Boron nitride aggregated grain

Patent metadata

Field	Value
Publication number	US-11268004-B2
Application number	US-201716339978-A
Country	US
Kind code	B2
Filing date	Aug 31, 2017
Priority date	Oct 7, 2016
Publication date	Mar 8, 2022
Grant date	Mar 8, 2022

Abstract

A boron nitride powder includes boron nitride aggregated grains that are formed by aggregation of scaly hexagonal boron nitride primary particles, the boron nitride powder having the following characteristic properties (A) to (C): (A) the primary particles of the scaly hexagonal boron nitride have an average long side length of 1.5 μm or more and 3.5 μm or less and a standard deviation of 1.2 μm or less; (B) the boron nitride aggregated grains have a grain strength of 8.0 MPa or more at a cumulative breakdown rate of 63.2% and a grain strength of 4.5 MPa or more at a cumulative breakdown rate of 20.0%; and (C) the boron nitride powder has an average particle diameter of 20 μm or more and 100 μm or less. Also provided are a method for producing the same and a thermally conductive resin composition including the same.

First claim

The invention claimed is:

1. A boron nitride powder comprising boron nitride aggregated grains that are formed by aggregation of scaly hexagonal boron nitride primary particles, the boron nitride powder having the following characteristics (A) to (C):
(A) the primary particles of the scaly hexagonal boron nitride have an average long side length of 1.5 μm or more and 3.5 μm or less and a standard deviation of 1.2 μm or less;
(B) the boron nitride aggregated grains have a grain strength of 8.0 MPa or more at a cumulative breakdown rate of 63.2% and a grain strength of 4.5 MPa or more at a cumulative breakdown rate of 20.0%; and
(C) the boron nitride powder has an average particle diameter of 20 μm or more and 100 μm or less.

2. The boron nitride powder according to claim 1 , wherein the average particle diameter of the boron nitride powder (C) is 30 μm or more and 80 μm or less.

3. The boron nitride powder according to claim 1 , prepared by a method for producing a boron nitride powder characterized by the steps of:
(a) pressure-nitridating and calcining a boron carbide having an average particle diameter of 6 μm or more and 55 μm or less and a carbon content of 18% or more and 21% or less and
(b) heat-treating the boron carbide by heating it to a temperature allowing initiation of decarburization, heating it to a retention temperature at a heating rate of 5° C./min or less, and heating it at a temperature of 1750° C. or higher for a period longer than 0.5 hour and shorter than 40 hours in a decarburization crystallization step after the pressure nitridation and calcination.

4. The boron nitride powder according to claim 3 , wherein the boron carbide is pressure-nitridated and calcined at a temperature of 1800° C. or higher and at a pressure of 0.7 MPa or more and 1.0 MPa or less in the step (a).

5. A thermally conductive resin composition, comprising the boron nitride powder according to claim 1 .

Assignees

• Denka Company Ltd

Inventors

• Takeda Go
• Taniguchi Yoshitaka

Classifications

• C08K2003/385

  Binary compounds of nitrogen with boron · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C09C3/041

  Grinding · CPC title

• C08K9/02

  Ingredients treated with inorganic substances · CPC title

• C09C3/066

  Treatment or coating resulting in a free metal containing surface-region (C09C1/0078 takes precedence) · CPC title