Dielectric composition and multilayered electronic component comprising the same

Patent metadata

Field	Value
Publication number	US-11984267-B2
Application number	US-202217992469-A
Country	US
Kind code	B2
Filing date	Nov 22, 2022
Priority date	Jun 28, 2019
Publication date	May 14, 2024
Grant date	May 14, 2024

Abstract

A dielectric composition includes a main ingredient having a perovskite structure represented by ABO 3 , where A is at least one of Ba, Sr, and Ca and B is at least one of Ti, Zr, and Hf, and a first accessory ingredient. The first accessory ingredient comprises 0.1 mole or more of a rare earth element, 0.02 mole or more of Nb, and 0.25 mole or more and 0.9 mole or less of Mg, a sum of contents of the rare earth element and Nb is 1.5 mole or less.

First claim

What is claimed is:

1. A dielectric composition, comprising:
a main ingredient having a perovskite structure represented by ABO 3 , where A is at least one selected from the group consisting of barium, strontium, and calcium and B is at least one selected from the group consisting of titanium, zirconium, and hafnium, and a first accessory ingredient,
wherein the first accessory ingredient comprises 0.1 mole or more of a rare earth element, 0.02 mole or more of niobium, and 0.25 mole or more of magnesium, based on 100 mole of the main ingredient,
wherein a sum of contents of the rare earth element and Nb is 1.5 mole or less, based on 100 mole of the main ingredient, and
wherein the rare earth element is a rare earth element having a smaller ionic radius than that of Dy selected from the group consisting of scandium (Sc), lanthanum (La), actinium (Ac), cerium (Ce), praseodymium (Pr), neodymium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), holmium (Ho), erbium (Er), thulium (Tm), and ruthenium (Lu).

2. The dielectric composition of claim 1 , wherein the first accessory ingredient comprises 0.25 mole or more and 0.7 mole or less of Mg, based on 100 mole of the main ingredient.

3. The dielectric composition of claim 1 , wherein the dielectric composition further comprises 0.1 to 2.0 mole of oxides or carbonates including at least one selected from the group consisting of manganese, vanadium, chromium, iron, nickel, cobalt, copper, and zinc, based on 100 mole of the main ingredient, as a second accessory ingredient.

4. The dielectric composition of claim 1 , wherein the dielectric composition further comprises 0.001 to 0.5 mole of an oxide including at least one of silicon and aluminum, or a glass compound including Si, based on 100 mole of the main ingredient, as a third accessory ingredient.

5. A multilayer electronic component, comprising:
a body including a dielectric layer and an internal electrode; and
an external electrode disposed on the body and connected to the internal electrode,
wherein the dielectric layer comprises a dielectric composition,
wherein the dielectric composition comprises a main ingredient having a perovskite structure represented by ABO 3 , where A is at least one of barium, strontium, and calcium and B is at least one of titanium, zirconium, and hafnium, and a first accessory ingredient,
wherein the first accessory ingredient comprises 0.1 mole or more of a rare earth element, 0.02 mole or more of niobium, and 0.25 mole or more of magnesium, and a sum of contents of the rare earth element and Nb is 1.5 mole or less, based on 100 mole of the main ingredient,
wherein the rare earth element is a rare earth element having a smaller ionic radius than that of Dy selected from the group consisting of scandium (Sc), lanthanum (La), actinium (Ac), cerium (Ce), praseodymium (Pr), neodymium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), holmium (Ho), erbium (Er), thulium (Tm), and ruthenium (Lu), and
wherein the internal electrode has an average thickness of 0.41 μm or less.

6. The multilayer electronic component of claim 5 , wherein the first accessory ingredient comprises 0.25 mole or more and 0.7 mole or less of Mg, based on 100 mole of the main ingredient.

7. The multilayer electronic component of claim 5 , wherein the dielectric composition further comprises 0.1 to 2.0 mole of oxides or carbonates including at least one selected from the group consisting of manganese, vanadium, chromium, iron, nickel, cobalt, copper and zinc, based on 100 mole of the main ingredient, as a second accessory ingredient.

8. The multilayer electronic component of claim 5 , wherein the dielectric composition further comprises 0.001 to 0.5 mole of an oxide including at least one of Si and Al or a glass compound including Si, based on 100 mole of the main ingredient, as a third accessory ingredient.

9. The multilayer electronic component of claim 5 , wherein the dielectric layer has an average thickness of 0.41 μm or less.

10. The multilayer electronic component of claim 5 , wherein a size of the multilayer electronic component is 1005 (length×width, 1.0 mm×0.5 mm) or less.

11. The multilayer electronic component of claim 5 , wherein the dielectric layer comprises a plurality of crystal grains and grain boundaries disposed between adjacent crystal grains, and the Nb is included in the plurality of crystal grains and the grain boundaries.

12. The multilayer electronic component of claim 5 , wherein the dielectric layer comprises a plurality of crystal grains and a grain boundary disposed between adjacent crystal grains, and an average grain size of the crystal grains is 200 nm or less.

Assignees

• Samsung Electro Mech

Inventors

• Ham Tae Young
• Jo Ji Hong
• Baik Seung In
• Kwon Hyung Soon

Classifications

• H01G4/1227 Primary

  based on alkaline earth titanates · CPC title

• C04B35/4682

  based on BaTiO3 perovskite phase · CPC title

• H01G4/012

  Form of non-self-supporting electrodes · CPC title

• H01G4/248

  the terminals embracing or surrounding the capacitive element, e.g. caps (H01G4/252 takes precedence) · CPC title

• H01G4/30

  Stacked capacitors (H01G4/33 takes precedence) · CPC title