Powder of hexagonal boron nitride, process for producing same, resin composition, and resin sheet

Patent metadata

Field	Value
Publication number	US-2018201818-A1
Application number	US-201615744426-A
Country	US
Kind code	A1
Filing date	Aug 19, 2016
Priority date	Sep 3, 2015
Publication date	Jul 19, 2018
Grant date	—

Abstract

A hexagonal boron nitride (hBN) powder containing an aggregate of primary particles of hBN, in which the powder has a primary particle size of less than 10 μm, a ratio of an average longer diameter (L 1 ) to an average thickness (d 1 ) of the primary particles, [L 1 /d 1 ], of 5.0 or more and 20 or less, and a BET specific surface area of less than 10 m 2 /g, and the powder has one maximum peak in a range of a particle size of 45 μm or more and 150 μm or less in a particle size distribution curve of a hexagonal boron nitride powder classified to have a particle size of 45 μm or more and 106 μm or less, and has a decrease rate of the maximum peak of 10% or more and less than 40% when a dispersion liquid obtained by dispersing the hexagonal boron nitride powder in water is subjected to an ultrasonic treatment for 1 minute, the peak decrease rate being calculated by expression (1), a method for producing the hBN powder, and a resin composition and a resin sheet each containing the hBN powder.

First claim

1 . A hexagonal boron nitride powder comprising an aggregate of primary particles of hexagonal boron nitride, wherein
the powder has a primary particle size of less than 10 μm, a ratio of an average longer diameter (L 1 ) to an average thickness (d 1 ) of the primary particles, [L 1 /d 1 ], of 5.0 or more and 20 or less, and a BET specific surface area of less than 10 m 2 /g, and the powder has one maximum peak in a range of a particle size of 45 μm or more and 150 μm or less in a particle size distribution curve of the hexagonal boron nitride powder classified to have a particle size of 45 μm or more and 106 μm or less, and has a decrease rate of the maximum peak of 10% or more and less than 40% when a dispersion liquid obtained by dispersing the hexagonal boron nitride powder in water is subjected to an ultrasonic treatment for 1 minute, the peak decrease rate being calculated by the following expression (1):
Peak decrease rate=[(maximum peak height before treatment( a ))−(maximum peak height after treatment( b ))]/(maximum peak height before treatment( a ))  (1).

2 . The hexagonal boron nitride powder as claimed in claim 1 , having a BET specific surface area of 1.5 m 2 /g or more and 6.0 m 2 /g or less.

3 . The hexagonal boron nitride powder as claimed in claim 1 , having a BET specific surface area of 1.5 m 2 /g or more and 5.0 m 2 /g or less.

4 . The hexagonal boron nitride powder as claimed in claim 1 , having a crystallite size of 260 Å or more and 1000 Å or less.

5 . The hexagonal boron nitride powder as claimed in claim 1 , having a bulk density of 0.50 g/cm 3 or more.

6 . A resin composition comprising 10% by volume or more and 90% by volume or less of the hexagonal boron nitride powder as claimed in claim 1 .

7 . A resin sheet comprising the resin composition as claimed in claim 6 or a cured product thereof.

8 . A method for producing the hexagonal boron nitride powder as claimed in claim 1 , the method comprising a step of mixing 100 parts by mass of a mixed powder comprising 50% by mass or more and 90% by mass or less of a boron nitride fine powder (A) and 10% by mass or more and 50% by mass or less of a boron compound (B) represented by a formula (B 2 O 3 ).(H 2 O) X wherein X=0 to 3, and 1.0 part by mass or more and 15 parts by mass or less in terms of carbon of a carbon source (C), molding a resultant mixture, and then firing a resultant under an atmosphere comprising a nitrogen gas, wherein
the boron nitride fine powder (A) has a ratio of an average longer diameter (L 2 ) to an average thickness (d 2 ) of primary particles thereof, [L 2 /d 2 ], of 2.0 or more and 15 or less, a 50% volume cumulative particle size D 50 of 0.20 μm or more and 5.0 μm or less, a BET specific surface area of 5.0 m 2 /g or more and 30 m 2 /g or less, and a crystallite size of 150 Å or more and 400 Å or less.

9 . The method for producing the hexagonal boron nitride powder as claimed in claim 8 , wherein the boron nitride fine powder (A) has a 50% volume cumulative particle size D 50 of 0.20 μm or more and 1.0 μm or less.

10 . The method for producing the hexagonal boron nitride powder as claimed in claim 8 , wherein the boron nitride fine powder (A) has a BET specific surface area of 5.0 m 2 /g or more and 20 m 2 /g or less.

11 . The method for producing the hexagonal boron nitride powder as claimed in claim 8 , wherein the boron nitride fine powder (A) has a crystallite size of 200 Å or more and 400 Å or less.

12 . The method for producing the hexagonal boron nitride powder as claimed in claim 8 , the method comprising a step of mixing 100 parts by mass of the mixed powder comprising 50% by mass or more and 90% by mass or less of the boron nitride fine powder (A) and 10% by mass or more and 50% by mass or less of the boron compound (B) represented by the formula (B 2 O 3 ).(H 2 O) X wherein X=0 to 3, and 1.0 part by mass or more and 15 parts by mass or less in terms of carbon of the carbon source (C), molding the resultant mixture, and then firing the resultant under an atmosphere comprising a nitrogen gas, wherein
the boron nitride fine powder (A) has a ratio of the average longer diameter (L 2 ) to the average thickness (d 2 ) of the primary particles thereof, [L 2 /d 2 ], of 2.0 or more and 15 or less, a 50% volume cumulative particle size D 50 of 0.20 μm or more and 1.0 μm or less, a BET specific surface area of 5.0 m 2 /g or more and 20 m 2 /g or less, and a crystallite size of 200 Å or more and 400 Å or less.

13 . The method for producing the hexagonal boron nitride powder as claimed in claim 8 , wherein the carbon source (C) is one or two selected from the group consisting of graphite and boron carbide.

Assignees

• Showa Denko Kk

Inventors

• Otsuka Yuki
• Fukasawa Masaru

Classifications

• C08K2201/005

  Additives being defined by their particle size in general · CPC title

• C08K2003/385

  Binary compounds of nitrogen with boron · CPC title

• C01P2006/12

  Surface area · CPC title

• C01P2006/32

  Thermal properties · CPC title

• C01P2004/50

  Agglomerated particles · CPC title