Electrode binder for secondary battery providing excellent adhesion strength and life characteristics

Patent metadata

Field	Value
Publication number	US-9620781-B2
Application number	US-201314409582-A
Country	US
Kind code	B2
Filing date	Jul 4, 2013
Priority date	Jul 11, 2012
Publication date	Apr 11, 2017
Grant date	Apr 11, 2017

Abstract

Disclosed is a binder for a secondary battery electrode including a copolymer of a hydrophilic monomer and a hydrophobic monomer, wherein, when a concentration of the copolymer is 5% in a solution based upon NMP as a solvent, a viscosity of the solution including the copolymer is 800 cP to 10000 cP. By using the binder, stability of an electrode is fundamentally improved from an electrode preparation process and, as such, a secondary battery having excellent lifespan characteristics is provided.

First claim

The invention claimed is:

1. A binder for a secondary battery electrode comprising a copolymer of a hydrophilic monomer and a hydrophobic monomer, wherein, when a concentration of the copolymer is 5% in a solution based upon NMP as a solvent, a viscosity of the solution comprising the copolymer is 800 cP to 10000 cP, and
wherein the copolymer is a copolymer of monomers comprising (A) at least one monomer selected from the group consisting of monomers comprising a nitrile group in 70 to 99 wt %, and (B) at least one monomer selected from the group consisting of monomers comprising a carboxylic acid group or an amide group in 1 to 30 wt %, based on a total weight of binder.

2. The binder for a secondary battery electrode according to claim 1 , wherein, when a concentration of the copolymer is 2% in a solution based upon NMP as a solvent, a viscosity of the solution comprising the copolymer is 30 cP to 700 cP.

3. The binder for a secondary battery electrode according to claim 1 , wherein, when a concentration of the copolymer is 5% in a solution based upon NMP as a solvent, a viscosity of the solution comprising the copolymer is 1000 cP to 5000 cP.

4. The binder for a secondary battery electrode according to claim 1 , wherein, when a concentration of the copolymer is 2% in a solution based upon NMP as a solvent, a viscosity of the solution comprising the copolymer is 50 cP to 500 cP.

5. The binder for a secondary battery electrode according to claim 1 , wherein the monomer comprising the nitrile group is at least one monomer selected the group consisting of a monomer group having a double bond comprising succinonitrile, sebaconitrile, nitrile fluoride and nitrile chloride, acrylonitrile, and methacrylonitrile.

6. The binder for a secondary battery electrode according to claim 1 , wherein the monomer comprising the carboxylic acid group or the amide group is at least one monomer selected the group consisting of an unsaturated monocarboxylic acid monomer such as acrylic acid, methacrylic acid, crotonic acid, isocrotonic acid and the like, an unsaturated dicarboxylic acid monomer such as maleic acid, fumaric acid, cytraconic acid, mesaconic acid, glutaconic acid and inaconic acid, an acid anhydride thereof, acrylamide, n-methylolacrylamide, n-butoxymethyl acrylamide, and methacrylamide.

7. The binder for a secondary battery electrode according to claim 1 , wherein the monomer comprising the nitrile group is acrylonitrile, the monomer comprising the carboxylic acid group or the amide group is acrylic acid, and a tensile strain is 5 to 100%.

8. The binder for a secondary battery electrode according to claim 1 , wherein the binder for an electrode is a binder for a cathode and/or a binder for an anode.

9. An electrode for a secondary battery, wherein an electrode active material and a conductive material bind to an electrode collector by the binder for a secondary battery electrode according to claim 1 .

10. The electrode for a secondary battery according to claim 9 , wherein the electrode collector has a thickness of 3 micrometers to 200 micrometers.

11. A lithium secondary battery comprising the electrode for a secondary battery according to claim 10 .

12. The electrode for a secondary battery according to claim 9 , wherein the electrode is a cathode and/or an anode.

Assignees

• Lg Chemical Ltd

Inventors

• Kang Min Ah
• Kim Young-Min
• Park Eun Joo

Classifications

• H01M10/052

  Li-accumulators · CPC title

• H01M4/622 Primary

  being polymers · CPC title

• H01M4/13

  Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof · CPC title

• C08F220/48

  with nitrogen-containing monomers · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title