Molten hydroxide membrane for separation of acid gases from emissions

Patent metadata

Field	Value
Publication number	US-10464015-B2
Application number	US-201615159681-A
Country	US
Kind code	B2
Filing date	May 19, 2016
Priority date	May 19, 2016
Publication date	Nov 5, 2019
Grant date	Nov 5, 2019

Abstract

In one embodiment, a separation membrane includes: a porous support structure; and at least one alkali metal hydroxide disposed within pores of the porous support structure. In another embodiment, a method for separating acidic gases from a gas mixture includes exposing the gas mixture to a separation membrane at an elevated temperature, where the separation membrane includes a porous support and at least one molten alkali metal hydroxide disposed within pores of the porous support.

First claim

What is claimed is:

1. A separation membrane, comprising:
a porous support structure, wherein the porous support structure is configured to retain at least one alkali metal hydroxide in a molten phase within pores of the porous support structure based on capillary action; and
at least one alkali metal hydroxide disposed within pores of the porous support structure.

2. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide is selected from a group consisting of lithium hydroxide, sodium hydroxide, potassium hydroxide, rubidium hydroxide, and cesium hydroxide.

3. The separation membrane as recited in claim 1 , comprising a mixture of at least two alkali metal hydroxides selected from a group consisting of: lithium hydroxide, sodium hydroxide and potassium hydroxide.

4. The separation membrane as recited in claim 1 , wherein the porous support structure is characterized by at least one gradient in pore size along an axis of the porous support structure.

5. The separation membrane as recited in claim 1 , wherein the porous support structure comprises a material selected from a group consisting of: inconel 600, grade 316 stainless steel, grade 304 stainless steel, an alkaline earth oxide, yttrium doped zirconium oxide, cerium oxide, calcium carbonate and silicon carbide.

6. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide is present in a molten phase.

7. The separation membrane as recited in claim 1 , wherein pores of the porous support structure are characterized by a diameter in a range from about 75 nm to about 1 millimeter.

8. The separation membrane as recited in claim 1 , comprising a porous conductive coating coupled to opposite ends of the separation membrane.

9. The separation membrane as recited in claim 1 , wherein the porous support structure is characterized by a cross-sectional area of at least 1 cm 2 and a thickness of at least 0.01 cm.

10. The separation membrane as recited in claim 1 , wherein the porous support structure comprises an aerogel comprising at least one material selected from the group consisting of: inconel 600, grade 316 stainless steel, an alkaline earth oxide, yttrium doped zirconium oxide, cerium oxide, magnesium oxide, aluminum oxide, calcium carbonate, silicon carbide, and combinations thereof.

11. A method for separating acidic gases from a gas mixture, the method comprising:
exposing the gas mixture to a separation membrane at an elevated temperature, wherein the separation membrane comprises:
a porous support structure, wherein the porous support structure is configured to retain at least one alkali metal hydroxide in a molten phase within pores of the porous support structure based on capillary action; and
at least one alkali metal hydroxide disposed within pores of the porous support structure.

12. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises a eutectic mixture of the alkali metal hydroxides.

13. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises an equimolar mixture of potassium hydroxide, sodium hydroxide, and lithium hydroxide.

14. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises a ternary mixture of potassium hydroxide, sodium hydroxide, and lithium hydroxide.

15. The separation membrane as recited in claim 14 , wherein the potassium hydroxide and the sodium hydroxide are each present in an amount less than the lithium hydroxide.

16. The separation membrane as recited in claim 14 , wherein the potassium hydroxide, the sodium hydroxide, and the lithium hydroxide are present in a ratio in a range from 4:1:1 to 1:1:4.

17. The separation membrane as recited in claim 1 , wherein the at least one alkali metal hydroxide comprises a ternary mixture of hydroxides present in a ratio in a range from 4:1:1 to 1:1:4.

18. The separation membrane as recited in claim 4 , wherein the size gradient is characterized by either:
a first profile in which larger of the pores are located near a first end of the porous support structure and smaller of the pores are located near a second end of the porous support structure, wherein the first and second ends of the porous support structure are positioned opposite one another; or
a second profile in which larger of the pores are located near the first and second ends of the porous support structure and smaller of the pores are located a central region between the first and second ends of the porous support structure.

19. The separation membrane as recited in claim 8 , wherein the conductive coating comprises activated carbon and/or a graphitic material.

Assignees

• L Livermore Nat Security Llc

Inventors

• Worsley Marcus
• Campbell Patrick
• Kim Sangil
• Merrill Matthew

Classifications

• B01D2311/13

  Use of sweep gas · CPC title

• B01D2257/50

  Carbon oxides · CPC title

• B01D2251/604

  Hydroxides · CPC title

• B01D69/02

  characterised by their properties · CPC title

• B01D61/38

  Liquid-membrane separation · CPC title