Odor sensor and odor sensing method

Patent metadata

Field	Value
Publication number	US-11977048-B2
Application number	US-202017605263-A
Country	US
Kind code	B2
Filing date	Feb 13, 2020
Priority date	May 31, 2019
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

A smell sensor includes an ion sensor having a sensitive film, a substance adsorption film disposed on the sensitive film and configured to adsorb a smell substance to be detected, and an electrode configured to apply a reference voltage to the substance adsorption film. The substance adsorption film is in a state of releasing a proton in response to absorbing the smell substance.

First claim

The invention claimed is:

1. A smell sensor comprising:
an ion sensor including an ion sensitive portion;
a substance adsorption film disposed on the ion sensitive portion and configured to adsorb a smell substance to be detected; and
an electrode configured to apply a reference voltage to the substance adsorption film,
wherein the substance adsorption film is in a state of releasing a proton in response to adsorbing the smell substance, and
wherein the substance adsorption film includes polyaniline in an emeraldine-salt state.

2. The smell sensor according to claim 1 ,
wherein the ion sensitive portion is configured to change a potential of the ion sensitive portion in response to a change in ion concentration in a vicinity of the ion sensitive portion due to proton release from the substance adsorption film.

3. The smell sensor according to claim 2 ,
further comprising a detector configured to detect the smell substance by monitoring an output value of the ion sensor in accordance with a potential of the ion sensitive portion and detecting a change in the output value of the ion sensor in accordance with a potential change of the ion sensitive portion.

4. The smell sensor according to claim 1 ,
wherein the substance adsorption film is fibrous or porous.

5. The smell sensor according to claim 1 ,
wherein a thickness of the substance adsorption film in a facing direction in which the ion sensitive portion and the substance adsorption film face each other is 5 μm or less.

6. The smell sensor according to claim 1 ,
further comprising a passivation layer provided to cover the ion sensor,
wherein the substance adsorption film is provided to cover the passivation layer,
wherein the passivation layer is provided with an opening exposing the ion sensitive portion to the outside,
wherein the ion sensitive portion is in contact with the substance adsorption film through the opening, and
wherein the substance adsorption film is provided along a shape of the opening.

7. A smell sensing method using a smell sensor comprising an ion sensor including an ion sensitive portion and a substance adsorption film disposed on the ion sensitive portion and configured to adsorb a smell substance to be detected, wherein the substance adsorption film includes polyaniline in an emeraldine-salt state, comprising:
a step of monitoring an output value of the ion sensor in accordance with a potential of the ion sensitive portion in a state where a reference voltage is applied to the substance adsorption film;
a step in which the substance absorption film releases a proton in response to adsorbing the smell substance;
a step in which the ion sensitive portion changes a potential of the ion sensitive portion in response to a change in ion concentration in a vicinity of the ion sensitive portion due to proton release from the substance adsorption film; and
a step of detecting the smell substance by detecting a change in an output value of the ion sensor in accordance with a potential change of the ion sensitive portion.

8. A smell sensing method using a smell sensor comprising an ion sensor including an ion sensitive portion and a substance adsorption film disposed on the ion sensitive portion and configured to adsorb a smell substance to be detected, wherein the substance adsorption film is fibrous or porous, comprising:
a step of monitoring an output value of the ion sensor in accordance with a potential of the ion sensitive portion in a state where a reference voltage is applied to the substance adsorption film;
a step in which the substance absorption film releases a proton in response to adsorbing the smell substance;
a step in which the ion sensitive portion changes a potential of the ion sensitive portion in response to a change in ion concentration in a vicinity of the ion sensitive portion due to proton release from the substance adsorption film; and
a step of detecting the smell substance by detecting a change in an output value of the ion sensor in accordance with a potential change of the ion sensitive portion.

9. A smell sensor comprising:
an ion sensor including an ion sensitive portion;
a substance adsorption film disposed on the ion sensitive portion and configured to adsorb a smell substance to be detected; and
an electrode configured to apply a reference voltage to the substance adsorption film,
wherein the substance adsorption film is in a state of releasing a proton in response to adsorbing the smell substance, and
wherein the substance adsorption film is fibrous or porous.

10. The smell sensor according to claim 9 ,
wherein the ion sensitive portion is configured to change a potential of the ion sensitive portion in response to a change in ion concentration in a vicinity of the ion sensitive portion due to proton release from the substance adsorption film.

11. The smell sensor according to claim 10 ,
further comprising a detector configured to detect the smell substance by monitoring an output value of the ion sensor in accordance with a potential of the ion sensitive portion and detecting a change in the output value of the ion sensor in accordance with a potential change of the ion sensitive portion.

12. The smell sensor according to claim 9 ,
wherein a thickness of the substance adsorption film in a facing direction in which the ion sensitive portion and the substance adsorption film face each other is 5 μm or less.

13. The smell sensor according to claim 9 ,
further comprising a passivation layer provided to cover the ion sensor,
wherein the substance adsorption film is provided to cover the passivation layer,
wherein the passivation layer is provided with an opening exposing the ion sensitive portion to the outside,
wherein the ion sensitive portion is in contact with the substance adsorption film through the opening, and
wherein the substance adsorption film is provided along a shape of the opening.

Assignees

• Hamamatsu Photonics Kk

Inventors

• Mizuno Seiichiro
• Yamamoto Hiroo
• Morita Sho
• WAKAMORI Toshiki

Classifications

• G01N27/333 Primary

  Ion-selective electrodes or membranes (glass electrodes G01N27/36) · CPC title

• G01N27/4141 Primary

  specially adapted for gases · CPC title