Electrically conductive adhesives comprising blend elastomers

Patent metadata

Field	Value
Publication number	US-10032945-B2
Application number	US-201414759927-A
Country	US
Kind code	B2
Filing date	Jan 9, 2014
Priority date	Jan 10, 2013
Publication date	Jul 24, 2018
Grant date	Jul 24, 2018

Abstract

Disclosed herein is an electrically conductive adhesive composition and its use in solar cell modules, wherein the electrically conductive adhesive comprises a polymer matrix and dispersed in the polymer matrix about 40-90 wt % of conductive particles, with the wt % of all components comprised in the compositions totaling to 100 wt %, and wherein the polymer matrix comprises or is formed of a blend of at least one ethylene/alkyl (meth)acrylate copolymer elastomer and at least one ethylene vinyl acetate copolymer at a weight ratio ranging from about 10:90 to about 70:30.

First claim

What is claimed is:

1. A solar cell module comprising at least one solar cell and at least one wiring member,
wherein,
(i) the at least one solar cell has at least one surface electrode and the at least one wiring member is connected to the at least one surface electrode via an electrically conductive adhesive;
(ii) the electrically conductive adhesive is formed of an adhesive composition comprising a polymer matrix and 40-90 wt % of electrically conductive particles dispersed in the polymer matrix, with the wt% of all components comprised in the adhesive composition totaling to 100 wt %; and
(iii)the polymer matrix comprises a polymer blend of at least one ethylene/alkyl (meth)acrylate copolymer elastomer and at least one ethylene/vinyl acetate copolymer at a weight ratio ranging from 10:90 to 70:30;
wherein the at least one ethylene/alkyl (meth)acrylate copolymer elastomer comprises polymerized units of ethylene and 40-90 wt % of polymerized units of at least one alkyl (meth)acrylate, based on the total weight of the ethylene/alkyl (meth)acrylate copolymer elastomer; and
wherein the at least one ethylene/vinyl acetate copolymer comprises polymerized units of ethylene and 5-50 wt % of copolymerized units of vinyl acetates, based on the total weight of the ethylene/vinyl acetate copolymer.

2. The solar cell module of claim 1 , wherein the weight ratio of the at least one ethylene/alkyl (meth)acrylate copolymer elastomer and at least one ethylene/vinyl acetate copolymer ranges from 15:85 to 70:30.

3. The solar cell module of claim 1 , wherein the at least one ethylene/alkyl (meth)acrylate copolymer elastomer is selected form the group consisting of ethylene/methyl (meth)acrylate copolymers, ethylene/ethyl (meth)acrylate copolymers, ethylene/butyl (meth)acrylate copolymers.

4. The solar cell module claim 1 , wherein the at least one ethylene/alkyl (meth)acrylate copolymer elastomer and/or the at least one ethylene/vinyl acetate copolymer is cross-linked with a cross-linking agent.

5. The solar cell module of claim 1 , wherein the electrically conductive particles are selected from metal particles and non-metal particles.

6. The solar cell module of claim 5 , wherein the electrically conductive particles are metal particles selected from particles of Cu, Ag, Ni, or alloys thereof.

7. The solar cell module of claim 5 , wherein the electrically conductive particles are metal particles selected from the group consisting of particles of Au, Ag, Ni, Cu, Al, Sn, Zn, Ti, Sn, Bi, W, Pb, and alloys of two or more thereof.

8. The solar cell module of claim 7 , wherein 40-85 wt % of the electrically conductive particles are dispersed in the polymer matrix, based on the total weight of the adhesive composition.

9. The solar cell module of claim 1 , wherein 40-85 wt % of the electrically conductive particles are dispersed in the polymer matrix, based on the total weight of the adhesive composition.

10. The solar cell module of claim 1 , wherein the at least one solar cell has a front surface electrode and a back surface electrode, and wherein there are one or more front wiring members connected to the front surface electrode via the electrically conductive adhesive and one or more back wiring members connected to the back surface electrode via the electrically conductive adhesive.

11. The solar cell module of claim 10 , wherein the at least one solar cell is a wafer-based solar cell.

12. The solar cell module of claim 10 , wherein the at least one solar cell is a thin film solar cell.

13. The solar cell module of claim 1 , wherein the at least one ethylene/alkyl (meth)acrylate copolymer elastomer comprises polymerized units of ethylene and 50-75 wt % of polymerized units of at least one alkyl (meth)acrylate, based on the total weight of the ethylene/alkyl (meth)acrylate copolymer elastomer.

14. The solar cell module of claim 1 , wherein the at least one ethylene/vinyl acetate copolymer comprises polymerized units of ethylene and 20-45 wt % of copolymerized units of vinyl acetates, based on the total weight of the ethylene vinyl acetate copolymer.

15. The solar cell module claim 1 , wherein the at least one ethylene/alkyl (meth)acrylate copolymer elastomer and/or the at least one ethylene/vinyl acetate copolymer is cross-linked with a cross-linking agent.

16. The solar cell module claim 3 , wherein the at least one ethylene/alkyl (meth)acrylate copolymer elastomer and/or the at least one ethylene/vinyl acetate copolymer is cross-linked with a cross-linking agent.

17. The solar cell module claim 1 , wherein the at least one ethylene/alkyl (meth)acrylate copolymer elastomer and/or the at least one ethylene/vinyl acetate copolymer is cross-linked with a cross-linking agent.

Assignees

• Du Pont
• Du Pont

Inventors

• Mu Minfang
• Liu Zengjun

Classifications

• C08K3/08

  Metals · CPC title

• C08K5/14

  Peroxides · CPC title

• C09J133/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C09J123/0853

  Vinylacetate · CPC title

• C09J9/02

  Electrically-conducting adhesives · CPC title