Odor sensor and odor sensing method

Patent metadata

Field	Value
Publication number	US-12517080-B2
Application number	US-202418608288-A
Country	US
Kind code	B2
Filing date	Mar 18, 2024
Priority date	May 31, 2019
Publication date	Jan 6, 2026
Grant date	Jan 6, 2026

Abstract

A smell sensor includes an ion sensor having a sensitive film, a substance adsorption film disposed on the sensitive film and configured to adsorb a smell substance to be detected, and an electrode configured to apply a reference voltage to the substance adsorption film. The substance adsorption film is in a state of releasing a proton in response to absorbing the smell substance.

First claim

The invention claimed is:

1 . A smell sensor comprising:
an ion sensor including an ion sensitive portion; a substance adsorption film disposed on the ion sensitive portion and configured to adsorb a smell substance to be detected; an electrode configured to apply a reference voltage to the substance adsorption film; and a passivation layer provided to cover the ion sensor, wherein the substance adsorption film is in a state of releasing a proton in response to adsorbing the smell substance, wherein the substance adsorption film is provided to cover the passivation layer, wherein the passivation layer is provided with an opening exposing the ion sensitive portion to the outside, wherein the ion sensitive portion is in contact with the substance adsorption film through the opening, and wherein the substance adsorption film is provided to form a depression recessed along a shape of the opening.

2 . The smell sensor according to claim 1 ,
wherein the electrode is configured to apply the reference voltage to a portion of the absorption film that does not overlap the opening.

3 . The smell sensor according to claim 1 ,
wherein the substance adsorption film includes polyaniline in an emeraldine-salt state.

4 . The smell sensor according to claim 1 ,
wherein the ion sensitive portion is configured to change a potential of the ion sensitive portion in response to a change in ion concentration in a vicinity of the ion sensitive portion due to proton release from the substance adsorption film.

5 . The smell sensor according to claim 4 ,
further comprising a detector configured to detect the smell substance by monitoring an output value of the ion sensor in accordance with a potential of the ion sensitive portion and detecting a change in the output value of the ion sensor in accordance with a potential change of the ion sensitive portion.

6 . The smell sensor according to claim 1 ,
wherein the substance adsorption film is fibrous or porous.

7 . The smell sensor according to claim 1 ,
wherein a thickness of the substance adsorption film in a facing direction in which the ion sensitive portion and the substance adsorption film face each other is 5 μm or less.

8 . A smell sensing method using a smell sensor comprising: an ion sensor including an ion sensitive portion; a substance adsorption film disposed on the ion sensitive portion and configured to adsorb a smell substance to be detected; and a passivation layer provided to cover the ion sensor, wherein the substance adsorption film is provided to cover the passivation layer, the passivation layer is provided with an opening exposing the ion sensitive portion to the outside, the ion sensitive portion is in contact with the substance adsorption film through the opening, and the substance adsorption film is provided to form a depression recessed along a shape of the opening, the method comprising:
a step of monitoring an output value of the ion sensor in accordance with a potential of the ion sensitive portion in a state where a reference voltage is applied to the substance adsorption film; a step in which the substance absorption film releases a proton in response to adsorbing the smell substance; a step in which the ion sensitive portion changes a potential of the ion sensitive portion in response to a change in ion concentration in a vicinity of the ion sensitive portion due to proton release from the substance adsorption film; and a step of detecting the smell substance by detecting a change in an output value of the ion sensor in accordance with a potential change of the ion sensitive portion.

Assignees

• Hamamatsu Photonics Kk

Inventors

• Mizuno Seiichiro
• Yamamoto Hiroo
• Morita Sho
• WAKAMORI Toshiki

Classifications

• G01N27/4141 Primary

  specially adapted for gases · CPC title

• G01N27/333 Primary

  Ion-selective electrodes or membranes (glass electrodes G01N27/36) · CPC title