Photoisomerizing polymers

Patent metadata

Field	Value
Publication number	US-2016355639-A1
Application number	US-201514835194-A
Country	US
Kind code	A1
Filing date	Aug 25, 2015
Priority date	Jun 4, 2015
Publication date	Dec 8, 2016
Grant date	—

Abstract

In an example, a process of forming a photoisomerizing azobenzene polymer includes chemically reacting an azobenzene material that includes at least two chlorocarbonyl functional groups with an amine to form a photoisomerizing azobenzene polymer. The photoisomerizing azobenzene polymer has a polymer chain that includes a first chlorocarbonyl group disposed at a first end of the polymer chain, a plurality of repeating azobenzene monomer units, and a second chlorocarbonyl group disposed at a second end of the polymer chain.

First claim

1 . A process of forming a photoisomerizing azobenzene polymer, the process comprising:
chemically reacting an azobenzene material that includes at least two chlorocarbonyl functional groups with an amine to form a photoisomerizing azobenzene polymer, wherein the photoisomerizing azobenzene polymer has a polymer chain that includes:
a first chlorocarbonyl group disposed at a first end of the polymer chain;
a plurality of repeating azobenzene monomer units; and
a second chlorocarbonyl group disposed at a second end of the polymer chain.

2 . The process of claim 1 , wherein:
exposure to a first wavelength of light results in azobenzene monomer units of the plurality of repeating azobenzene monomer units undergoing a first change of configuration to a cis-azobenzene configuration; and exposure to a second wavelength of light results in azobenzene monomer units of the plurality of repeating azobenzene monomer units undergoing a second change of configuration to a trans-azobenzene configuration.

3 . The process of claim 2 , wherein the first wavelength of light is about 365 nanometers.

4 . The process of claim 2 , wherein the second wavelength of light is about 420 nanometers.

5 . The process of claim 1 , wherein the azobenzene material includes azobenzene-4,4′-dicarbonyl dichloride, and wherein the amine includes 1,4-diaminobutane.

6 . A process of removing metal ions from a solution, the process comprising:
adding, to the solution that includes metal ions, a composition of matter that includes:
a particle;
a photoisomerizing polymer bonded to a first portion of the particle; and
a chelating material, distinct from the photoisomerizing polymer, the chelating material bonded to a second portion of the particle, the chelating material including one or more functional groups to bond one of more metal ions of the metal ions to the second portion of the particle; and
after adding the composition of matter to the solution:
exposing the solution to light having a first wavelength to induce a first change of configuration of monomer units of the photoisomerizing polymer from a first configuration to a second configuration; and
exposing the solution to light having a second wavelength to induce a second change of configuration of monomer units of the photoisomerizing polymer from the second configuration to the first configuration.

7 . The process of claim 6 , wherein the photoisomerizing polymer includes a photoisomerizing azobenzene polymer.

8 . The process of claim 6 , wherein
the first change of configuration and the second change of configuration result in a first change of spatial position of the particle.

9 . The process of claim 6 , wherein the one or more functional groups of the chelating material include one or more silane groups.

10 . The process of claim 6 , wherein the metal ions include a mercury (Hg) ion, a silver (Ag) ion, a lead (Pb) ion, a cadmium (Cd) ion, a thallium (Tl) ion, or a combination thereof.

11 . The process of claim 6 , wherein the particle includes a silica particle.

12 . The process of claim 11 , wherein the silica particle has a characteristic dimension in a range of about 100 nanometers to about 1 micrometer.

13 . The process of claim 6 , wherein the first wavelength is about 365 nanometers.

14 . The process of claim 6 , wherein the second wavelength is about 420 nanometers.

15 . The process of claim 7 , wherein the photoisomerizing azobenzene polymer is formed by reacting an azobenzene material that includes at least two chlorocarbonyl functional groups with an amine.

16 . The process of claim 15 , wherein the azobenzene material includes azobenzene-4,4′-dicarbonyl dichloride, and wherein the amine includes 1,4-diaminobutane.

17 . The process of claim 7 , wherein:
an azobenzene monomer unit of the photoisomerizing azobenzene polymer undergoes a first change of configuration from the trans-azobenzene configuration to the cis-azobenzene configuration when exposed to the first wavelength of light; the azobenzene monomer unit undergoes a second change of configuration from the cis-azobenzene configuration to the trans-azobenzene configuration when exposed to the second wavelength of light; and the first change of configuration and the second change of configuration result in a first change of spatial position of the particle.

18 . The process of claim 8 , wherein the first change of spatial position of the particle is in a first direction that is different from a second direction associated with sedimentation after metal ion capture by the chelating material.

19 . The process of claim 6 , wherein the steps of exposing the solution to light having the first wavelength and exposing the solution to light having the second wavelength are separated by a time interval of up to ten seconds.

20 . The process of claim 6 , wherein exposing the solution to light having the first wavelength occurs for a duration between 1 and 10 seconds, and wherein exposing the solution to light having the second wavelength occurs for a duration between 1 and 10 seconds.

Assignees

• IBM

Inventors

• Wertz Jason T

Classifications

• C08J2377/06

  Polyamides derived from polyamines and polycarboxylic acids (C08J2377/10 takes precedence) · CPC title

• B01D15/26 Primary

  characterised by the separation mechanism · CPC title

• C08G69/28 Primary

  Preparatory processes · CPC title

• C08G69/48

  Polymers modified by chemical after-treatment · CPC title

• C08G69/26

  derived from polyamines and polycarboxylic acids · CPC title