Photovoltaic devices and methods of forming the same

Patent metadata

Field	Value
Publication number	US-12021163-B2
Application number	US-201917418532-A
Country	US
Kind code	B2
Filing date	Dec 23, 2019
Priority date	Dec 27, 2018
Publication date	Jun 25, 2024
Grant date	Jun 25, 2024

Abstract

A photovoltaic device includes an electron blocking layer (EBL) and an absorber layer. The EBL is positioned between the absorber layer and a back contact layer. A material of the EBL is a cadmium zinc telluride Cd (1-y) Zn (y) Te, and a material of the absorber layer is a cadmium telluride selenide CdTe (1-x) Se (x) producing a lattice mismatch between the materials of the EBL and between the materials of the absorber of less than about two tenths of a percent when x˜y and has a value less than about 0.4.

First claim

What is claimed is:

1. A photovoltaic device, comprising:
a front layer stack, wherein the front layer stack comprises a plurality of transparent layers;
an absorber layer having a first surface disposed on the front layer stack and a second surface, the absorber layer comprising cadmium, tellurium, and selenium;
an electron blocking layer having a first surface disposed on the second surface of the absorber layer and a second surface, the first surface of the electron blocking layer having a band gap that is at least 0.1 eV greater than a band gap of the second surface the absorber layer; and
a back contact layer disposed on the second surface of the electron blocking layer;

wherein:
the electron blocking layer comprises cadmium, zinc, and tellurium; and
a lattice mismatch between the electron blocking layer relative to the absorber layer is less than 4%

wherein:
the electron blocking layer has a mole ratio of Cd (1-y) Zn (y) Te, where y is in a range from 0.005 to 0.4;
the absorber layer has a mole ratio of CdTe (1-x) Se (x) , where x is in a range from 0.005 to 0.4;
the absorber layer is compositionally graded whereby a value of x is greater at the first surface than at the second surface of the absorber layer; and
the electron blocking layer is compositionally graded, and the value of y is greater at the second surface than at the first surface of the electron blocking layer, and wherein the value of y at the first surface of the electron blocking layer is in a range from 0.15 to 0.30.

2. The photovoltaic device of claim 1 , wherein the lattice mismatch between the electron blocking layer relative to the absorber layer is less than 2%.

3. The photovoltaic device of claim 1 , wherein:
a magnitude of a difference between x and the second surface of the absorber layer and y at the first surface of the electron blocking layer is less than 0.05.

4. The photovoltaic device of claim 3 , wherein x is less than 0.3.

5. The photovoltaic device of claim 1 , wherein the electron blocking layer has a mole ratio of Cd (1-y) Zn (y) Te, wherein y is in a range of 0.1 to 0.4.

6. The photovoltaic device of claim 1 , wherein the absorber layer has a mole ratio of CdTe (1-x) Se (x) , wherein x is a range of 0.1 to 0.4.

7. The photovoltaic device of claim 1 , further comprising a transition layer between the absorber layer and the electron blocking layer, wherein:
the transition layer comprises a quaternary material having a mole ratio of Cd (1-y) Zn (y) Te (1-x) Se (x) ;
y is in a range between about 0.005 to about 0.4; and
x is in a range between about 0.005 to about 0.4.

8. The photovoltaic device of claim 7 , wherein a magnitude of the difference between x and y is less than 0.005 throughout the transition layer.

9. The photovoltaic device of claim 1 , wherein the back contact comprises a zinc telluride layer, and wherein the back contact directly contacts the second surface of the electron blocking layer.

