Lithium ion batteries comprising nanofibers

Patent metadata

Field	Value
Publication number	US-11050118-B2
Application number	US-201816035823-A
Country	US
Kind code	B2
Filing date	Jul 16, 2018
Priority date	Mar 2, 2012
Publication date	Jun 29, 2021
Grant date	Jun 29, 2021

Abstract

Lithium ion batteries, electrodes, nanofibers, and methods for producing same are disclosed herein. Provided herein are batteries having (a) increased energy density; (b) decreased pulverization (structural disruption due to volume expansion during lithiation/de-lithiation processes); and/or (c) increased lifetime. In some embodiments described herein, using high throughput, water-based electrospinning process produces nanofibers of high energy capacity materials (e.g., ceramic) with nanostructures such as discrete crystal domains, mesopores, hollow cores, and the like; and such nanofibers providing reduced pulverization and increased charging rates when they are used in anodic or cathodic materials.

First claim

What is claimed is:

1. A process for producing a battery separator, the process comprising coaxially gas assisted electrospinning a fluid stock to form a nanofiber mat, the fluid stock comprising (i) a plurality of ceramic or clay nanoparticles, or a combination thereof, or a ceramic precursor, and (ii) a polymer, the separator comprising one or more nanofiber(s) comprising a continuous polymer matrix with ceramic or clay domains embedded therein to form the nanofibers, less than 25% of the embedded domains being aggregated.

2. The process of claim 1 , further comprising annealing the nanofiber mat.

3. The process of claim 1 , further comprising the act of compressing the nanofiber mat at a pressure between 0.1 Mpa to 10 Mpa, or the acts of annealing the nanofiber mat followed by compressing the nanofiber mat at a pressure between 0.1 Mpa to 10 Mpa.

4. The process of claim 1 , wherein the polymer is a solvent soluble polymer.

5. The process of claim 2 , wherein the nanofiber mat is annealed at a temperature between 100° C. and 300° C.

6. The process of claim 5 , wherein the annealing of the nanofiber mat is performed under inert conditions.

7. The process of claim 2 , wherein the nanofiber mat has a thickness of between 10-100 microns.

8. The process of claim 1 , wherein the separator has an average pore size of between 0.25 micron and about 1 micron.

9. The process of claim 1 , wherein less than 10% of the embedded domains are aggregated.

10. The process of claim 1 , wherein the polymer comprises polyethylene (PE), ultra high molecular weight polyethylene (UHMWPE), polypropylene (PP), polyvinyl alcohol (PVA), polyacrylonitrile (PAN), polyvinylidene fluoride (PVDF), nylon, aramid, polyethylene terephthalate (PET), polyimide, polymethylmethacrylate (PMMA), or any combination thereof.

11. The process of claim 1 , wherein the continuous polymer matrix comprises polyethylene (PE), ultra high molecular weight polyethylene (UHMWPE), polypropylene (PP), polyvinyl alcohol (PVA), polyacrylonitrile (PAN), polyvinylidene fluoride (PVDF), nylon, aramid, polyethylene terephthalate (PET), polyimide, polymethylmethacrylate (PMMA), or any combination thereof.

12. The process of claim 1 , wherein the ceramic is selected from the group consisting of silica, zirconia, alumina, and any combination thereof.

13. The process of claim 1 , wherein the separator comprises 1-15 wt. % ceramic.

14. The process of claim 13 , wherein the separator comprises 3-12 wt. % ceramic.

15. The process of claim 1 , wherein a weight ratio of the ceramic nanoparticles or the ceramic precursor to polymer present in the fluid stock is at least 1:5.

16. The process of claim 10 , wherein the polymer is selected from the group consisting of polyacrylonitrile (PAN), polyvinylidene fluoride (PVDF), and any combination thereof.

17. The process of claim 11 , wherein the continuous polymer matrix comprises polyacrylonitrile (PAN), polyvinylidene fluoride (PVDF), or any combination thereof.

18. A process for producing a battery separator, the process comprising coaxially gas assisted electrospinning a fluid stock to form a nanofiber mat, the fluid stock comprising (i) a plurality of ceramic or clay nanoparticles or a ceramic precursor, and (ii) a polymer, the separator comprising one or more nanofiber(s) comprising a continuous polymer matrix with non-aggregated ceramic or clay nanostructure(s) embedded therein, wherein the polymer matrix is PE, UHMPWPE, PP, PVA, PAN, PEO, PVP, PVDF, PMMA, or a combination thereof, and wherein the one or more polymer nanocomposite nanofiber(s) comprises 0.5-50 wt. % ceramic and/or clay.

19. The process of claim 1 , wherein the nanofibers comprise a hollow core.

20. A process for producing a battery separator, the process comprising producing a non-woven mat of nanofibers by electrospinning a fluid stock to form nanofibers, the fluid stock consisting of: (i) a plurality of nanostructures comprising a clay, a ceramic, a ceramic precursor, or any combination thereof, (ii) a polymer portion comprising a polymer; and (iii) a solvent portion comprising an aqueous medium or a non-aqueous solvent; wherein the electrospinning is coaxially gas assisted to form a continuous polymer matrix with discrete non-aggregated ceramic and/or clay domains embedded therein.

Assignees

• Univ Cornell

Inventors

• Joo Yong Lak
• Hansen Nathaniel S
• Cho Daehwan
• Kim Kyoung Woo

Classifications

• H01M50/42

  Acrylic resins · CPC title

• H01M50/491

  Porosity · CPC title

• H01M50/489

  Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties · CPC title

• H01M50/414

  Synthetic resins, e.g. thermoplastics or thermosetting resins · CPC title

• D01F9/20

  from polyaddition, polycondensation or polymerisation products (D01F9/145, D01F9/16, D01F9/18 take precedence) · CPC title