Electrode for electrochlorination processes

Patent metadata

Field	Value
Publication number	US-12195365-B2
Application number	US-201916959199-A
Country	US
Kind code	B2
Filing date	Mar 13, 2019
Priority date	Mar 14, 2018
Publication date	Jan 14, 2025
Grant date	Jan 14, 2025

Abstract

The present invention relates to an electrode for electrochlorination processes, optionally operable under polarity reversal conditions, comprising an active layer provided with a doped Ru—Ti catalytic composition.

First claim

The invention claimed is:

1. An electrode suitable for electrochlorination processes comprising a valve metal substrate and at least one active layer comprising a catalytic composition of ruthenium, titanium and at least a first doping agent X or oxides thereof, wherein ruthenium is between 20-50%, titanium is equal or below 79.5% and X is between 0.5-7% expressed in weight percentage referred to the elements, X is selected from the group consisting of scandium, strontium, hafnium and combinations of at least two of scandium, strontium, hafnium, bismuth, zirconium, aluminium, wherein the catalytic composition is selected from the group consisting of RuTiHf, RuTiSc, RuTiSr, RuTiScSr and RuTiScZr.

2. The electrode according to claim 1 , wherein the catalytic composition comprises 27-35% of ruthenium, 71% or less of titanium and 2-3% of X.

3. Method for manufacturing an electrode according to claim 1 comprising applying a solution comprising precursors of ruthenium, titanium and said doping agent X to a valve metal substrate and subsequently decomposing said solution by a thermal treatment in air at a temperature between 450° C.-500° C.

4. The method according to claim 3 , wherein said solution further comprises precursors of doping agent Y selected from the group consisting of copper, rhodium, platinum, iridium and combinations thereof.

5. The method according to claim 4 , wherein said solution further comprises precursors of doping agent Z, wherein Z is palladium.

6. Process for hypochlorite mediated water disinfection comprising the following steps:
flowing an aqueous solution containing NaCl between two opposite electrodes, where at least one of said two opposite electrodes is the electrode according to claim 1 ,
applying an external voltage between said two opposite electrodes thereby producing hypochlorite in said aqueous solution.

7. Low salinity pool implementing the process according to claim 6 .

8. An electrode suitable for electrochlorination processes comprising a valve metal substrate and at least one active layer comprising a catalytic composition of ruthenium, titanium and at least a first doping agent X or oxides thereof and a second doping agent Y or oxides thereof, wherein ruthenium is between 20-50%, titanium is equal or below 79.3%, X is between 0.5-7% and Y is between 0.2-3.2%, expressed in weight percentage referred to the elements, X is selected from the group consisting of scandium, strontium, hafnium, bismuth, zirconium, aluminium and combinations thereof, Y is selected from the group consisting of copper, rhodium, platinum, iridium and combinations thereof, wherein the catalytic composition is selected from the group consisting of RuTiZrCu, RuTiScRh, RuTiScCu, RuTiScCuRh, RuTiBiRh, RuTiBiCu and RuTiZrRh.

9. The electrode according to claim 8 , wherein the catalytic composition comprises 27-35% of ruthenium, 70.4% or less of titanium, 2-3% of X, and 0.6-1.7% of Y.

10. Process for hypochlorite mediated water disinfection comprising the following steps:
flowing an aqueous solution containing NaCl between two opposite electrodes, where at least one of said two opposite electrodes is the electrode according to claim 8 ,
applying an external voltage between said two opposite electrodes thereby producing hypochlorite in said aqueous solution.

11. Low salinity pool implementing the process according to claim 10 .

12. The electrode according to 8 , wherein the catalytic composition further comprises 0.2-2.2% of a third doping agent Z or its oxides, Z being palladium and wherein the catalytic composition is selected from the group consisting of RuTiScRhPd and RuTiScCuPd.

13. The electrode according to claim 5 , wherein the catalytic composition comprises 27-35% of ruthenium, 69.9% or less of titanium, 2-3% of X, and 0.6-1.7% of Y and 0.5-1.4% of Z.

14. Process for hypochlorite mediated water disinfection comprising the following steps:
flowing an aqueous solution containing NaCl between two opposite electrodes, where at least one of said two opposite electrodes is the electrode according to claim 12 ,
applying an external voltage between said two opposite electrodes thereby producing hypochlorite in said aqueous solution.

15. Low salinity pool implementing the process according to claim 14 .

Assignees

• Industrie De Nora Spa

Inventors

• Ramunni Anna
• Timpano Fabio

Classifications

• C25B11/089

  Alloys · CPC title

• C25B11/063

  Valve metal, e.g. titanium · CPC title

• C02F2201/4613

  Inversing polarity · CPC title

• C02F2103/42

  from bathing facilities, e.g. swimming pools · CPC title

• C02F2001/46142

  Catalytic coating · CPC title