10. A photovoltaic device, comprising:
an electron blocking layer formed from Cd (1-y) Zn (y) Te, wherein y is in a range between about 0.005 to about 0.4; and
an absorber layer formed from CdTe (1-x) Se (x) , wherein x is in a range between about 0.005 to about 0.4; and
wherein a lattice mismatch between the electron blocking layer relative to the absorber layer is less than 4%
wherein:
the absorber layer has a first surface and a second surface, wherein the second surface of the absorber layer is closer to a back contact than the first surface of the absorber layer;
the electron blocking layer is between the absorber layer and the back contact;
the electron blocking layer has a first surface and a second surface, wherein the second surface of the electron blocking layer is closer to the back contact than the first surface of the electron blocking layer;
the absorber layer is compositionally graded and a value of x is greater at the first surface than at the second surface of the absorber layer; and
the electron blocking layer is compositionally graded, and the value of y is greater at the second surface than at the first surface of the electron blocking layer, and wherein the value of y at the first surface of the electron blocking layer is in a range between 0.15 to 0.30.

11. The photovoltaic device of claim 10 , wherein the composition of the electron blocking layer and the absorber layer is selected such that a magnitude of a difference between x and y, at an absorber interface between the absorber layer and the electron blocking layer, is less than 0.005, and wherein the lattice mismatch between the electron blocking layer relative to the absorber layer is less than or equal to 0.2%.

12. The photovoltaic device of claim 10 , further comprising a transition layer between the absorber layer and the electron blocking layer, wherein the transition layer comprises a quaternary material having a mole ratio of Cd (1-y) Zn (y) Te (1-x) Se (x) .

13. The photovoltaic device of claim 10 , further comprising a back contact disposed adjacent the electron blocking layer.

14. The photovoltaic device of claim 13 , wherein the back contact comprises zinc telluride.

15. The photovoltaic device of claim 10 , wherein a lattice mismatch between the electron blocking layer relative to the absorber layer is less than 2%.

16. A photovoltaic device, comprising:
a front layer stack, wherein the front layer stack comprises a plurality of transparent layers;
an absorber layer having a first surface disposed on the front layer stack and a second surface;
an electron blocking layer having a first surface disposed over the second surface of the absorber layer and a second surface, the first surface of the electron blocking layer having a band gap that is at least 0.1 eV greater than a band gap of the second surface the absorber layer;
a back contact layer disposed over the second surface of the electron blocking layer;
wherein:
the electron blocking layer comprises a first polycrystalline material with a first plurality of grains having a zinc-blende structure, wherein the first polycrystalline material comprises cadmium, zinc, and tellurium;
the absorber layer comprises a second polycrystalline material with a second plurality of grains having a zinc-blende structure, wherein the second polycrystalline material comprises cadmium, tellurium, and selenium; and
a lattice mismatch between the electron blocking layer relative to the absorber layer is less than 4%; and

a transition layer between the absorber layer and the electron blocking layer, wherein:
the transition layer comprises a quaternary material having a mole ratio of Cd (1-y) Zn (y) Te (1-x) Se (x) , where y is in a range between about 0.005 to about 0.4, and x is in a range between about 0.005 to about 0.4

wherein:
the absorber layer is compositionally graded, whereby a concentration of selenium is greater at the first surface than at the second surface of the absorber layer;
the electron blocking layer is compositionally graded, whereby a concentration of zinc is greater at the second surface than at the first surface of the electron blocking layer; and
the electron blocking layer has a mole ratio of Cd (1-y) Zn (y) Te, where the value of y at the first surface of the electron blocking layer is in a range between 0.15 to 0.30.

Assignees

• First Solar Inc

Inventors

• Powell Rick
• Choi Jongwoo

Classifications

• H10F71/125

  The active layers comprising only Group II-VI materials, e.g. CdS, ZnS or CdTe · CPC title

• H10F10/162 Primary

  comprising only Group II-VI materials, e.g. CdS/CdTe photovoltaic cells · CPC title

• H10F77/123 Primary

  comprising only Group II-VI materials, e.g. CdS, ZnS or HgCdTe · CPC title

• Y02E10/543

  Solar cells from Group II-VI materials · CPC title

• H01L31/073 Primary

  Electricity · mapped topic