Oxide superconductor and method for manufacturing same

Patent metadata

Field	Value
Publication number	US-12156483-B2
Application number	US-202117191599-A
Country	US
Kind code	B2
Filing date	Mar 3, 2021
Priority date	Sep 15, 2020
Publication date	Nov 26, 2024
Grant date	Nov 26, 2024

Abstract

An oxide superconductor of an embodiment includes an oxide superconducting layer including at least one superconducting region containing barium (Ba), copper (Cu) and a first rare earth element, having a continuous perovskite structure, and having a size of 100 nm×100 nm×100 nm or more, and a non-superconducting region in contact with the at least one superconducting region, containing praseodymium (Pr), barium (Ba), copper (Cu), and a second rare earth element, having a ratio of a number of atoms of the praseodymium (Pr) to a sum of a number of atoms of the second rare earth element and the number of atoms of the praseodymium (Pr) being 20% or more, having a continuous perovskite structure continuous with the continuous perovskite structure of the superconducting region, and having a size of 100 nm×100 nm×100 nm or more.

First claim

What is claimed is:

1. An oxide superconductor, comprising:
an oxide superconducting layer including
at least one superconducting region containing barium (Ba), copper (Cu), and at least one first rare earth element selected from the group consisting of yttrium (Y), lanthanum (La), neodymium (Nd), samarium (Sm), europium (Eu), gadolinium (Gd), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu), the at least one superconducting region having a continuous perovskite structure, and the at least one superconducting region having a size of 100 nm×100 nm×100 nm or more, and
a non-superconducting region in contact with the at least one superconducting region, the non-superconducting region containing praseodymium (Pr), barium (Ba), copper (Cu), and at least one second rare earth element selected from the group consisting of yttrium (Y), lanthanum (La), neodymium (Nd), samarium (Sm), europium (Eu), gadolinium (Gd), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu), a ratio of a number of atoms of the praseodymium (Pr) to a sum of a number of atoms of the at least one second rare earth element and the number of atoms of the praseodymium (Pr) in the non-superconducting region being equal to or more than 20%, the non-superconducting region having a continuous perovskite structure continuous with the continuous perovskite structure of the at least one superconducting region, and the non-superconducting region having a size of 100 nm×100 nm×100 nm or more.

2. The oxide superconductor according to claim 1 , wherein the at least one superconducting region includes a first superconducting region and a second superconducting region, and the non-superconducting region is disposed between the first superconducting region and the second superconducting region.

3. The oxide superconductor according to claim 1 , further comprising:
a substrate,
wherein the oxide superconducting layer is disposed on the substrate, and
an area of the oxide superconducting layer facing the substrate is equal to or more than 90% of a surface area of the substrate.

4. The oxide superconductor according to claim 1 , further comprising:
a substrate; and
an intermediate layer disposed between the substrate and the oxide superconducting layer,
wherein the non-superconducting region is lattice-matched with the intermediate layer.

5. The oxide superconductor according to claim 1 , wherein the oxide superconducting layer contains fluorine (F) of equal to or more than 2.0×10 15 atoms/cm 3 and equal to or less than 5.0×10 19 atoms/cm 3 , and carbon (C) of equal to or more than 1.0×10 17 atoms/cm 3 and equal to or less than 5.0×10 20 atoms/cm 3 .

6. The oxide superconductor according to claim 1 , wherein the at least one first rare earth element and the at least one second rare earth element are the same.

7. The oxide superconductor according to claim 1 , wherein the superconducting region contains praseodymium (Pr), and a ratio of a number of atoms of the praseodymium (Pr) to a sum of a number of atoms of the at least one first rare earth element and the number of atoms of the praseodymium (Pr) is equal to or less than 15%.

8. The oxide superconductor according to claim 1 , wherein the at least one first rare earth element is two kinds or more.

9. The oxide superconductor according to claim 1 , wherein the superconducting region further includes a clustered atomically substituted artificial pin.

Assignees

• Toshiba Kk

Inventors

• Araki Takeshi
• Hayashi Mariko

Classifications

• H10N60/01

  Manufacture or treatment · CPC title

• C04B2235/85

  Intergranular or grain boundary phases · CPC title

• C04B2235/768

  Perovskite structure ABO3 · CPC title

• C04B2235/661

  Multi-step sintering · CPC title

• C04B2235/656

  characterised by specific heating conditions during heat treatment · CPC title