Particulate compositions for the formation of geopolymers, their use and methods for forming geopolymers therewith, and geopolymers obtained therefrom

Patent metadata

Field	Value
Publication number	US-10472282-B2
Application number	US-201615553691-A
Country	US
Kind code	B2
Filing date	Feb 29, 2016
Priority date	Feb 27, 2015
Publication date	Nov 12, 2019
Grant date	Nov 12, 2019

Abstract

The present invention relates to dry particulate composition for forming a geopolymer, comprising an alkali metal hydroxide, an alkali metal silicate, and an aluminosilicate. The invention further relates to methods for forming geopolymers and geopolymers formed according to said methods or using the said dry particulate composition.

First claim

The invention claimed is:

1. A dry particulate composition for forming a geopolymer, comprising:
(i) an alkali metal hydroxide,
(ii) an alkali metal silicate, and
(iii) an aluminosilicate,

wherein at least 45 wt.-% of the aluminosilicate is in an amorphous state, based on the total weight of aluminosilicate in the composition, and the aluminosilicate has a product of the specific surface area in m 2 /g and the amorphous phase content in the range from 5 to 15.

2. A dry particulate composition according to claim 1 , wherein at least 50 wt.-% of the aluminosilicate is in an amorphous state.

3. A dry particulate composition according to claim 1 , comprising from 1 wt.-% to 25 wt.-% alkali metal hydroxide, from 15 wt.-% to 50 wt.-% alkali metal silicate, and from 30 wt.-% to 80 wt.-% aluminosilicate, expressed as a proportion of the total weight of the dry particulate composition.

4. A dry particulate composition according to claim 1 wherein the said alkali metal hydroxide is selected from the group consisting of NaOH, KOH, LiOH, RbOH, CsOH, and mixtures thereof.

5. A dry particulate composition according to claim 1 , wherein the alkali metal of the said alkali metal silicate is selected from the group consisting of Na, K, Li, Rb, Cs, and mixtures thereof.

6. A dry particulate composition according to claim 1 , wherein said aluminosilicate is selected from the group consisting of metakaolin, fly ash, halloysite, metahalloysite, slag, rock dust, sand, activated clay, kaolin, mica, feldspar and mixtures thereof.

7. A dry particulate composition according to claim 1 , wherein at least 70 wt.-% of said aluminosilicate is in an amorphous state, based on the total weight of aluminosilicate in the composition and said aluminosilicate has a product of the specific surface area in m 2 /g and the amorphous phase content in the range from 10 to 15.

8. A dry particulate composition according to claim 1 , wherein the aluminosilicate in the amorphous state has a specific surface area in the range from 7 to 15 m 2 /g.

9. A geopolymer obtained by mixing a dry particulate composition with water, wherein the dry particulate composition comprises (i) an alkali metal hydroxide, (ii) an alkali metal silicate, and (iii) an aluminosilicate, wherein at least 45 wt.-% of the aluminosilicate is in an amorphous state, based on the total weight of aluminosilicate in the composition, and the aluminosilicate has a product of the specific surface area in m 2 /g and the amorphous phase content in the range from 5 to 15.

10. The geopolymer according to claim 9 , wherein the amount of water is 50 wt.-% or less, based on the total weight of particulate composition and water.

11. The geopolymer according to claim 9 , wherein the geopolymer further comprises aggregated materials after the addition of water and prior to geopolymerisation of the mixture.

12. The geopolymer according to claim 9 , wherein the geopolymer is used in products or articles selected from mortars, concretes, cements, coatings, waste management articles for toxic or nuclear waste immobilization, geopolymeric high-tech/fiber reinforced composites, geopolymeric foams, insulation, fire-proof coatings, foundry equipment, bricks, resins, binders, roads, or pavements.

13. The geopolymer according to claim 9 , wherein at least 50 wt.-% of the aluminosilicate is in an amorphous state.

14. The geopolymer according to claim 9 , wherein the dry particulate composition comprises from 1 wt.-% to 25 wt.-% alkali metal hydroxide, from 15 wt.-% to 50 wt.-% alkali metal silicate, and from 30 wt.-% to 80 wt.-% aluminosilicate, expressed as a proportion of the total weight of the dry particulate composition.

15. The geopolymer according to claim 9 , wherein said aluminosilicate is selected from the group consisting of metakaolin, fly ash, halloysite, metahalloysite, slag, rock dust, sand, activated clay, kaolin, mica, feldspar and mixtures thereof.

16. The geopolymer according to claim 9 , wherein at least 50 wt. % of said aluminosilicate is in an amorphous state, based on the total weight of aluminosilicate in the composition.

17. The geopolymer according to claim 9 , wherein at least 70 wt. % of said aluminosilicate is in an amorphous state, based on the total weight of aluminosilicate in the composition and said aluminosilicate has a product of the specific surface area in m 2 /g and the amorphous phase content in the range from 10 to 15.

18. The geopolymer according to claim 9 , wherein the aluminosilicate in the amorphous state has a specific surface area in the range from 7 to 15 m 2 /g.

19. A dry particulate composition for forming a geopolymer, comprising: (i) an alkali metal hydroxide, (ii) an alkali metal silicate, and (iii) an aluminosilicate, wherein at least 45 wt.-% of the aluminosilicate is in an amorphous state, based on the total weight of aluminosilicate in the composition, and the aluminosilicate has a product of the specific surface area in m 2 /g and the amorphous phase content in the range from 1 to 15 and wherein the aluminosilicate has a specific surface area in the range from 7 to 15 m 2 /g.

Assignees

• Imertech Sas

Inventors

• Autef Alexandre

Classifications

• C04B18/02

  Agglomerated materials {, e.g. artificial aggregates} · CPC title

• C04B28/006 Primary

  containing mineral polymers, e.g. geopolymers of the Davidovits type · CPC title

• C04B12/005

  Geopolymer cements, e.g. reaction products of aluminosilicates with alkali metal hydroxides or silicates · CPC title

• C04B40/0042

  Powdery mixtures · CPC title

• C04B14/10

  Clay {(sepiolite C04B14/042; grog C04B18/025)} · CPC title