Percolated mullite and a method of forming same

Patent metadata

Field	Value
Publication number	US-9527775-B2
Application number	US-201214362351-A
Country	US
Kind code	B2
Filing date	Dec 7, 2012
Priority date	Dec 9, 2011
Publication date	Dec 27, 2016
Grant date	Dec 27, 2016

Abstract

A method of producing percolated mullite in a body of material, the method including the step of heating the body of material, wherein the body of material has a composition that includes alumina and silica, and the weight ratio of alumina:silica is from approximately 10:90 to approximately 77:23. The percolated mullite produced extends continuously and/or substantially throughout the entire body of material.

First claim

The claims defining the invention are as follows:

1. A method of producing percolated mullite in a body of material, the method including the step of heating the body of material at a temperature in the range of from 1400° C. to 1600° C. for at least 2 hours, wherein the body of material has a composition that includes alumina and silica, and the weight percent ratio of alumina:silica is from 10:90 to 60:40 when normalized to exclude non-alumina and non-silica impurities.

2. A method as claimed in claim 1 , wherein the body includes pre-existing mullite, and/or a pre-existing glass component.

3. A method as claimed in claim 1 , wherein the composition includes at least one flux.

4. A method as claimed in claim 3 , wherein the at least one flux is an oxide and/or salt of an alkali, alkaline earth, transition metal or lanthanide, or a semimetal oxide, metalloid oxide, or a halogen.

5. A method as claimed in claim 1 , wherein the composition of the body includes a naturally occurring raw material and/or a synthetic raw material capable of forming mullite when heated.

6. A method as claimed in claim 1 , wherein the body is comprised principally of fly ash, bottom ash, municipal ash, bagasse ash or rise husk ash, or mixtures thereof.

7. A method as claimed in claim 1 , wherein the composition of the body includes one or more materials selected from the group consisting of fly ash, bottom ash, municipal ash, bagasse ash, rise hush ash, mullite, kyanite, sillimanite, andalusite, topaz, pyrophyllite, clays, phyllite-schist, saprolite clay, kyanite-staurolite, anorthosite, syenite, emery rock, other aluminosilicates, bauxite, alumina, aluminium hydrates, and red mud.

8. A method as claimed in claim 1 , wherein the body is heated at a temperature in the range of from 1400° C. and to 1600° C. for at least 8 hours.

9. A method as claimed in claim 1 , wherein the body is heated at a temperature of at least 1500° C.

10. Percolated mullite produced in accordance with the method of claim 1 .

11. A method as claimed in claim 1 , wherein the weight percent ratio of alumina:silica is from 10:90 to 55:45.

12. A method as claimed in claim 1 , wherein the weight percent ratio of alumina:silica is from 10:90 to 35:65.

13. A method as claimed in claim 1 , wherein the weight percent ratio of alumina:silica is from 10:90 to 30:70.

14. A body of material including a percolated mullite microstructure formed of a continuous or effectively continuous interconnected scaffold or network of direct-bonded mullite grains, the direct bonded mullite grains being such that glass is excluded from between the grains, wherein the percolated mullite microstructure extends continuously and substantially throughout the entire body.

15. A body of material as claimed in claim 14 , wherein the material is a principally 3-3 composite, with mullite and glass forming mutually interpenetrating 3-dimensional networks.

16. A body of material as claimed in claim 14 , wherein the material is a principally 0-3 composite, wherein the mullite forms a 3-dimensional network and residual glass is isolated in individual regions not in mutual contact.

17. A body of material as claimed in claim 15 , wherein the microstructure consists of a mullite volume content relative to the total mullite and glass content of less than 95%.

18. A body of material as claimed in claim 17 , wherein the microstructure consists of a mullite volume content relative to the total mullite and glass content of less than 90%.

19. A body of material as claimed in claim 16 , wherein the microstructure consists of a mullite volume content, relative to the total mullite and glass content of greater than or equal to 90%.

20. A body of material as claimed in claim 19 , wherein the microstructure consists of a mullite volume content, relative to the total mullite and glass content of greater than or equal to 95%.

21. A method of producing percolated mullite in a body of material, the method including the step of heating the body of material, wherein the body of material has a composition that includes alumina and silica, and the weight percent ratio of alumina:silica is from 24:76 to 48:52 when normalized to exclude non-alumina and non-silica impurities.

22. A method of producing percolated mullite in a body of material, the method including the step of heating the body of material, wherein the body of material has a composition that includes alumina and silica, and the weight percent ratio of alumina:silica is from 10:90 to 65:35 when normalized to exclude non-alumina and non-silica impurities, and wherein the body includes pre-existing mullite.

23. A method of producing percolated mullite in a body of material, the method including the step of heating the body of material, wherein the body of material has a composition that includes alumina and silica, and the weight percent ratio of alumina:silica is from 10:90 to 65:35 when normalized to exclude non-alumina and non-silica impurities, and wherein the body includes a pre-existing glass component.

24. A method of producing percolated mullite in a body of material, the method including the step of heating the body of material, wherein the body of material has a composition that includes alumina and silica, and the weight percent ratio of alumina:silica is from 10:90 to 65:35 when normalized to exclude non-alumina and non-silica impurities, and wherein the body is comprised principally of fly ash, bottom ash, municipal ash, bagasse ash, rice husk ash, or mixtures thereof.

Assignees

• Newsouth Innovations Pty Ltd
• Vecor Ip Holdings Ltd

Inventors

• Sorrell Charles Christopher
• Koshy Pramod
• Koszo Sandor

Classifications

• C04B2235/3205

  Alkaline earth oxides or oxide forming salts thereof, e.g. beryllium oxide · CPC title

• C04B35/62204

  using waste materials or refuse (clay-wares containing waste materials C04B33/132) · CPC title

• C04B35/657

  for manufacturing refractories (C04B35/05, C04B35/107, C04B35/484 take precedence) · CPC title

• C04B35/107

  Refractories by fusion casting · CPC title

• C04B2235/5228

  Silica and alumina, including aluminosilicates, e.g. mullite · CPC title