 second to 60 seconds.

4. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a melting point of at least 1500° C.

5. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a geometric void in the range of from 10% to 70%.

6. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a pore volume within a geometric solid, the pore volume being not greater than 20%.

7. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a bulk density in the range of from 0.5 g/cm 3 to 5 g/cm 3 .

8. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a thermal conductivity in the range of from 0.1 W/mK to 50 W/mK.

9. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a thermal expansion coefficient in the range of from 0.2×10 −6 /K to 15×10 −6 /K.

10. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a thermal capacity in the range of from 500 J/dm 3 K to 3000 J/dm 3 K.

11. The reactor of claim 1 , wherein at least one of the first and second thermal masses includes at least one ceramic selected from the group consisting of yttria, zirconia, alumina, and mixtures thereof.

12. The reactor of claim 1 , wherein at least one of the first and second thermal masses has an average wetted surface area per unit volume in the range of about 5 cm −1 to 50 cm −1 .

13. The reactor of claim 1 , wherein at least one of the first and second thermal masses has a ceramic honeycomb monolith form.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Hershkowitz Frank
• Keusenkothen Paul F
• Laurenzi Ian J

Classifications

• B01J2208/00513

  using inert heat absorbing solids in the bed · CPC title

• B01J2219/00076

  with heat exchange elements inside the reactor · CPC title

• B01J2219/00164

  controlling the flow · CPC title

• C10G9/26

  with discontinuously preheated non-moving solid material, e.g. blast and run · CPC title

• C07C5/327

  Formation of non-aromatic carbon-to-carbon double bonds only · CPC title