Rare earth regenerator material particle, rare earth regenerator material particle group, and cold head, superconducting magnet, examination apparatus, and cryopump using the same

Patent metadata

Field	Value
Publication number	US-11015101-B2
Application number	US-201916545318-A
Country	US
Kind code	B2
Filing date	Aug 20, 2019
Priority date	Oct 9, 2012
Publication date	May 25, 2021
Grant date	May 25, 2021

Abstract

A rare earth regenerator material particle and a regenerator material particle group having a high long-term reliability, and a superconducting magnet, an examination apparatus, a cryopump and the like using the same are provided. A rare earth regenerator material particle contains a rare earth element as a constituent component, and in the particle, a peak indicating a carbon component is detected in a surface region by an X-ray photoelectron spectroscopy analysis.

First claim

What is claimed is:

1. A G-M type refrigerator, comprising:
a regenerator container;
a first regenerator material particle group filled in the regenerator container; and
a second regenerator material particle group filled in the regenerator container and divided with the first regenerator material particle group by a metal mesh material, and having a specific heat peak temperature lower than that of the first regenerator material particle group,
wherein a regenerator material particle constituting at least one of the first and second regenerator material particle groups is a rare earth generator material particle comprising a rare earth element as a constituent component,
a peak indicating a carbon component and a peak indicating a compound containing the rare earth element and oxygen are detected in a surface region of the rare earth generator material particle by an X-ray photoelectron spectroscopy analysis,
an entire content of carbon in the rare earth generator material particle including the carbon component is 5 mass ppm or more and 100 mass ppm or less, and
the carbon component detected in the surface region of the rare earth generator material particle has at least one selected from the group consisting of a C—C bond, a C—H bond, a C—O bond, a C═0 bond, and an O—C═O bond.

2. The refrigerator according to claim 1 , wherein the rare earth generator material particle comprises an intermetallic compound represented by a composition formula of RMa, wherein R is at least one element selected from the group consisting of rare earth elements, M is at least one element selected from the group consisting of Cu, Ni, and Co, and a is a number (atomic ratio) satisfying 0.1≤a≤4.0.

3. The refrigerator according to claim 2 , wherein a peak indicating a compound of the M element and oxygen are detected in the surface region by the X-ray photoelectron spectroscopy analysis.

4. The refrigerator according to claim 3 , wherein a ratio (A/B) of an atomicity A of the rare earth element in the compound of the rare earth element and oxygen to an atomicity B of the M element in the compound of the M element and oxygen exceeds the value of the a.

5. The refrigerator according to claim 2 , wherein the intermetallic compound is at least one selected from the group consisting of HoCu2, HoCu, Er3Ni, ErNi, and Er3Co.

6. The refrigerator according to claim 5 , wherein the intermetallic compound is HoCu2, and a reflectance of light with a wavelength of 600 nm in the particle is 20% or more.

7. The refrigerator to claim 1 , wherein the metal mesh material is a copper mesh material.

8. The refrigerator according to claim 1 , wherein the first regenerator material particle group is a lead regenerator material particle group, and the second regenerator material particle group is a rare earth generator material particle group which is made of the rare earth generator material particle.

9. The refrigerator according to claim 1 , wherein the first regenerator material particle group is a rare earth generator material particle group which is made of the rare earth generator material particle, and the second regenerator material particle group is a gadolinium oxysulfide regenerator material particle group.

10. The refrigerator according to claim 1 , wherein the refrigerator is configured to realize a temperature of 10 K or less.

Assignees

• Toshiba Kk
• Toshiba Materials Co Ltd

Inventors

• Yamada Katsuhiko
• Fuse Keiichi

Classifications

• C09K5/08

  Materials not undergoing a change of physical state when used (C09K5/16, C09K5/20 take precedence) · CPC title

• C09K5/14 Primary

  Solid materials, e.g. powdery or granular · CPC title

• F17C5/00

  Methods or apparatus for filling containers with liquefied, solidified, or compressed gases under pressures (adding propellants to aerosol containers B65B31/00) · CPC title

• F25B9/00

  Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point · CPC title

• C09K5/00 Primary

  Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion · CPC title