Treatment of acid gases using molten alkali metal borates, and associated methods of separation

Patent metadata

Field	Value
Publication number	US-12558651-B2
Application number	US-202318167023-A
Country	US
Kind code	B2
Filing date	Feb 9, 2023
Priority date	Nov 7, 2019
Publication date	Feb 24, 2026
Grant date	Feb 24, 2026

Abstract

The removal of acid gases (e.g., non-carbon dioxide acid gases) using sorbents that include salts in molten form, and related systems and methods, are generally described.

First claim

What is claimed is:

1 . A system, comprising:
a sorber comprising:
a first inlet configured to receive a stream comprising an acid gas,
a second inlet configured to receive a sorbent,
a first outlet configured to output a treated gas lean in the acid gas relative to the stream comprising the acid gas, and
a second outlet configured to output a stream comprising the sorbent loaded with the acid gas;
a desorber comprising:
a first inlet configured to receive the sorbent loaded with the acid gas,
a second inlet configured to receive a sweep gas,
a first outlet configured to output the sorbent lean in the acid gas relative to the sorbent loaded with the acid gas, and
a second outlet configured to output a stream rich in the acid gas relative to the sweep gas;
a liquid-solid separator configured to receive at least a portion of the sorbent lean in the acid gas relative to the sorbent loaded with the acid gas and to output sulfurous solids and liquid sorbent; and a vessel configured to receive the sulfurous solids and to output aqueous alkali metals; wherein the system is configured such that the aqueous alkali metals are merged with the liquid sorbent and transported to the sorber.

2 . The system of claim 1 , wherein the liquid-solid separator receives a first portion of the sorbent lean in the acid gas relative to the sorbent loaded with the acid gas, and the system is configured such that the aqueous alkali metals are merged with a second portion of the sorbent lean in the acid gas relative to the sorbent loaded with the acid gas prior to being transported to the sorber.

3 . The system of claim 1 , wherein the vessel is a first vessel, and the system further comprises a second vessel configured to receive limewater and the sulfurous solids and to output a sulfurous product stream.

4 . The system of claim 3 , wherein the sulfurous product stream comprises gypsum.

5 . The system of claim 1 , wherein the liquid-solid separator comprises a cross-flow filter.

6 . A method, comprising:
transporting an acid gas to a sorber such that the acid gas interacts with a sorbent to produce a stream comprising sorbent loaded with the acid gas; transporting the sorbent loaded with the acid gas to a desorber such that the sorbent interacts with a sweep gas to produce a stream comprising the sorbent lean in the acid gas relative to the sorbent loaded with the acid gas; transporting a portion of the sorbent lean in the acid gas to a liquid-solid separator to produce a stream comprising sulfurous solids and a stream comprising liquid sorbent; and transporting the sulfurous solids to a vessel to produce a stream comprising aqueous alkali metals and a stream comprising a sulfurous product.

7 . The method of claim 6 , further comprising transporting limewater to the vessel such that the limewater interacts with the sulfurous solids to produce the aqueous alkali metals and the stream comprising the sulfurous product.

8 . The method of claim 6 , further comprising merging the aqueous alkali metals with the stream comprising the liquid sorbent to produce a merged stream.

9 . The method of claim 8 , wherein the portion of the sorbent lean in the acid gas is a first portion of the sorbent lean in the acid gas and the merged stream is a first merged stream, and further comprising merging the merged stream with a second portion of the sorbent lean in the acid gas to produce a second merged stream.

10 . The method of claim 9 , further comprising transporting the second merged stream to the sorber.

Assignees

• Massachusetts Inst Technology

Inventors

• Hatton Trevor Alan
• Harada Takuya
• Halliday Cameron G

Classifications

• B01D2251/302

  of lithium · CPC title

• B01D2257/302

  Sulfur oxides · CPC title

• B01D2257/404

  Nitrogen oxides other than dinitrogen oxide · CPC title

• B01D2257/402

  Dinitrogen oxide · CPC title

• B01D2251/60

  Inorganic bases or salts · CPC title