Rare earth regenerator material particle, rare earth regenerator material particle group, and cold head, superconducting magnet, examination apparatus, and cryopump using the same

Patent metadata

Field	Value
Publication number	US-11692117-B2
Application number	US-202117240687-A
Country	US
Kind code	B2
Filing date	Apr 26, 2021
Priority date	Oct 9, 2012
Publication date	Jul 4, 2023
Grant date	Jul 4, 2023

Abstract

A rare earth regenerator material particle and a regenerator material particle group having a high long-term reliability, and a superconducting magnet, an examination apparatus, a cryopump and the like using the same are provided. A rare earth regenerator material particle contains a rare earth element as a constituent component, and in the particle, a peak indicating a carbon component is detected in a surface region by an X-ray photoelectron spectroscopy analysis.

First claim

What is claimed is:

1. A pulse type refrigerator, comprising:
a regenerator container; and
a plurality of regenerator material particle groups which are different in kind, and are filled in the regenerator container while being divided from each other,
wherein at least one of the plurality of regenerator material particle groups comprises a rare earth generator material particle containing a rare earth element,
a peak indicating a carbon component and a peak indicating a compound containing the rare earth element and oxygen are detected in a surface region of the rare earth generator material particle by an X-ray photoelectron spectroscopy analysis,
an entire content of carbon in the rare earth generator material particle including the carbon component is 5 mass ppm or more and 100 mass ppm or less, and
the carbon component detected in the surface region of the rare earth generator material particle has at least one selected from the group consisting of a C—C bond, a C—H bond, a C—O bond, a C=O bond, and an O—C=O bond.

2. The refrigerator according to claim 1 , wherein the rare earth generator material particle comprises an intermetallic compound represented by a composition formula of RMa, wherein R is at least one element selected from the group consisting of rare earth elements, M is at least one element selected from the group consisting of Cu, Ni, and Co, and a is a number (atomic ratio) satisfying 0.1≤a≤4.0.

3. The refrigerator according to claim 2 , wherein a peak indicating a compound of the M element and oxygen are detected in the surface region of the rare earth generator material particle by the X-ray photoelectron spectroscopy analysis.

4. The refrigerator according to claim 3 , wherein a ratio (A/B) of an atomicity A of the rare earth element in the compound of the rare earth element and oxygen to an atomicity B of the M element in the compound of the M element and oxygen exceeds the value of the a.

5. The refrigerator according to claim 2 , wherein the intermetallic compound is at least one selected from the group consisting of HoCu 2 , HoCu, Er 3 Ni, ErNi, and Er 3 Co.

6. The refrigerator according to claim 1 , wherein the plurality of regenerator material particle groups are divided by a metal mesh material.

7. The refrigerator to claim 6 , wherein the metal mesh material is a copper mesh material.

8. The refrigerator according to claim 1 , wherein the plurality of regenerator material particle groups comprises a first regenerator material particle group comprising a lead regenerator material particle, and a second regenerator material particle group comprising the rare earth generator material particle.

9. The refrigerator according to claim 1 , wherein the plurality of regenerator material particle groups comprises a first regenerator material particle group comprising the rare earth generator material particle, and a second regenerator material particle group comprising a gadolinium oxysulfide regenerator material particle.

10. The refrigerator according to claim 1 , wherein the plurality of regenerator material particle groups comprises a first regenerator material particle group comprising a lead regenerator material particle, a second regenerator material particle group comprising the rare earth generator material particle group, and a third regenerator material particle group comprising a gadolinium oxysulfide regenerator material particle.

Assignees

• Toshiba Kk
• Toshiba Materials Co Ltd

Inventors

• Yamada Katsuhiko
• Fuse Keiichi

Classifications

• C22C1/047

  comprising intermetallic compounds {(C22C1/0441 takes precedence)} · CPC title

• C09K5/14 Primary

  Solid materials, e.g. powdery or granular · CPC title

• B22F9/08

  by casting, e.g. through sieves or in water, by atomising or spraying (using electric discharge B22F9/14) · CPC title

• F17C5/00

  Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures (adding propellants to aerosol containers B65B31/00) · CPC title

• C22C1/0425

  Copper-based alloys · CPC title