Modification of continuous carbon fibers during precursor formation for composites having enhanced moldability

Patent metadata

Field	Value
Publication number	US-9896783-B2
Application number	US-201514849010-A
Country	US
Kind code	B2
Filing date	Sep 9, 2015
Priority date	Sep 9, 2015
Publication date	Feb 20, 2018
Grant date	Feb 20, 2018

Abstract

Methods of producing continuous carbon fibers for composites having enhanced moldability are provided. Discrete regions are introduced into a continuous precursor fiber comprising an acrylic polymer material, such as polyacrylonitrile (PAN), as the precursor fiber is formed. The precursors may be heterogeneous fibers having a second distinct material interspersed in discrete regions with the acrylic polymer material. Alternatively, the precursors may be heterogeneous fibers where laser is applied to the acrylic polymer material in discrete regions to cause localized molecular disruptions. After the continuous precursor fiber is heated for carbonization and/or graphitization, the precursor forms a continuous carbon fiber having a plurality of discrete weak regions. These relatively weak regions provide noncontiguous break points that reduce stiffness and improve moldability for carbon fiber polymeric composites, while retaining high strength levels. Carbon fiber polymeric composites incorporating continuous carbon fibers having the plurality of discrete noncontiguous weak regions are also provided.

First claim

What is claimed is:

1. A method of producing a continuous carbon fiber for use in composites having enhanced moldability, the method comprising:
incorporating a plurality of discrete regions into a continuous heterogeneous precursor fiber comprising a polymer material by co-spinning a first polymeric and a second distinct polymeric material together to form a stream of a first polymeric material having a second distinct polymeric material intermittently introduced into the stream to form the continuous heterogeneous precursor fiber,
wherein after the continuous heterogeneous precursor fiber is heated for carbonization and graphitization, the continuous heterogeneous precursor fiber forms a continuous heterogeneous carbon fiber having a plurality of discrete weak regions corresponding to the plurality of discrete regions.

2. The method of claim 1 , wherein the first polymeric material is an acrylic polymer material.

3. The method of claim 2 , wherein the second distinct polymeric material is selected from the group consisting of: lignin, polyethylene, polystyrene, polymers comprising submicron filler particles, and combinations thereof.

4. The method of claim 1 , wherein the first polymeric material is an acrylic copolymer formed from an acrylonitrile monomer and a second monomer selected from the group consisting of: acrylic acid, itaconic acid, methacrylic acid, vinyl esters, vinyl amides, vinyl halides, salts of vinyl compounds, salts of sulfonic acids, and combinations thereof.

5. The method of claim 1 , wherein the plurality of weak regions has an ultimate tensile strength that is at least 50% less than an ultimate tensile strength of a remainder of the continuous heterogeneous carbon fiber.

6. The method of claim 1 , wherein each respective discrete weak region of the plurality of weak regions has a length of less than or equal to about 2 inches.

7. The method of claim 1 , wherein each respective region of the plurality of weak regions is spaced apart from an adjacent weak region in the continuous heterogeneous carbon fiber by a distance of greater than or equal to about 0.1 inches to less than or equal to about 12 inches.

8. The method of claim 1 , wherein the continuous heterogeneous carbon fiber formed is a plurality of continuous heterogeneous carbon fibers each having an average length of greater than or equal to about 2 inches.

9. A method of producing a continuous carbon fiber for use in composites having enhanced moldability, the method comprising:
incorporating a plurality of discrete regions into a continuous precursor fiber comprising a polymer material that is an acrylic polymer material by forming a stream of the acrylic polymer material and intermittently introducing a second distinct polymeric material into the stream to form a heterogeneous precursor fiber, wherein the intermittently introducing comprises co-spinning the acrylic polymer material and the second distinct polymeric material in a system comprising a pan spinneret and an internal dispersing spinneret so that the second distinct polymeric material is intermittently introduced into the stream of the acrylic polymer exiting the pan spinneret by rotating the internal dispersing spinneret during the co-spinning, wherein after the heterogeneous precursor fiber is heated for carbonization and graphitization, the heterogeneous precursor fiber forms a continuous carbon fiber having a plurality of discrete weak regions corresponding to the plurality of discrete regions.

10. The method of claim 9 , wherein the second distinct polymeric material is selected from the group consisting of: lignin, polyethylene, polystyrene, polymers comprising submicron filler particles, and combinations thereof.

11. The method of claim 9 , wherein the polymer material is an acrylic copolymer formed from an acrylonitrile monomer and a second monomer selected from the group consisting of: acrylic acid, itaconic acid, methacrylic acid, vinyl esters, vinyl amides, vinyl halides, salts of vinyl compounds, salts of sulfonic acids, and combinations thereof.

12. The method of claim 9 , wherein the plurality of weak regions has an ultimate tensile strength that is at least 50% less than an ultimate tensile strength of a remainder of the continuous carbon fiber.

13. The method of claim 9 , wherein each respective discrete weak region of the plurality of weak regions has a length of less than or equal to about 2 inches.

14. The method of claim 9 , wherein the continuous carbon fiber formed is a plurality of continuous carbon fibers each having an average length of greater than or equal to about 2 inches and wherein each respective region of the plurality of weak regions is spaced apart from an adjacent weak region in the continuous carbon fiber by a distance of greater than or equal to about 0.1 inches to less than or equal to about 12 inches.

15. A method of producing a continuous carbon fiber for use in composites having enhanced moldability, the method comprising:
incorporating a plurality of discrete regions into a continuous precursor fiber comprising a polymer material, wherein the incorporating of the plurality of discrete regions into the continuous precursor fiber further comprises:
spinning a feedstock comprising the polymer material and a solvent; and
applying laser energy in the plurality of discrete regions of streams of the feedstock to accelerate volatilization of the solvent, wherein the plurality of discrete regions has a different molecular organization than the remainder of the continuous precursor fiber formed after solvent has been removed, wherein after the continuous precursor fiber is heated for carbonization and graphitization, the continuous precursor fiber forms a continuous carbon fiber having a plurality of discrete weak regions corresponding to the plurality of discrete regions.

16. The method of claim 15 , wherein the polymer material is an acrylic copolymer formed from an acrylonitrile monomer and a second monomer selected from the group consisting of: acrylic acid, itaconic acid, methacrylic acid, vinyl esters, vinyl amides, vinyl halides, salts of vinyl compounds, salts of sulfonic acids, and combinations thereof.

17. The method of claim 15 , wherein the plurality of weak regions has an ultimate tensile strength that is at least 50% less than an ultimate tensile strength of a remainder of the continuous carbon fiber.

18. The method of claim 15 , wherein each respective discrete weak region of the plurality of weak regions has a length of less than or equal to about 2 inches.

19. The method of claim 15 , wherein the continuous carbon fiber formed is a plurality of continuous carbon fibers each having an average length of greater than or equal to about 2 inches and wherein each respective region of the plurality of weak regions is spaced apart from an adjacent weak region in the continuous carbon fiber by a distance of greater than or equal to about 0.1 inches to less than or equal to about 12 inches.

Assignees

• Gm Global Tech Operations Llc

Inventors

• Kia Hamid G

Classifications

• D01F9/225

  from stabilised polyacrylonitriles · CPC title

• D01F9/21 Primary

  from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds · CPC title

• D01F6/54

  of polymers of unsaturated nitriles · CPC title

• D01F9/22 Primary

  from polyacrylonitriles · CPC title

• D10B2101/00

  Inorganic fibres · CPC title