Magnetic magnesium-manganese layered double metal oxide composite and preparation and application

Patent metadata

Field	Value
Publication number	US-12060283-B2
Application number	US-201917292009-A
Country	US
Kind code	B2
Filing date	Oct 25, 2019
Priority date	Nov 8, 2018
Publication date	Aug 13, 2024
Grant date	Aug 13, 2024

Abstract

A magnetic magnesium-manganese layered double metal oxide composite and preparation and application. A soluble magnesium salt and a soluble manganese salt are dissolved in water to obtain a magnesium-manganese salt complex liquid; and a soluble carbonate and a soluble hydroxide are dissolved in water to obtain a carbonate-hydroxide complex liquid; a ferroferric oxide powder is added to the carbonate-hydroxide complex liquid, and then ethanol is added for ultrasonic dispersion to obtain a dispersion liquid; then the magnesium-manganese salt complex liquid is added for aging, centrifuging, washing, drying, grinding for sieving, and calcinating at 250-550° C. to obtain a magnetic magnesium-manganese layered double metal oxide composite. The composite of the present invention has relatively strong magnetism to Cd removal, and is featured by high adsorption efficiency, rapid adsorption rate and stability. Moreover, the composite can not only immobilize Cd efficiently, but also can be separated and recycled by magnet.

First claim

What is claimed is:

1. A method for preparing a magnetic magnesium-manganese layered double metal oxide composite, comprising the following steps of:
step 1, dissolving a soluble magnesium salt and a manganese salt in water to obtain a magnesium-manganese salt complex liquid; and dissolving a soluble carbonate and a soluble hydroxide in water to obtain a carbonate-hydroxide complex liquid, wherein the manganese salt is a divalent manganese salt;
step 2, adding a ferroferric oxide powder to the carbonate-hydroxide complex liquid to obtain a first solution, and adding ethanol to the first solution to obtain a second solution, and dispersing the ferroferric oxide powder in the second solution by using ultrasonic dispersion to obtain a dispersion liquid, wherein the ferroferric oxide powder is a nanosized powder;
step 3, adding the magnesium-manganese salt complex liquid to the dispersion liquid in step 2 to obtain a third solution, and aging and centrifuging the third solution to obtain a mixture, and washing, drying, grinding and sieving the mixture to obtain a precursor powder; and
step 4, calcinating the precursor powder obtained in step 3 at 250-550° C. to obtain the magnetic magnesium-manganese layered double metal oxide composite.

2. The method for preparing the magnetic magnesium-manganese layered double metal oxide composite according to claim 1 , wherein in the step 1, the magnesium salt is magnesium chloride, magnesium nitrate or magnesium sulfate; the manganese salt is manganese chloride, manganese nitrate or manganese sulfate; the carbonate is sodium carbonate or potassium carbonate; and the hydroxide is sodium hydroxide or potassium hydroxide.

3. The method for preparing the magnetic magnesium-manganese layered double metal oxide composite according to claim 1 , wherein in the step 1, a molar ratio of the magnesium salt to the manganese salt to the carbonate to the hydroxide is (5-60):(5-40):(2-30):(5-60).

4. The method for preparing the magnetic magnesium-manganese layered double metal oxide composite according to claim 1 , wherein in the magnesium-manganese salt complex liquid of the step 1, the magnesium salt has a concentration of 0.03-0.09 mol/L; the manganese salt has a concentration of 0.01-0.045 mol/L; and in the carbonate-hydroxide complex liquid, the carbonate has a concentration of 0.005-0.2 mol/L; and hydroxide has a concentration of 0.005-0.4 mol/L.

5. The method for preparing the magnetic magnesium-manganese layered double metal oxide composite according to claim 1 , wherein a ratio of the mass of the ferroferric oxide to the mole of the carbonate in the step 2 is (0.5-5) g:(0.01-1) mol.

6. The method for preparing the magnetic magnesium-manganese layered double metal oxide composite according to claim 1 , wherein an adding amount of the ethanol in the step 2 is 0.1-2 times a volume of the carbonate-hydroxide complex liquid; and the ultrasonic dispersion time is 10-60 min.

7. The method for preparing the magnetic magnesium-manganese layered double metal oxide composite according to claim 1 , wherein the magnesium-manganese salt complex liquid in the step 3 is added to the dispersion liquid in a way of dropwise adding with a rate of 0.1-5 mL/min; the aging time is 12-36 h; the drying refers to drying for 12-36 h at 50-80° C.; and the grinding for sieving refers to grinding for 100 to 500-mesh sieving.

8. The method for preparing the magnetic magnesium-manganese layered double metal oxide composite according to claim 1 , wherein the calcinating time in the step 4 is 1-5 h.

9. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 1 .

10. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 2 .

11. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 3 .

12. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 4 .

13. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 5 .

14. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 6 .

15. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 7 .

16. A magnetic magnesium-manganese layered double metal oxide composite, prepared by the method according to claim 8 .

Assignees

• Univ South China Tech

Inventors

• Wu Pingxiao
• Chen Meiqing
• Dang Zhi
• Zhu Nengwu

Classifications

• H01F1/0063

  in a non-magnetic matrix, e.g. granular solids (granular films H01F10/007) · CPC title

• C02F2101/20

  Heavy metals or heavy metal compounds · CPC title

• C02F1/62

  Heavy metal compounds · CPC title

• C02F1/481

  using permanent magnets · CPC title

• C01P2006/42

  Magnetic properties · CPC title