Organometallic solution based high resolution patterning compositions and corresponding methods
US-2016116839-A1 · Apr 28, 2016 · US
US2019018317A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2019018317-A1 |
| Application number | US-201816132671-A |
| Country | US |
| Kind code | A1 |
| Filing date | Sep 17, 2018 |
| Priority date | Mar 24, 2016 |
| Publication date | Jan 17, 2019 |
| Grant date | — |
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An actinic ray-sensitive or radiation-sensitive composition, and an actinic ray-sensitive or radiation-sensitive composition obtained from a method for purifying an actinic ray-sensitive or radiation-sensitive composition and a method for producing an actinic ray-sensitive or radiation-sensitive composition contain a cation having a metal atom and a ligand, and have each of a content of sodium, a content of magnesium, and a content of iron of 50 ppm by mass or less with respect to the total solid content of the actinic ray-sensitive or radiation-sensitive composition. A pattern forming method includes the method for producing or purifying the actinic ray-sensitive or radiation-sensitive composition. A method for producing an electronic device includes the pattern forming method.
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What is claimed is: 1 . An actinic ray-sensitive or radiation-sensitive composition comprising: a cation having a metal atom; and a ligand, wherein a content of sodium is 50 ppm by mass or less with respect to a total solid content of the actinic ray-sensitive or radiation-sensitive composition, a content of magnesium is 50 ppm by mass or less with respect to the total solid content of the actinic ray-sensitive or radiation-sensitive composition, and a content of iron is 50 ppm by mass or less with respect to the total solid content of the actinic ray-sensitive or radiation-sensitive composition. 2 . The actinic ray-sensitive or radiation-sensitive composition according to claim 1 , containing a suboxide cation of the metal atom, a counter anion, a peroxide-based ligand, and water. 3 . The actinic ray-sensitive or radiation-sensitive composition according to claim 1 , containing the cation having the metal atom, an organic ligand, and an organic solvent. 4 . The actinic ray-sensitive or radiation-sensitive composition according to claim 1 , wherein the metal atom is at least one selected from the group consisting of hafnium, zirconium, and tin. 5 . The actinic ray-sensitive or radiation-sensitive composition according to claim 1 , wherein the metal atom is at least one selected from the group consisting of hafnium and zirconium. 6 . The actinic ray-sensitive or radiation-sensitive composition according to claim 1 , wherein the metal atom is tin. 7 . A method for purifying an actinic ray-sensitive or radiation-sensitive composition, comprising purifying the actinic ray-sensitive or radiation-sensitive composition containing a cation having a metal atom and a ligand until a content of sodium reaches 50 ppm by mass or less with respect to a total solid content of the actinic ray-sensitive or radiation-sensitive composition, a content of magnesium reaches 50 ppm by mass or less with respect to the total solid content of the actinic ray-sensitive or radiation-sensitive composition, and a content of iron reaches 50 ppm by mass or less with respect to the total solid content of the actinic ray-sensitive or radiation-sensitive composition. 8 . The method for purifying an actinic ray-sensitive or radiation-sensitive composition according to claim 7 , wherein the purifying step is recrystallizing the actinic ray-sensitive or radiation-sensitive composition by the use of water or an organic solvent. 9 . The method for purifying an actinic ray-sensitive or radiation-sensitive composition according to claim 8 , wherein the water or the organic solvent has a content of sodium of 50 ppm by mass or less with respect to the water or the organic solvent, a content of magnesium of 50 ppm by mass or less with respect to the water or the organic solvent, and a content of iron of 50 ppm by mass or less with respect to the water or the organic solvent. 10 . The method for purifying an actinic ray-sensitive or radiation-sensitive composition according to claim 7 , further comprising measuring the contents of sodium, magnesium, and iron in the actinic ray-sensitive or radiation-sensitive composition by inductively coupled plasma mass spectrometry. 11 . A method for producing an actinic ray-sensitive or radiation-sensitive composition containing a cation having a metal atom and a ligand, comprising preparing an actinic ray-sensitive or radiation-sensitive composition by the use of a material obtained by purification such that: a content of sodium is 50 ppm by mass or less with respect to a total solid content of the actinic ray-sensitive or radiation-sensitive composition, a content of magnesium is 50 ppm by mass or less with respect to the total solid content of the actinic ray-sensitive or radiation-sensitive composition, and a content of iron is 50 ppm by mass or less with respect to the total solid content of the actinic ray-sensitive or radiation-sensitive composition. 12 . The method for producing an actinic ray-sensitive or radiation-sensitive composition according to claim 11 , wherein the purification is performed by recrystallizing the material by the use of water or an organic solvent. 13 . The method for producing an actinic ray-sensitive or radiation-sensitive composition according to claim 12 , wherein the water or the organic solvent has a content of sodium of 50 ppm by mass or less with respect to the water or the organic solvent, a content of magnesium of 50 ppm by mass or less with respect to the water or the organic solvent, and a content of iron of 50 ppm by mass or less with respect to the water or the organic solvent. 14 . The method for producing an actinic ray-sensitive or radiation-sensitive composition according to claim 11 , further comprising measuring the contents of sodium, magnesium, and iron in the actinic ray-sensitive or radiation-sensitive composition by inductively coupled plasma mass spectrometry. 15 . A pattern forming method comprising the method for purifying an actinic ray-sensitive or radiation-sensitive composition according to claim 7 . 16 . A pattern forming method comprising the method for producing an actinic ray-sensitive or radiation-sensitive composition according to claim 11 . 17 . A method for manufacturing an electronic device, comprising the pattern forming method according to claim 15 . 18 . A method for manufacturing an electronic device, comprising the pattern forming method according to claim 16 .
Treatment before imagewise removal, e.g. prebaking {(G03F7/265 takes precedence)} · CPC title
involving an interaction between the metallic and non-metallic component, e.g. photodope systems · CPC title
Treatment after imagewise removal, e.g. baking · CPC title
using coherent light; using polarised light · CPC title
Coating on a rotating support, e.g. using a whirler or a spinner · CPC title
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