Process to convert reduced sulfur species and water into hydrogen and sulfuric acid

Patent metadata

Field	Value
Publication number	US-12110601-B2
Application number	US-202217894674-A
Country	US
Kind code	B2
Filing date	Aug 24, 2022
Priority date	May 18, 2018
Publication date	Oct 8, 2024
Grant date	Oct 8, 2024

Abstract

A method for producing a cement material wherein 1) a first acid is reacted with a first cement precursor to form a second cement precursor, and 2) the second cement precursor is converted to a cement material. The first cement precursor includes one or more of Ca, Si, or Al, and the reaction with the first acid produces a second cement precursor that includes one or more of Ca, Si, or Al, and the conjugate base of the first acid. The second step can be performed by thermally converting the second cement precursor to a cement material by sintering or thermally decomposing the second cement precursor at a temperature in the range of 500 to 2000° C. The first step can be performed in the presence of water as a wet slurry. The concentration of the first acid can be greater than 20% by weight.

First claim

I claim:

1. A method for producing a cement material comprising:
(a) reacting a first acid and a first cement precursor comprising an element selected from the group consisting of Ca, Si, and Al or a combination thereof to form a second cement precursor, compositionally different from the first cement precursor, wherein the second cement precursor comprises an element selected from the group consisting of Ca, Si, and Al or a combination thereof, and a conjugate base of the first acid; and
(b) converting the second cement precursor to a cement material, compositionally different from the first and second cement precursors, wherein the cement material is a Portland cement, and wherein converting the second cement precursor to the cement material comprises thermally converting the second cement precursor by sintering or thermally decomposing the second cement precursor, thereby forming the cement material, wherein the step of sintering or thermally decomposing comprises treating the second cement precursor at a temperature selected from the range of 500 to 2000° C.

2. The method of claim 1 , wherein step (a) is performed in the presence of water as a wet slurry.

3. The method of claim 1 , wherein the second cement precursor comprises Ca.

4. The method of claim 1 , wherein the first acid is at a concentration of greater than or equal to 20% by mass.

5. The method of claim 1 , wherein thermally converting occurs in the presence of an additive.

6. The method of claim 5 , wherein the additive comprises silica, alumina, or iron oxide, or a combination thereof.

7. The method of claim 6 , wherein the additive comprises silica.

8. The method of claim 7 , wherein the cement material comprises one or more silicates.

9. The method of claim 6 , wherein the additive comprises alumina and/or iron oxide.

10. The method of claim 1 , wherein the cement material comprises a composite cement material.

11. The method of claim 1 , further comprising adding one or more aggregates to the cement material to produce a composite cement material.

12. The method of claim 11 , wherein the aggregate comprises sand and gravel and the composite cement material comprises concrete.

13. The method of claim 11 , wherein the aggregate comprises fine aggregates and the composite cement material comprises mortar.

14. The method of claim 1 , further comprising capturing carbon dioxide to form captured carbon dioxide and storing the captured carbon dioxide (CO 2 ).

15. The method of claim 14 , wherein the captured CO 2 comprises a bicarbonate.

Assignees

• California Inst Of Techn

Inventors

• Finke Cody E

Classifications

• C01B17/78

  characterised by the catalyst used · CPC title

• C01B17/88

  Concentration of sulfuric acid · CPC title

• C01B17/74

  Preparation · CPC title

• C01B17/69

  Sulfur trioxide; Sulfuric acid · CPC title

• C01F11/48

  Sulfites · CPC title