Dielectric film-forming composition

Patent metadata

Field	Value
Publication number	US-11945894-B2
Application number	US-202117352484-A
Country	US
Kind code	B2
Filing date	Jun 21, 2021
Priority date	Jul 2, 2020
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

This disclosure relates to a dielectric film-forming composition that includes at least one cyclized polydiene resin, and one or both of at least one reactive functional compound and at least one catalyst.

First claim

The invention claimed is:

1. A dielectric film-forming composition, comprising:
a) at least one cyclized polydiene resin having a substituted or unsubstituted alkenyl group;
b) at least one reactive functional compound having at least two functional groups capable of reacting with the substituted or unsubstituted alkenyl group on cyclized polydiene resin; and
c) at least one catalyst capable of inducing reaction of the cyclized polydiene resin with the reactive functional compound,
wherein the at least one cyclized polydiene resin is in an amount of from about 2 wt % to about 40 wt % of the composition.

2. The composition of claim 1 , wherein the at least one cyclized polydiene resin comprises a cyclized polyisoprene, a cyclized polybutadiene, a cyclized polypentadiene, or a copolymer thereof.

3. The composition of claim 1 , wherein the at least one cyclized polydiene resin has a weight average molecular weight (Mw) of from at least about 5,000 Daltons to at most about 500,000 Daltons.

4. The composition of claim 1 , wherein the at least one cyclized polydiene resin is a mixture of:
a) a cyclized polydiene resin with a weight average molecular weight of from about 5,000 Daltons to about 20,000 Daltons;
b) a cyclized polydiene resin with a weight average molecular weight of from about 25,000 Daltons to about 60,000 Daltons; and
c) a cyclized polydiene resin with a weight average molecular weight of from about 70,000 Daltons to about 200,000 Daltons.

5. The composition of claim 1 , wherein the dielectric film-forming composition is capable of forming a dielectric film having a Tg of at least about 120° C.

6. The composition of claim 1 , wherein the at least one of the reactive functional compound comprises a compound containing at least two functional groups selected from the groups consisting of a (meth)acrylate group, an olefin group, a cycloolefin group, an alkynyl group, and a combination thereof.

7. The composition of claim 1 , wherein the at least one reactive functional compound is in an amount of from about 1 wt % to about 25 wt % of the composition.

8. The composition of claim 1 , wherein the at least one catalyst is in an amount of from about 0.2 wt % to about 3 wt % of the composition.

9. A dielectric film-forming composition, comprising:
a) at least one cyclized polydiene resin; and
b) at least one cyanate ester compound, the at least one cyanate ester compound comprising at least two cyanate groups.

10. The composition of claim 9 , wherein the at least one cyanate ester compound has Structure (I):
A-(O—CΞN) m   (I),

wherein m is an integer of at least 2 and A is a divalent organic group comprising a substituted or unsubstituted aromatic group.

11. The composition of claim 10 , wherein the at least one cyanate ester compound has Structure (II):

wherein R is a hydrogen atom, a C 1 -C 3 alkyl group, a fully or partially halogen substituted C 1 -C 3 alkyl group, or a halogen atom; and X is a single bond, —O—, —S—, —(C═O)—, —(C═O)—O—, —O—(C═O)—, —(S═O)—, —(SO 2 )—, —CH 2 CH 2 —O—, a substituted or unsubstituted C 1 -C 10 alkylene, a fully or partially fluoro substituted C 1 -C 4 alkylene, a substituted or unsubstituted C 3 -C 10 cycloalkylene, or one of the following groups:

12. The composition of claim 9 , wherein the at least one cyanate ester compound has Structure (II):

wherein n 1 is an integer of at least 2, n 2 and n 3 are independently 0 or an integer from 1 to 100, R 1 is a C 1 -C 10 alkyl or C 1 -C 20 arylalkyl group, R 2 is a substituted or unsubstituted C 1 -C 10 alkyl, a substituted or unsubstituted C 3 -C 10 cycloalkyl, a substituted or unsubstituted aryl group, or a —(C═O)—OR 4 group, in which R 4 is a non-acid sensitive substituted alkyl or arylalkyl group; and
R 3 is a substituted or unsubstituted C 1 -C 10 alkyl, or a fluoro substituted C 1 -C 4 alkyl.

13. The composition of claim 9 , wherein the at least one cyanate ester compound is in an amount of from about 1 wt % to about 25 wt % of the composition.

14. A dielectric film-forming composition, comprising:
a) at least one cyclized polydiene resin having a substituted or unsubstituted alkenyl group;
b) at least one reactive functional compound having at least two functional groups capable of reacting with the substituted or unsubstituted alkenyl group on the cyclized polydiene resin;
c) at least one cyanate ester compound, the at least one cyanate ester compound comprising at least two cyanate groups;
d) at least one catalyst capable of inducing reaction of the cyclized polydiene resin with the reactive functional compound; and
e) optionally, at least one solvent.

Assignees

• Fujifilm Electronic Mat Usa Inc

Inventors

• De Binod B
• Reinerth William A
• Malik Sanjay
• Dilocker Stephanie
• Sakamuri Raj

Classifications

• H10W72/00

  Interconnections or connectors in packages · CPC title

• C09D4/06

  {Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond} in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00 · CPC title

• C08F279/02 Primary

  on to polymers of conjugated dienes · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title

• C08L51/003

  grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds (C08L51/04, C08L51/06 take precedence) · CPC title