Fiber production method and carbon fiber production method

Patent metadata

Field	Value
Publication number	US-11286579-B2
Application number	US-201816495965-A
Country	US
Kind code	B2
Filing date	Mar 2, 2018
Priority date	Mar 27, 2017
Publication date	Mar 29, 2022
Grant date	Mar 29, 2022

Abstract

A method of producing a fiber is provided, the method including extruding, from a spinneret, a spinning dope solution containing a fiber-forming polymer dissolved in a solvent, once allowing the solution to run in air, and then guiding the solution into the liquid of a coagulation bath to allow coagulation, wherein a gas-phase portion formed in a vertically downward direction from an extrusion surface of the spinneret to the liquid surface of the coagulation bath has a unidirectional air flow, and has an air flow rate per unit time (Af) which satisfies, in relation to the amount of the solvent in the spinning dope solution per unit time (As) in the gas-phase-portion volume (Vh), the relational expression 0.0008 m3≤Af/(As/Vh)≤0.0015 m3. A method of producing a fiber, which, in dry-jet wet spinning, suppresses occurrence of dew condensation in the spinneret, and reduces deterioration of the appearance caused by winding on rollers in the subsequent process or by fuzzing or yarn break in the stretching process, to enable significant improvement of the productivity and the appearance as a whole, is provided.

First claim

The invention claimed is:

1. A method of producing a fiber, the method comprising extruding, from a spinneret, a spinning dope solution containing an acrylonitrile copolymer dissolved in a solvent, once allowing the solution to run in air, and then guiding the solution into a coagulation bath liquid to allow coagulation,
wherein a number of holes in the spinneret is not less than 2000 and not more than 50,000,
a gas-phase portion formed in a vertically downward direction from an extrusion surface of the spinneret to a coagulation bath liquid surface has a unidirectional air flow,
a relative standard deviation of the wind velocities at four points in an outer periphery of the spinneret in the gas-phase portion is not more than 40%,
and has an air flow rate per unit time (Af) which satisfies, in relation to the amount of the solvent in the spinning dope solution per unit time (As) in the gas-phase-portion volume (Vh), the relational expression 0.0008 m 3 ≤Af/(As/Vh)≤0.0015 m 3 .

2. The method of producing a fiber according to claim 1 , wherein an hourly average of an absolute humidity at each of four points in an outer periphery of the spinneret in the gas-phase portion is not more than 20 g/m 3 .

3. A method of producing a carbon fiber, comprising producing a fiber by the method of producing a fiber according to claim 1 , performing stabilization treatment in an oxidizing gas at 200 to 300° C., and then heating the fiber in an inert gas at not less than 1000° C.

Assignees

• Toray Industries

Inventors

• Nagasaka Takuya
• Ishio Keiichi
• Yano Fumiya
• Furukawa Naoyuki
• Nagano Seiji
• Matsubara Yuma

Classifications

• D01D5/06 Primary

  Wet spinning methods {(D01D5/0046 takes precedence)} · CPC title

• D01F6/38

  comprising unsaturated nitriles as the major constituent · CPC title

• D01F6/18 Primary

  from polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• D10B2321/10

  polymers of unsaturated nitriles, e.g. polyacrylonitrile, polyvinylidene cyanide · CPC title