Static dissipating coatings, electronic circuits comprising such coatings, and methods of forming such coatings and circuits

Patent metadata

Field	Value
Publication number	US-12065585-B2
Application number	US-202117473488-A
Country	US
Kind code	B2
Filing date	Sep 13, 2021
Priority date	Oct 29, 2020
Publication date	Aug 20, 2024
Grant date	Aug 20, 2024

Abstract

Described herein are static dissipating coatings and thermally-stable static-controlled (TSSC) electronic circuits, comprising such coatings. Also described herein are methods of forming such coatings and circuits. In some examples, a static dissipating coating comprises a conductive polymer and a thermally-stable base polymer. The conductive polymer comprises polyaniline and, in some examples, a conductive agent, such as dinonylnaphthalene sulfonic acid (DNNSA), dodecyl benzene sulfonic acid (DBSA), and/or camphor sulfonic acid (CSA). The thermally-stable base polymer comprises one or more copolymers of butyl-methacrylate, such as poly-butylmethacrylate-co-methyl methacrylate (PBM). The amount of the conductive polymer is specifically controlled to ensure the coating's overall conductivity and thermal stability. In some examples, the conductive polymer concentration is at or less than 25% by weight. The conductivity of the coating is between 10 −9 S/cm and 10 −6 S/cm even after being exposed to 150° C. for up to 24 hours.

First claim

What is claimed is:

1. A thermally-stable static-controlled electronic circuit comprising:
a base structure;
electronic components, disposed on and supported by the base structure; and
a static dissipating coating, conformally covering the base structure and each of the electronic components, wherein:
the static dissipating coating comprises a conductive polymer and a thermally-stable base polymer,
the conductive polymer comprises polyaniline and a conductive agent, selected from the group consisting of dinonylnaphthalene sulfonic acid (DNNSA), dodecyl benzene sulfonic acid (DBSA), camphor sulfonic acid (CSA), and combinations thereof,
the thermally-stable base polymer comprises one or more copolymers of butyl-methacrylate, and
wherein the conductive polymer and the thermally-stable base polymer are both soluble in cymene.

2. The thermally-stable static-controlled electronic circuit of claim 1 , wherein the conductive agent is dinonylnaphthalene sulfonic acid (DNNSA).

3. The thermally-stable static-controlled electronic circuit of claim 1 , wherein the one or more copolymers of butyl-methacrylate in the thermally-stable base polymer comprise poly-butylmethacrylate-co-methyl methacrylate (PBM).

4. The thermally-stable static-controlled electronic circuit of claim 1 , wherein a concentration of the conductive polymer in the static dissipating coating is at or less than 25% by weight.

5. The thermally-stable static-controlled electronic circuit of claim 4 , wherein the concentration of the conductive polymer in the static dissipating coating is between 5% by weight and 20% by weight.

6. The thermally-stable static-controlled electronic circuit of claim 1 , wherein a conductivity of the static dissipating coating is between 10 −9 S/cm and 10 −6 S/cm.

7. The thermally-stable static-controlled electronic circuit of claim 1 , wherein a conductivity of the static dissipating coating varies less than 100 times through an entire volume of the static dissipating coating.

8. The thermally-stable static-controlled electronic circuit of claim 1 , wherein a conductivity of the static dissipating coating varies less than 10 times through an entire volume of the static dissipating coating.

9. The thermally-stable static-controlled electronic circuit of claim 1 , wherein the static dissipating coating is transparent.

10. The thermally-stable static-controlled electronic circuit of claim 1 , wherein the static dissipating coating is substantially free from any metal-based structures and from any carbon-based structures.

11. The thermally-stable static-controlled electronic circuit of claim 1 , wherein the static dissipating coating further comprises an antioxidant agent.

12. The thermally-stable static-controlled electronic circuit of claim 1 , further comprising a ground contact, disposed on and supported by the base structure, wherein the ground contact is electrically insulated from the electronic components, and wherein the static dissipating coating conformally covers the ground contact and provides the static dissipation from each of the electronic components to the ground contact.

13. The thermally-stable static-controlled electronic circuit of claim 1 , wherein the base structure is one of a printed circuit board or a flexible circuit.

14. The thermally-stable static-controlled electronic circuit of claim 1 , wherein the static dissipating coating provides static dissipation to the electronic components while preventing electrical shorts between the electronic components.

15. The thermally-stable static-controlled electronic circuit of claim 1 , wherein resistance of the static dissipating coating changes less than 100 times when subjected to 150° C. for 24 hours.

16. The thermally-stable static-controlled electronic circuit of claim 1 , wherein a conductivity of the static dissipating coating varies less than 100 times through an entire volume of the static dissipating coating.

17. A static dissipating coating for conformal coating over electronic components, the static dissipating coating comprising:
a conductive polymer, comprising polyaniline and a conductive agent, selected from the group consisting of dinonylnaphthalene sulfonic acid (DNNSA), dodecyl benzene sulfonic acid (DBSA), camphor sulfonic acid (CSA), and combinations thereof; and
a thermally-stable base polymer, comprising one or more copolymers of butyl methacrylate, and
wherein the conductive polymer and the thermally-stable base polymer are both soluble in cymene.

18. A method of forming a thermally-stable static-controlled electronic circuit, the method comprising:
providing a conductive polymer and a thermally-stable base polymer, wherein the conductive polymer comprises one or more polyanilines and a conductive agent, selected from the group consisting of dinonylnaphthalene sulfonic acid (DNNSA), dodecyl benzene sulfonic acid (DBSA), camphor sulfonic acid (CSA), and combinations thereof, wherein and the thermally-stable base polymer comprises one or more copolymers of butyl-methacrylate;
forming a static dissipating ink using a solvent, the conductive polymer, and the thermally-stable base polymer, wherein the conductive polymer and the thermally-stable base polymer are both soluble in cymene; and
forming a static dissipating coating using the static dissipating ink, the static dissipating coating is formed over a base structure with electronic components disposed on and supported by the base structure such that the static dissipating coating conformally covers the base structure and each of the electronic components and providing static dissipation to the electronic components while preventing electrical shorts among the electronic components.

19. The method according to claim 18 , wherein forming the static dissipating coating comprises one or more of dip-coating, spray-coating, or 3-D printing.

20. The method according to claim 18 , wherein at least one of the conductive polymer or the thermally-stable base polymer is provided as a polymer solution in a base solvent, the base solvent forming a portion of the static dissipating ink.

Assignees

• Boeing Co

Inventors

• Kinlen Patrick John

Classifications

• H10W70/63

  Vias, e.g. via plugs · CPC title

• H10W90/734

  between a chip and a stacked insulating package substrate, interposer or RDL · CPC title

• H10W42/60

  protecting against electrostatic charges or discharges, e.g. Faraday shields (integrated devices comprising arrangements for electrical protection H10D89/60) · CPC title

• H10W74/47

  comprising organic materials, e.g. plastics or resins · CPC title

• H01B1/128

  comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes · CPC title