Methods for recovering iodine (I2)

Patent metadata

Field	Value
Publication number	US-12378113-B2
Application number	US-202217572542-A
Country	US
Kind code	B2
Filing date	Jan 10, 2022
Priority date	Jan 14, 2021
Publication date	Aug 5, 2025
Grant date	Aug 5, 2025

Abstract

Methods of recovering iodine (I 2 ) from a stream including iodine (I 2 ) vapor and at least one of: an inert gas and water vapor can include contacting the stream with an alkaline solution to form an iodide salt, contacting the stream with an adsorbent to selectively adsorb water from the stream, contacting the stream with a concentrated acid to absorb the water vapor from the stream, desublimating or condensing the iodine (I 2 ) vapor to form solid or liquid iodine (I 2 ), or contacting the stream with a material to condense or de-sublimate the iodine (I 2 ) vapor from the stream as the material at least one of: absorbs latent heat through a phase change of the material and absorbs sensible heat.

First claim

What is claimed is:

1. A method of recovering iodine (I 2 ), the method comprising:
providing a stream including iodine (I 2 ) vapor and water vapor;
contacting the stream with an adsorbent to selectively adsorb water from the stream, wherein the adsorbent is selected from the group consisting of 3A, 4A, 5A or XH-9 molecular sieves, alumina, calcium sulfate, silica gel, calcium chloride, sodium sulfate, calcium iodide, magnesium chloride, magnesium iodide, or combinations thereof.

2. The method of claim 1 , wherein in the providing step, the stream is provided from an iodine (I 2 ) drying process.

3. The method of claim 2 , further comprising recycling the iodine (I 2 ) vapor to the iodine (I 2 ) drying process after the contacting step.

4. The method of claim 1 , further comprising desublimating the iodine (I 2 ) vapor after the contacting step to recover iodine (I 2 ).

5. The method of claim 1 , further comprising regenerating the adsorbent by heating the adsorbent to a temperature of from 90° C. to 120° C. to vaporize iodine adhered to the adsorbent, and then heating the adsorbent to from about 150° C. to about 350° C. to desorb the water from the adsorbent.

6. The method of claim 1 , wherein the stream further comprises an inert gas.

7. The method of claim 1 , wherein the adsorbent comprises 4A molecular sieves.

8. The method of claim 1 , wherein the adsorbent comprises 3A molecular sieves.

9. The method of claim 1 , wherein the adsorbent comprises 5A molecular sieves.

10. The method of claim 1 , wherein the adsorbent comprises XH-9 molecular sieves.

11. The method of claim 1 , wherein the adsorbent comprises alumina.

12. The method of claim 1 , wherein the adsorbent comprises calcium sulfate.

13. The method of claim 1 , wherein the adsorbent comprises silica gel.

14. The method of claim 1 , wherein the adsorbent comprises calcium chloride.

15. The method of claim 1 , wherein the adsorbent comprises sodium sulfate.

16. The method of claim 1 , wherein the adsorbent comprises calcium iodide.

17. The method of claim 1 , wherein the adsorbent comprises magnesium chloride.

18. The method of claim 1 , wherein the adsorbent comprises magnesium iodide.

19. The method of claim 1 , further comprising reacting iodine from the iodine (I 2 ) vapor with hydrogen to produce hydrogen iodide.

20. The method of claim 19 , further comprising employing the hydrogen iodide in a process for preparing an iodoalkane.

Assignees

• Honeywell Int Inc

Inventors

• Chiu Yuon
• Kopkalli Haluk
• Wang Tao
• Uhrich Kevin

Classifications

• B01J20/18

  Synthetic zeolitic molecular sieves · CPC title

• B01D2252/504

  Mixtures of two or more absorbents · CPC title

• B01D2252/10

  Inorganic absorbents · CPC title

• B01D2259/40088

  by heating · CPC title

• B01D2257/202

  Single element halogens · CPC title