Binder for non-aqueous electrolyte rechargeable battery, negative electrode slurry for rechargeable battery including the same, negative electrode for rechargeable battery including the same, and rechargeable battery including the same

Patent metadata

Field	Value
Publication number	US-11575133-B2
Application number	US-202016857809-A
Country	US
Kind code	B2
Filing date	Apr 24, 2020
Priority date	Apr 26, 2019
Publication date	Feb 7, 2023
Grant date	Feb 7, 2023

Abstract

An embodiment provides a binder for a non-aqueous electrolyte rechargeable battery including a copolymer (A) and a copolymer (B), wherein the copolymer (A) includes a unit (a-1) derived from a (meth)acrylic acid-based monomer, and a unit (a-2) derived from a (meth)acrylonitrile monomer, and the copolymer (B) includes a unit (b-1) derived from an aromatic vinyl-based monomer; and a unit (b-2) derived from an ethylenic unsaturated monomer which is at least one of an unsaturated carboxylic acid alkylester monomer, a (meth)acrylic acid-based monomer, a unsaturated carboxylic acid amide monomer, or combinations thereof.

First claim

What is claimed is:

1. A binder for a non-aqueous electrolyte rechargeable battery, comprising a copolymer (A) and a copolymer (B),
the copolymer (A) comprises a unit (a-1) derived from a (meth)acrylic acid-based monomer, and a unit (a-2) derived from a (meth)acrylonitrile monomer, and
the copolymer (B) comprises a unit (b-1) derived from an aromatic vinyl-based monomer; and a unit (b-2) derived from an ethylenic unsaturated monomer which is at least one of an unsaturated carboxylic acid alkylester monomer, a (meth)acrylic acid-based monomer, an unsaturated carboxylic acid amide monomer, or combinations thereof,
wherein the unit (a-2) derived from a (meth)acrylonitrile monomer is included in an amount of about 35 wt % to about 65 wt %, based on 100 wt % of the copolymer (A).

2. The binder of claim 1 , wherein the copolymer (A) further comprises a unit (a-3) derived from another monomer copolymerizable with the (meth)acrylic acid-based monomer and/or (meth)acrylonitrile monomer.

3. The binder of claim 1 , wherein the unit (a-1) derived from the (meth)acrylic acid-based monomer is included in an amount of about 35 wt % to about 65 wt %.

4. The binder of claim 2 , wherein the unit (a-3) derived from another monomer copolymerizable with the (meth)acrylic acid-based monomer and/or (meth)acrylonitrile monomer is included in an amount of greater than about 0 wt % and less than or equal to about 20 wt % based on 100 wt % of the copolymer (A).

5. The binder of claim 1 , wherein the binder has a particle shape.

6. The binder of claim 1 , wherein at least a portion of the copolymer (B) is surrounded by the copolymer (A).

7. The binder of claim 1 , wherein the copolymer (A) is included in an amount of about 50 parts by weight to about 95 parts by weight based on 100 parts by weight of the copolymer (B).

8. The binder of claim 1 , wherein the (meth)acrylic acid-based monomer is at least one of (meth)acrylic acid, an alkali metal salt of (meth)acrylic acid, an ammonium salt of (meth)acrylic acid, or combinations thereof.

9. The binder of claim 1 , wherein when the copolymer (A) is present in an aqueous solution at a solid content of about 7 wt %, a viscosity of the aqueous solution is in a range of about 500 mPa·s to about 3000 mPa·s.

10. The binder of claim 1 , wherein when the copolymer (B) is present in an aqueous solution at a solid content of about 7 wt %, a viscosity of the aqueous solution is in a range of about 500 mPa·s to about 3000 mPa·s.

11. The binder of claim 1 , wherein the unit (b-2) derived from an ethylenic unsaturated monomer is included in an amount of greater than or equal to about 5 wt % based on 100 wt % of the copolymer (B).

12. The binder of claim 1 , wherein the glass transition temperature of the copolymer (B) is in a range of about 15° C. to about 100° C.

13. A negative electrode slurry for a rechargeable battery comprising
the binder for the non-aqueous electrolyte rechargeable battery of claim 1 and a negative active material, and
the negative active material includes an active material comprising a silicon atom.

14. A negative electrode for a rechargeable battery, comprising
a current collector; and a negative active material layer comprising the binder for the non-aqueous electrolyte rechargeable battery of claim 1 formed on the current collector.

15. A rechargeable battery comprising the negative electrode for the rechargeable battery of claim 14 .

Assignees

• Samsung Sdi Co Ltd

Inventors

• Fukatani Tomoyuki
• Hoshiba Koji
• Fukuchi Iwao

Classifications

• C08F220/48

  with nitrogen-containing monomers · CPC title

• H01M2004/027

  Negative electrodes · CPC title

• H01M4/622 Primary

  being polymers · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title