Oil well cement composite permeation enhancement agent suitable for hydrate layer and preparation method

Patent metadata

Field	Value
Publication number	US-11866367-B2
Application number	US-202318109859-A
Country	US
Kind code	B2
Filing date	Feb 15, 2023
Priority date	May 7, 2022
Publication date	Jan 9, 2024
Grant date	Jan 9, 2024

Abstract

An oil well cement composite permeation enhancement agent suitable for a hydrate layer and a preparation method thereof are disclosed. In parts by weight, the composition of raw materials of the composite permeation enhancement agent is 4.6 parts-5.0 parts of kerosene, 0.23 parts-0.25 parts of emulsifier, 0.8 parts-1.1 parts of modified polypropylene fiber, 10.0 parts-12.0 parts of porous and permeable microspheres, 1.0 part-1.2 parts of paraffin, and 57.5 parts-62.5 parts of water. The composite permeation enhancement agent can effectively improve the permeability of the cement stone which reshapes the formation framework and increase the mining rate of hydrate. The oil well cement composite permeation enhancement agent has the advantages of long-term performance, low cost, and green environmental protection. The composite permeation enhancement agent of the present invention does not need secondary treatment to increase permeation, the operation is convenient and fast, and the working time of holding pressure is reduced.

First claim

What is claimed is:

1. An oil well cement composite permeation enhancement agent for a hydrate layer, wherein, in parts by weight, a composition of raw materials of the oil well cement composite permeation enhancement agent is 4.6 parts-5.0 parts of kerosene, 0.23 parts-0.25 parts of an emulsifier, 0.8 parts-1.1 parts of a surface-modified polypropylene fiber, 10.0 parts-12.0 parts of porous and permeable microspheres, 1.0 part-1.2 parts of paraffin, and 57.5 parts-62.5 parts of water;
wherein a length of the surface-modified polypropylene fiber is 5 mm-6 mm, a diameter of each of the porous and permeable microspheres is 0.27 mm-0.55 mm, and an aperture of each of the porous and permeable microspheres is 0.15 mm-0.25 mm;
a specific preparation process of the surface-modified polypropylene fiber is as follows: first, swelling a polypropylene fiber with a xylene for 60 min-80 min, then taking it out and filtering to dry to obtain a first resulting fiber; soaking the first resulting fiber in an acetone solution for 3 h-4 h, then washing with a distilled water and drying in an air to obtain a second resulting fiber; followed by soaking the second resulting fiber with a silane coupling agent with a concentration of 50% for 120 min to modify and optimize a surface of the polypropylene fiber to obtain a third resulting fiber; after a modification is completed, washing the third resulting fiber to be neutral with the distilled water and drying to obtain the surface-modified polypropylene fiber; finally, blowing the surface-modified polypropylene fiber into a root shape with an air gun and packing for a set aside.

2. The oil well cement composite permeation enhancement agent for a hydrate layer, wherein the kerosene is a colorless and transparent pure kerosene.

3. The oil well cement composite permeation enhancement agent for a hydrate layer according to claim 1 , wherein the paraffin is a solid paraffin of C18-30.

4. A method for a preparation of the oil well cement composite permeation enhancement agent for the hydrate layer according to claim 1 , comprising specific steps of:
(1) mixing the distilled water with the emulsifier and stirring well, then adding with the kerosene and stirring at a high speed to obtain an emulsion;
(2) heating the paraffin to be a liquid paraffin and immersing hollow porous and permeable microspheres into the liquid paraffin, followed by placing in an open container;
placing the open container in a vacuum chamber, conducting a vacuuming under a negative pressure, wherein a temperature of the vacuum chamber is higher than a melting point of the paraffin; then, refrigerating the hollow porous and permeable microspheres until the liquid paraffin becomes a solid paraffin; wherein the paraffin is stored in a center of the hollow porous and permeable microspheres in a solid form, and paraffin-bearing microspheres are obtained;
(3) adding the surface-modified polypropylene fiber into the emulsion and adding the paraffin-bearing microspheres while stirring to obtain the oil well cement composite permeation enhancement agent.

5. The method for the preparation of the oil well cement composite permeation enhancement agent for the hydrate layer according to claim 4 , wherein a mass fraction of the kerosene in the emulsion is 8%.

6. The method for the preparation of the oil well cement composite permeation enhancement agent for the hydrate layer according to claim 4 , wherein the kerosene is a colorless and transparent pure kerosene.

7. The method for the preparation of the oil well cement composite permeation enhancement agent for the hydrate layer according to claim 4 , wherein the paraffin is a solid paraffin of C18-30.

Assignees

• Univ China Petroleum East China

Inventors

• Lu Chang
• Liu Huajie
• Guo Shenglai
• Bu Yuhuan
• Xiang Changyou
• Wang Qiang
• Guo Xinyang

Classifications

• C04B16/0633 Primary

  Polypropylene · CPC title

• C04B16/085

  expanded in situ, i.e. during or after mixing the mortar, concrete or artificial stone ingredients · CPC title

• C04B40/0039 Primary

  Premixtures of ingredients · CPC title

• C04B2111/00284

  Materials permeable to liquids · CPC title

• C04B14/044

  Polysilicates, e.g. geopolymers · CPC title