Brush polymer terminated with phosphonate for DSA
US-12286503-B2 · Apr 29, 2025 · US
US12529144B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12529144-B2 |
| Application number | US-202217735151-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 3, 2022 |
| Priority date | Nov 12, 2019 |
| Publication date | Jan 20, 2026 |
| Grant date | Jan 20, 2026 |
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A composition includes a polymer and a solvent. The polymer includes a group (X) which is at least one selected from the group consisting of: a group including at least two cyano groups; a group including —B(OR)2; a group including —PO(OR)2; and a group including —P(OR)2. Each R independently represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms. The polymer preferably includes the group (X) at an end of a main chain thereof or at an end of a side chain thereof.
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What is claimed is: 1 . A method of producing a substrate, the method comprising: applying a composition directly or indirectly on a base material to form a coating film; and heating the coating film, wherein: the base material comprises a surface layer which comprises: a first region comprising a metal atom; and a second region not comprising a metal atom; the base material comprises a metal atom at least one of in or on at least a part of the surface layer; and the composition comprises: a polymer comprising a group (X) which is at least one selected from the group consisting of: a group comprising at least two cyano groups; a group comprising —B(OR) 2 ; a group comprising —PO(OR) 2 ; and a group comprising —P(OR) 2 , wherein, each R independently represents a hydrogen atom or a monovalent hydrocarbon group having 1 to 10 carbon atoms; and a solvent. 2 . The method according to claim 1 , wherein the metal atom constitutes a metal simple substance, an alloy, an electrically conductive nitride, or a silicide. 3 . The method according to claim 1 , wherein the metal atom is an atom of copper, iron, zinc, cobalt, aluminum, titanium, tin, tungsten, zirconium, tantalum, germanium, molybdenum, ruthenium, gold, silver, platinum, palladium, or nickel. 4 . The method according to claim 1 , further comprising after the heating, bringing a removing liquid into contact with the coating film. 5 . The method according to claim 4 , wherein the removing liquid comprises at least one selected from the group consisting of an acid and a base. 6 . The method according to claim 1 , further comprising applying a rinse agent on the coating film after the heating to remove the coating film formed on the second region, while keeping the coating film formed on the first region remained. 7 . The method according to claim 6 , after the applying of the rinse agent, further comprising depositing a metal oxide selectively on the second region to form a metal oxide pattern. 8 . The method according to claim 6 , after the applying of the rinse agent, bringing a removing liquid into contact with the coating film. 9 . The method according to claim 7 , after the applying of the rinse agent, bringing a removing liquid into contact with the coating film.
taking place solely at one end or both ends of the polymer backbone, i.e. not in the side or lateral chains · CPC title
Chemical modification by after-treatment (graft polymers, block polymers, crosslinking with unsaturated monomers or with polymers C08F251/00 - C08F299/00; of conjugated diene rubbers C08C) · CPC title
Introducing phosphorus atoms or phosphorus-containing groups · CPC title
with acid solutions · CPC title
with after-treatment of the deposited inorganic material · CPC title
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