Method of producing cobalt-coated precursor, cobalt-coated precursor produced thereby, and positive electrode active material prepared using same
US-11031593-B2 · Jun 8, 2021 · US
US11767230B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11767230-B2 |
| Application number | US-201816762721-A |
| Country | US |
| Kind code | B2 |
| Filing date | Nov 21, 2018 |
| Priority date | Nov 21, 2017 |
| Publication date | Sep 26, 2023 |
| Grant date | Sep 26, 2023 |
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A positive electrode active material precursor is provided, which includes a transition metal hydroxide particle represented by Formula 1 and a cobalt oxide particle and a manganese oxide particle attached to the surface of the transition metal hydroxide particle. A preparation method thereof, a positive electrode active material prepared using the same, a positive electrode including the positive electrode active material, and a secondary battery including the positive electrode are also provided.
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The invention claimed is: 1. A positive electrode active material precursor comprising: a transition metal hydroxide particle represented by Formula 1 below; and a cobalt oxide particle and a manganese oxide particle directly attached to a surface of the transition metal hydroxide particle: [Ni a Co b M 1 c M 2 d ](OH) 2 [Formula 1] wherein, 0.8≤a<1, 0<b<0.2, 0≤c≤0.1, and 0≤d≤0.1, M 1 is one or more selected from the group consisting of Mn and Al, and M 2 is one or more selected from the group consisting of Ba, Ca, Zr, Ti, Mg, Ta, Nb, and Mo. 2. The positive electrode active material precursor of claim 1 , wherein the positive electrode active material precursor, which includes the transition metal hydroxide particle represented by formula 1, the cobalt oxide particle, and the manganese oxide particle, includes cobalt in an amount of 10-18000 ppm based on a total weight of the positive electrode active material precursor. 3. The positive electrode active material precursor of claim 1 , wherein the positive electrode active material precursor, which includes the transition metal hydroxide particle represented by formula 1, the cobalt oxide particle, and the manganese oxide particle, includes manganese in an amount of 10-12000 ppm based on total weight of the positive electrode active material precursor. 4. The positive electrode active material precursor of claim 1 , wherein the positive electrode active material precursor, which includes the transition metal hydroxide particle represented by formula 1, the cobalt oxide particle, and the manganese oxide particle, has a weight ratio of cobalt:manganese of 6:4 to 8:2. 5. The positive electrode active material precursor of claim 1 , wherein a molar ratio of nickel and cobalt elements in the transition metal hydroxide particle are constant.
Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements · CPC title
Chemistry & Metallurgy · mapped topic
Oxides · CPC title
oxides · CPC title
Positive electrodes · CPC title
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