Methods of forming near-net fiber reinforced thermoplastic composite components

Patent metadata

Field	Value
Publication number	US-11584044-B2
Application number	US-201916555762-A
Country	US
Kind code	B2
Filing date	Aug 29, 2019
Priority date	Aug 29, 2019
Publication date	Feb 21, 2023
Grant date	Feb 21, 2023

Abstract

A method is provided for forming a near-net thermoplastic composite component includes co-spraying a mixture comprising a thermoplastic polymer material and a chopped reinforcing material deposited onto at least one region associated with a tool having a first temperature and defining a near-net component shape. The mixture and adjacent tool is heated to a second temperature while the mixture is on the tool. The first temperature is below the solidification temperature of the thermoplastic polymer material and the second temperature is above the solidification temperature. Then, the mixture is exposed to a negative pressure to promote removal of gases from the mixture and put under compressive force to densify the mixture. The thermoplastic polymer material melts and flows. The tool is cooled to the first temperature and removing the mixture to form the near-net thermoplastic composite component having randomly oriented chopped reinforcement material distributed within a thermoplastic polymer matrix.

First claim

What is claimed is:

1. A method of forming a near-net thermoplastic composite component comprising:
co-spraying a mixture comprising a thermoplastic polymer material and a chopped reinforcing material to directly deposit the mixture onto at least one region associated with a tool having a first temperature and defining a near-net component shape;
heating the mixture to a second temperature while the mixture is on the tool, wherein the first temperature is below the solidification temperature of the thermoplastic polymer material and the second temperature is above a solidification temperature of the thermoplastic polymer material, so that the thermoplastic polymer material flows;
exposing the mixture on the tool to a negative pressure to promote removal of gases from the mixture;
applying compressive force to the mixture; and
cooling the tool to the first temperature and removing the mixture to form the near-net thermoplastic composite component having randomly oriented chopped reinforcement material distributed within a thermoplastic polymer matrix.

2. The method of claim 1 , wherein the at least one region associated with a tool comprises a first region and a second distinct region, wherein the mixture is deposited onto the first region to define a first material composition and the mixture is deposited onto the second distinct region to define a second material composition, and wherein the first material composition and the second material composition are distinct from one another.

3. The method of claim 1 , further comprising heating the tool to the first temperature.

4. The method of claim 1 , wherein the heating the mixture to the second temperature comprises inductively heating a surface of the tool so that the thermoplastic polymer material melts and flows during the applying compressive force to the mixture.

5. The method of claim 1 , wherein the heating the mixture to the second temperature comprises heating the mixture with one or more infrared heaters so that the thermoplastic polymer material melts and flows during the applying compressive force to the mixture, wherein the one or more infrared heaters are movable relative to the tool and are moved over the tool after the co-spraying and removed prior to the applying compressive force to the mixture.

6. The method of claim 1 , wherein the tool comprises at least two complementary parts that are closed and sealed together prior to the exposing the mixture on the tool to the negative pressure and the applying compressive force to the mixture.

7. The method of claim 1 , wherein the chopped reinforcing material is selected from the group consisting of: carbon, glass, basalt, polyparaphenylene terephthalamide, hemp, kenaf, and combinations thereof and the thermoplastic polymer is selected from the group consisting of: nylon 6, nylon 66, nylon 12, polyethylene, polypropylene, polycarbonate, polyacrylates, polymethylmethacrylate, acrylonitrile-butadiene-styrene (ABS), polycarbonate and acrylonitrile-butadiene-styrene blend (PC-ABS), polybutylene terephthalate and polycarbonate blend (PBT and PC), polyphenylene oxide, polyetherimide, and combinations thereof.

8. The method of claim 1 , wherein the thermoplastic polymer material is in the form of a powder having an average particle diameter of greater than or equal to about 0.3 μm to less than or equal to about 300 μm.

9. The method of claim 1 , wherein an amount of a thermoplastic polymer matrix in the near-net thermoplastic composite component is greater than or equal to about 40 volume % to less than or equal to about 95 volume %.

10. The method of claim 1 , wherein the thermoplastic polymer material and the chopped reinforcing material are electrostatically charged during the co-spraying to facilitate the depositing onto the at least one region associated with the tool.

11. The method of claim 1 , wherein the co-spraying comprises:
spray chopping the mixture comprising the thermoplastic polymer material and the chopped reinforcing material is directly deposited onto the at least one region associated with the tool having the first temperature.

12. The method of claim 11 , wherein the spray chopping comprises feeding the thermoplastic polymer material as a powder into a spray chop gun and also feeding a fiber of the chopped reinforcing material into the spray chop gun to form the chopped reinforcing material that is directly deposited onto at least one region.

13. The method of claim 11 , wherein the spray chopping comprises feeding a string of thermoplastic polymer material into a spray chop gun and also feeding a fiber of the chopped reinforcing material into the spray chop gun that forms chopped thermoplastic polymer material and the chopped reinforcing material is directly deposited onto the at least one region.

14. The method of claim 13 , wherein a first diameter of the string of the thermoplastic polymer material is greater than or equal to about 0.5 to less than or equal to about 3 times a second diameter of the fiber of the chopped reinforcing material.

15. The method of claim 11 , wherein the chopped reinforcing material is selected from the group consisting of: carbon, glass, basalt, polyparaphenylene terephthalamide, hemp, kenaf, and combinations thereof and the thermoplastic polymer is selected from the group consisting of: nylon 6, nylon 66, nylon 12, polyethylene, polypropylene, polycarbonate, polyacrylates, polymethylmethacrylate, acrylonitrile-butadiene-styrene (ABS), polycarbonate and acrylonitrile-butadiene-styrene blend (PC-ABS), polybutylene terephthalate and polycarbonate blend (PBT and PC), poly phenylene oxide, polyetherimide, and combinations thereof.

16. The method of claim 11 , wherein the thermoplastic polymer material and the chopped reinforcing material are electrostatically charged during the spray chopping to facilitate the direct depositing onto the at least one region associated with the tool.

17. The method of claim 2 , wherein the first material composition comprises a first chopped reinforcing material having a first length and the second material composition comprises a second chopped reinforcing material having a second length that is different from the first length.

18. The method of claim 2 , wherein the first material composition comprises a first volume percent of the thermoplastic polymer material and a second volume percent of the chopped reinforcing material and the second material composition comprises a third volume percent of the thermoplastic polymer material and a fourth volume percent of the chopped reinforcing material, and wherein the first volume percent and the third volume percent of the thermoplastic polymer material are different and the second volume percent and the fourth volume percent of the chopped reinforcing material are different.

19. The method of claim 2 , wherein the first material composition is deposited at a first thickness and the second material composition is deposited at a second thickness that is different from the first thickness.

20. The method of claim 2 , wherein the first material composition comprises a first chopped reinforcing material and the second material composition comprises a second chopped reinforcing material that is different from the first chopped reinforcing material.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Shah Bhavesh
• Rodgers William R
• Voss Mark A
• Wathen Terrence

Classifications

• B29C35/0805 Primary

  using electromagnetic radiation · CPC title

• B29C2035/0283

  Thermal pretreatment of the plastics material · CPC title

• B29C70/46

  using matched moulds, e.g. for deforming sheet moulding compounds [SMC] or prepregs · CPC title

• B29C2035/1616

  using liquids · CPC title

• B29C35/02

  Heating or curing, e.g. crosslinking or vulcanizing {during moulding, e.g. in a mould}(cold vulcanisation B29C35/18 {; vulcanising tyres, presses therefor B29D30/0601}) · CPC title