Rare earth regenerator material particle, rare earth regenerator material particle group, and cold head, superconducting magnet, examination apparatus, and cryopump using the same

Patent metadata

Field	Value
Publication number	US-10047265-B2
Application number	US-201514680306-A
Country	US
Kind code	B2
Filing date	Apr 7, 2015
Priority date	Oct 9, 2012
Publication date	Aug 14, 2018
Grant date	Aug 14, 2018

Abstract

A rare earth regenerator material particle and a regenerator material particle group having a high long-term reliability, and a superconducting magnet, an examination apparatus, a cryopump and the like using the same are provided. A rare earth regenerator material particle contains a rare earth element as a constituent component, and in the particle, a peak indicating a carbon component is detected in a surface region by an X-ray photoelectron spectroscopy analysis.

First claim

What is claimed is:

1. A rare earth regenerator material particle, comprising a rare earth element as a constituent component,
wherein a peak indicating a carbon component and a peak indicating a compound containing the rare earth element and oxygen are detected in a surface region of the particle by an X-ray photoelectron spectroscopy analysis,
an entire content of carbon in the particle including the carbon component is 5 mass ppm or more and 50 mass ppm or less, and
the carbon component detected in the surface region of the particle has at least one selected from the group consisting of a C—C bond, a C—H bond, a C—O bond, a C═O bond, and an O—C═O bond.

2. The particle according to claim 1 , comprising an intermetallic compound represented by a composition formula of RMa, wherein R is at least one element selected from the group consisting of rare earth elements, M is at least one element selected from the group consisting of Cu, Ni, and Co, and a is a number (atomic ratio) satisfying 0.1≤a≤4.0.

3. The particle according to claim 2 , wherein a peak indicating a compound of the rare earth element and oxygen and a peak indicating a compound of the M element and oxygen are detected in the surface region by the X-ray photoelectron spectroscopy analysis.

4. The particle according to claim 2 , wherein a ratio (A/B) of an atomicity A of the rare earth element in a compound of the rare earth element and oxygen to an atomicity B of the M element in a compound of the M element and oxygen exceeds the value of the a.

5. The particle according to claim 2 , wherein the intermetallic compound is at least one selected from the group consisting of HoCu 2 , HoCu, Er 3 Ni, ErNi, and Er 3 Co.

6. The particle according to claim 2 , wherein the intermetallic compound is HoCu 2 , and a reflectance of light with a wavelength of 600 nm in the particle is 20% or more.

7. A rare earth regenerator material particle group, comprising a plurality of the rare earth regenerator material particles according to claim 1 .

8. The particle group according to claim 7 , wherein a ratio of the particle in which a form factor R represented by L 2 /4πA exceeds 1.5 is 5% or less, wherein L is a circumferential length of a projected image of the particle, and A is an actual area of the projected image.

9. A cold head, comprising the rare earth regenerator material particle group according to claim 7 .

10. A cold head, comprising:
a first stage having a regenerator material; and
a second stage having a plurality of regenerator material-filled layers in which different compounds of regenerator material particle groups are respectively filled,
wherein at least one of the regenerator material-filled layers is provided with the rare earth regenerator material particle group according to claim 7 .

11. A superconducting magnet, comprising the cold head according to claim 9 .

12. An examination apparatus, comprising the cold head according to claim 9 .

13. A cryopump, comprising the cold head according to claim 9 .

Assignees

• Toshiba Kk
• Toshiba Materials Co Ltd
• Toshiba Materials Co Ltd

Inventors

• Yamada Katsuhiko
• Fuse Keiichi

Classifications

• B22F9/08

  by casting, e.g. through sieves or in water, by atomising or spraying (using electric discharge B22F9/14) · CPC title

• C09K5/00 Primary

  Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion · CPC title

• F17C5/00

  Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures (adding propellants to aerosol containers B65B31/00) · CPC title

• F25B9/00

  Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point · CPC title

• C09K5/14 Primary

  Solid materials, e.g. powdery or granular · CPC title