Oxide superconductor and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-11417820-B2
Application number	US-202016912306-A
Country	US
Kind code	B2
Filing date	Jun 25, 2020
Priority date	Sep 16, 2015
Publication date	Aug 16, 2022
Grant date	Aug 16, 2022

Abstract

An oxide superconductor includes: REBa2Cu3O7-x (RE being one element selected from a “RE element group” of Pr, Nd, Sm, Eu, Gd, Y, Tb, Dy, Ho, Er, Tm, Yb, and Lu). The RE includes at least three types of metallic elements (M1, M2, and M3), and the three types of metallic elements are any element of the RE element group selected in order. In an oxide system satisfying R(M1)≤20 mol % and R(M2)≥60 mol % and R(M3)≤20 mol %, R(M1) being an average metallic element ratio of M1 in M1+M2+M3, SD(Ms)>0.15 is satisfied at a position at 50% of an average film thickness of a cross section including the c-axis, Ms being the metallic element of not larger of R(M1) and R(M3), SD(Ms) being a standard deviation/average value of a concentration of Ms.

First claim

What is claimed is:

1. A method for manufacturing an oxide superconductor, comprising:
forming an oxide superconductor as a film by making a gel film using a methanol solution, by two or more refining processes to expel water and acetic acid from the methanol solution, by obtaining a pre-bake film of an oxide and fluoride by decomposing a trifluoroacetic acid group in a pre-bake process, by forming a perovskite structure having a number of oxygen atoms of 6.0 in a main bake in a humidified atmosphere of 725 to 850 degrees C., and by performing oxygen annealing, the methanol solution having metal trifluoroacetate hydrate as a major component,
a mole ratio of metallic elements of RE:Ba:Cu being 1:2:3, (RE being one element selected from a “RE element group” of Pr, Nd, Sm, Eu, Gd, Y, Tb, Dy, Ho, Er, Tm, Yb, and Lu) wherein RE includes at least three types of metallic elements (M 1 , M 2 , and M 3 ) in a superconducting: layer, the three types of metallic elements being any element of the RE element group selected in order, R(M 1 )≤20 mol % and R(M 2 )≥60 mol % and R(M 3 )≤20 mol % being satisfied to obtain REBa 2 Cu 3 O 7-x having a single perovskite structure oriented in a c-axis, R(M 1 ) being an average metallic element ratio of M 1 in M 1 +M 2 +M 3 , R(M 2 ) being an average metallic element ratio of M 2 in M 1 +M 2 +M 3 , R(M 3 ) being an average metallic element ratio of M 3 in M 1 +M 2 +M 3 ,
SD(Ms)>0.15 being satisfied at a position at 50% of an average superconducting film thickness of a cross section including the c-axis oriented superconducting layer, if R(M 1 ) is equal to or smaller than R(M 3 ), Ms is M 1 , SD(Ms) being a standard deviation of concentration values of Ms over the average value of the Ms concentration.

2. The method of claim 1 , wherein the M 1 is Pr, Nd, or Sm.

3. The method of claim 1 , wherein the first film is provided on a base member included in the base body, or the first film is provided on an intermediate layer provided on the base member.

4. The method of claim 1 , wherein high purification processing of the solution is performed.

5. The method of claim 1 , wherein the solution is made by processes including a process using pentafluoropropionic acid, and a process of substituting trifluoroacetic acid for at least a portion of the pentafluoropropionic acid after the process using the pentafluoropropionic acid.

6. The method of claim 1 , wherein the M 1 is Nd.

7. The method of claim 1 , wherein the M 1 is Sm.

8. The method of claim 1 , wherein the M 1 is Pr.

Assignees

• Toshiba Kk

Inventors

• Araki Takeshi
• Hayashi Mariko
• Fuke Hiroyuki

Classifications

• C04B2235/768

  Perovskite structure ABO3 · CPC title

• C04B2235/3281

  Copper oxides, cuprates or oxide-forming salts thereof, e.g. CuO or Cu2O · CPC title

• C04B2235/449

  Organic acids, e.g. EDTA, citrate, acetate, oxalate · CPC title

• C04B35/62218

  obtaining ceramic films, e.g. by using temporary supports · CPC title

• C04B2235/721

  Carbon content · CPC title